File name: Pandora219s1_Ilocos_20241213_L2Fit_fout2c3d20240215p1-8.txt File generation date: 20241214T000252.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 219 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora219_OF_v2d20220124.txt Instrument calibration file used: Pandora219s1_CF_v3d20240215.txt Level 1 file used: Pandora219s1_Ilocos_20241213_L1_smca1c3d20240215p1-8.txt Full location name: Mariano Marcos State University Short location name: Ilocos Country of location: Philippines Location latitude [deg]: 18.0582 Location longitude [deg]: 120.5451 Location altitude [m]: 34 Local noon date: 20241213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 101 First and last pixel inside fitting window: 186 327 Nominal wavelengths inside fitting window [nm]: 305.0695 305.2108 305.3521 305.4933 305.6346 305.7758 305.9170 306.0583 306.1995 306.3407 306.4818 306.6230 306.7642 306.9053 307.0464 307.1876 307.3287 307.4698 307.6109 307.7519 307.8930 308.0341 308.1751 308.3161 308.4572 308.5982 308.7392 308.8802 309.0211 309.1621 309.3031 309.4440 309.5849 309.7258 309.8667 310.0076 310.1485 310.2894 310.4303 310.5711 310.7119 310.8528 310.9936 311.1344 311.2752 311.4159 311.5567 311.6975 311.8382 311.9789 312.1197 312.2604 312.4011 312.5418 312.6824 312.8231 312.9637 313.1044 313.2450 313.3856 313.5262 313.6668 313.8074 313.9480 314.0885 314.2291 314.3696 314.5101 314.6506 314.7911 314.9316 315.0721 315.2126 315.3530 315.4935 315.6339 315.7743 315.9147 316.0551 316.1955 316.3359 316.4762 316.6166 316.7569 316.8972 317.0375 317.1778 317.3181 317.4584 317.5987 317.7389 317.8792 318.0194 318.1596 318.2998 318.4400 318.5802 318.7204 318.8605 319.0007 319.1408 319.2809 319.4210 319.5611 319.7012 319.8413 319.9814 320.1214 320.2615 320.4015 320.5415 320.6815 320.8215 320.9615 321.1014 321.2414 321.3814 321.5213 321.6612 321.8011 321.9410 322.0809 322.2208 322.3606 322.5005 322.6403 322.7802 322.9200 323.0598 323.1996 323.3393 323.4791 323.6189 323.7586 323.8984 324.0381 324.1778 324.3175 324.4572 324.5968 324.7365 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241212T225022.5Z 9112.951650 184 1 50.28 2 84.36 116.61 125.59 313.01 0.00 1 0.00 1 0 25 5.634e-01 4.415e-02 4.475e-01 3.471e-02 7.267891e-01 1.961453e-02 7.110999e-03 -6.000000e+00 3.227421e-01 225.23 -2.00 3.11 -2.00 322.07 0.00e+00 -1.116560e-02 1.023895e-02 8.189774e-03 -6.000000e+00 1.712400e-02 292.67 -2.00 20.00 -2.00 321.48 0.00e+00 8.941 0.003 302.00 328.00 3 2.0959e-01 7.6399e-02 1.1073e-01 -6.0000e+00 7.9138e-01 1.0458e+00 9.4219e-02 8.8571e-02 -6.0000e+00 8.6190e-01 -1.5055e+00 5.8850e-02 2.0701e-02 -6.0000e+00 5.1728e-01 6.2012e-01 3.0121e-02 1.5530e-02 -6.0000e+00 2.2384e-01 3.5582e-05 -5.5517e-04 1.0592e-03 1.0351e-04 -6.0000e+00 1.5586e-02 6.7028e-02 8.9547e-05 12 8 8 10 0 0 54.60 23.40 0.64 0.06703 0.06286 27 6 1 5 0 1862.160 26.41 19.99 23.40 32.46 0.0 1001.33 70880 -27441 900000 198059 181569 -76761 187832 18107 64128 -84395 12787 900000 46985 900000 -11347 80244 -41524 1943 129318 125225 8299 900000 1356 130171 900000 900000 900000 -60067 -4653 -15659 100601 -47620 116212 -31888 900000 19917 -40478 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-2249 3339 5547 3893 2621 -1731 -722 736 6910 -1785 3765 -4928 13098 -1319 4354 -5564 -1671 -4037 -1966 672 4458 1343 -5317 486 -5109 -3075 -10685 -1205 -4600 -1183 -355 1215 2590 2563 -1658 -9463 5494 -2549 -324 -4772 3053 -4949 9470 -3969 6979 7658 5269 4707 774 1818 -6220 921 1435 4527 -10158 -4903 -2204 -2315 6145 7688 8446 294 -2622 -2654 -246 -8072 SS 20241212T230227.8Z 9112.960044 187 1 49.39 2 81.80 117.71 127.53 315.33 0.00 1 0.00 1 0 25 4.320e-01 1.080e-02 2.345e-01 5.492e-03 5.833633e-01 2.965911e-03 6.302640e-03 -6.000000e+00 2.450549e-01 225.23 -2.00 3.11 -2.00 321.63 0.00e+00 1.980907e-03 1.692842e-03 5.766272e-03 -6.000000e+00 1.156386e-02 292.67 -2.00 20.00 -2.00 320.99 0.00e+00 6.568 0.001 302.00 328.00 3 2.8004e-01 1.1719e-02 7.6601e-02 -6.0000e+00 6.0247e-01 4.6261e-02 1.6464e-02 4.9578e-02 -6.0000e+00 6.5451e-01 -1.3126e-01 1.5500e-02 1.9371e-02 -6.0000e+00 3.9236e-01 4.9069e-02 7.2101e-03 4.4215e-03 -6.0000e+00 1.6976e-01 3.8894e-04 5.4761e-04 1.6861e-04 8.2761e-05 -6.0000e+00 1.1632e-02 6.7165e-02 2.2894e-05 12 8 8 10 0 0 17.72 23.38 0.28 0.06717 0.07128 102 22 1 5 0 484.200 26.41 20.00 23.38 33.50 0.0 1006.30 -97447 -172973 85227 -102260 900000 -218691 -142183 -158296 -74622 -96395 -135855 -109109 -136773 -86450 -88966 -39728 -49142 -43065 -68356 -6499 -9692 16923 -23788 -2990 766 -53492 -107 -34118 14959 -19408 -19250 -9002 26594 7286 -24803 -25719 -13582 2237 -5066 19377 531 16555 11464 2817 -4759 9236 9645 6186 11623 -440 -1283 173 8568 3406 11741 3421 2412 2281 6008 4737 7205 2536 3086 5451 -165 3177 -247 2422 1568 5247 999 2463 2278 635 229 -2179 -2879 -703 -2410 61 -209 -2863 -1204 -1681 -178 -645 1334 2508 913 1760 -632 -1865 -1530 -1647 -679 462 621 641 -1117 -1099 -2147 -1691 -355 -1086 -1845 -1263 -950 -429 751 568 805 617 145 -1132 -576 -1177 257 268 618 755 867 1833 660 1313 -1001 -886 -338 317 -46 181 -518 -578 -657 194 333 62 874 261 240 -348 -353 -888 -522 -2189 456 -597 900000 -4045 -1384 -2080 -472 -798 -1785 -1328 -2796 -1346 -1732 -541 -813 -734 -1597 -85 -132 181 -417 -47 12 -1536 -2 -764 211 -444 -525 -259 595 195 -881 -989 -542 94 -279 962 35 975 810 220 -410 707 754 520 977 -46 -152 22 1106 496 1647 542 390 362 901 736 1188 497 681 1258 -39 716 -59 607 458 1660 350 855 758 199 65 -582 -768 -201 -826 24 -94 -1473 -649 -976 -110 -423 890 1668 600 1075 -369 -1050 -869 -1035 -488 380 585 665 -1190 -1108 -1989 -1430 -298 -991 -1810 -1302 -1046 -513 990 830 1246 959 219 -1633 -790 -1632 369 410 992 1215 1354 2747 971 1845 -1390 -1188 -467 488 -81 344 -1054 -1236 -1491 468 848 164 2327 701 623 -862 -830 -2045 SS 20241212T231708.4Z 9112.970236 192 1 49.46 2 78.73 119.13 129.76 318.38 0.00 1 0.00 1 0 25 1.856e-01 8.993e-03 4.212e-02 1.628e-03 4.627891e-01 8.442251e-04 4.985468e-03 -6.000000e+00 1.048519e-01 225.23 -2.00 3.11 -2.00 320.65 0.00e+00 8.097700e-04 3.489361e-04 2.715430e-03 -6.000000e+00 4.876916e-03 292.67 -2.00 20.00 -2.00 319.86 0.00e+00 4.940 0.000 302.00 328.00 3 1.1895e-01 2.7361e-03 5.4629e-02 -6.0000e+00 2.5809e-01 -3.5375e-02 3.5086e-03 2.8043e-02 -6.0000e+00 2.8035e-01 -9.2586e-04 3.0465e-03 1.1949e-02 -6.0000e+00 1.6834e-01 -5.7891e-03 1.5250e-03 3.1916e-03 -6.0000e+00 7.2919e-02 2.3613e-03 5.7224e-04 4.9343e-05 3.8912e-05 -6.0000e+00 4.9910e-03 6.7021e-02 1.6957e-05 11 8 0 10 0 0 48.32 23.37 0.24 0.06702 0.07132 276 59 1 5 0 179.180 26.41 20.00 23.37 34.88 0.0 1011.79 -70933 -44085 -57125 -77025 -58003 -89549 -41940 -70841 -19688 -72873 -26597 -46529 -16700 -29940 -7548 -14489 -2491 -12143 -16529 -1288 -15890 -1431 -19874 758 -9305 2375 -14422 -1216 -11790 -2790 -3228 -2398 -4456 -9444 -6207 -14443 -1858 -5288 3303 -2430 1895 -818 1817 2032 1343 1243 118 607 -1729 1696 -1116 3460 975 3583 470 2512 1061 494 654 168 2498 2656 4136 975 1360 -1363 -423 -356 1899 1325 2481 1492 1523 883 -1453 -1118 -4237 -1751 -2799 -851 -2166 -1739 -2319 -569 21 993 1494 1732 1813 281 450 -1721 -1090 -1339 -434 -118 1358 756 5 -909 -1733 -1702 -1090 -1119 -1825 -870 -1190 373 603 1297 996 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