File name: Pandora219s1_Ilocos_20250827_L2Fit_fout2c3d20240215p1-8.txt File generation date: 20250827T160410.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 219 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora219_OF_v2d20220124.txt Instrument calibration file used: Pandora219s1_CF_v3d20240215.txt Level 1 file used: Pandora219s1_Ilocos_20250827_L1_smca1c3d20240215p1-8.txt Full location name: Mariano Marcos State University Short location name: Ilocos Country of location: Philippines Location latitude [deg]: 18.0582 Location longitude [deg]: 120.5451 Location altitude [m]: 34 Local noon date: 20250827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 101 First and last pixel inside fitting window: 186 327 Nominal wavelengths inside fitting window [nm]: 305.0695 305.2108 305.3521 305.4933 305.6346 305.7758 305.9170 306.0583 306.1995 306.3407 306.4818 306.6230 306.7642 306.9053 307.0464 307.1876 307.3287 307.4698 307.6109 307.7519 307.8930 308.0341 308.1751 308.3161 308.4572 308.5982 308.7392 308.8802 309.0211 309.1621 309.3031 309.4440 309.5849 309.7258 309.8667 310.0076 310.1485 310.2894 310.4303 310.5711 310.7119 310.8528 310.9936 311.1344 311.2752 311.4159 311.5567 311.6975 311.8382 311.9789 312.1197 312.2604 312.4011 312.5418 312.6824 312.8231 312.9637 313.1044 313.2450 313.3856 313.5262 313.6668 313.8074 313.9480 314.0885 314.2291 314.3696 314.5101 314.6506 314.7911 314.9316 315.0721 315.2126 315.3530 315.4935 315.6339 315.7743 315.9147 316.0551 316.1955 316.3359 316.4762 316.6166 316.7569 316.8972 317.0375 317.1778 317.3181 317.4584 317.5987 317.7389 317.8792 318.0194 318.1596 318.2998 318.4400 318.5802 318.7204 318.8605 319.0007 319.1408 319.2809 319.4210 319.5611 319.7012 319.8413 319.9814 320.1214 320.2615 320.4015 320.5415 320.6815 320.8215 320.9615 321.1014 321.2414 321.3814 321.5213 321.6612 321.8011 321.9410 322.0809 322.2208 322.3606 322.5005 322.6403 322.7802 322.9200 323.0598 323.1996 323.3393 323.4791 323.6189 323.7586 323.8984 324.0381 324.1778 324.3175 324.4572 324.5968 324.7365 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250826T230437.6Z 9369.961546 67 1 49.74 2 71.54 85.14 114.72 91.96 0.00 1 0.00 1 0 17 5.897e-02 9.229e-03 3.267e-02 3.415e-03 3.395447e-01 1.719511e-03 3.652912e-03 -6.000000e+00 3.363758e-02 227.33 -2.00 3.11 -2.00 319.39 0.00e+00 7.867917e-04 4.701077e-04 1.281032e-03 -6.000000e+00 1.566110e-03 295.07 -2.00 20.00 -2.00 318.45 0.00e+00 3.117 0.000 302.00 328.00 3 3.1521e+00 4.9350e-03 3.4783e-02 -6.0000e+00 8.3133e-02 1.4364e-02 5.8482e-03 1.7246e-02 -6.0000e+00 9.0084e-02 9.5213e-03 4.1782e-03 7.9628e-03 -6.0000e+00 5.4081e-02 -1.3426e-02 2.1954e-03 2.0961e-03 -6.0000e+00 2.3413e-02 7.0636e-04 1.1813e-03 1.0203e-04 2.3833e-05 -6.0000e+00 1.5863e-03 5.9671e-02 1.2189e-04 11 8 0 10 0 0 99.96 23.18 0.19 0.05967 0.06855 58 12 1 5 0 857.460 26.21 20.00 23.18 33.57 0.0 994.76 -18645 4815 -15990 -21629 -678 -28446 -15023 -7179 -12739 -35950 7327 -15216 2649 -13105 10144 -5314 -3434 -2089 -6711 2466 -1409 3163 -3872 7690 -6711 -537 -680 124 -1641 4894 -335 -2048 758 -3781 -5753 -4286 838 -5006 2148 827 2100 -143 -558 278 750 -935 -1820 302 -2764 1436 -112 2262 915 1359 566 1101 -246 421 1816 1233 2241 2661 2163 1132 861 -441 -322 -539 1360 1188 1345 1337 1333 646 -472 -938 -3175 -638 -2038 -1354 -1848 -2995 -2892 -762 -146 699 781 819 1027 320 480 -1353 -1272 -1109 -387 -27 889 1205 303 -534 -1448 -1547 -584 -980 -1885 -741 -1084 458 310 1322 601 538 -26 -873 -621 -537 256 254 623 184 1050 714 1001 576 305 -938 257 277 -285 -228 -695 -513 -617 378 -24 489 740 870 -77 -229 -549 -895 -643 141 -576 -746 -17 -990 -509 -256 -528 -1926 257 -746 128 -877 620 -413 -276 -176 -620 216 -128 278 -387 733 -780 -60 -74 13 -164 536 -43 -269 105 -583 -856 -664 142 -1085 521 230 615 -41 -179 89 240 -304 -589 95 -904 475 -41 866 378 587 254 504 -115 192 803 559 1075 1398 1246 682 494 -238 -169 -297 833 813 973 977 944 431 -288 -518 -1697 -344 -1261 -950 -1459 -2597 -2635 -725 -148 748 867 917 1116 327 448 -1185 -1073 -986 -380 -30 1085 1586 403 -675 -1695 -1686 -638 -1165 -2408 -981 -1515 668 487 2203 944 911 -42 -1302 -867 -743 366 387 1012 307 1713 1138 1532 842 428 -1268 345 399 -450 -382 -1219 -921 -1156 745 -45 951 1467 1736 -151 -477 -1098 -1754 SS 20250827T000310.5Z 9370.002205 106 1 49.48 2 57.64 89.40 101.35 96.32 0.00 1 0.00 1 0 17 1.288e-02 8.799e-03 1.501e-03 5.576e-04 2.120830e-01 2.795263e-04 2.278534e-03 -6.000000e+00 7.345146e-03 227.33 -2.00 3.11 -2.00 317.17 0.00e+00 5.681410e-04 4.032766e-05 2.910492e-04 -6.000000e+00 3.420539e-04 295.07 -2.00 20.00 -2.00 316.22 0.00e+00 1.862 0.000 302.00 328.00 3 1.6476e+00 7.3479e-04 2.0732e-02 -6.0000e+00 1.8153e-02 1.5720e-02 8.2895e-04 9.7013e-03 -6.0000e+00 1.9672e-02 3.5686e-03 4.8870e-04 4.6945e-03 -6.0000e+00 1.1810e-02 -9.6846e-03 2.4110e-04 1.2973e-03 -6.0000e+00 5.1118e-03 1.2924e-02 9.6207e-04 1.6165e-05 1.5011e-05 -6.0000e+00 3.4649e-04 6.0606e-02 9.2869e-05 11 8 0 10 0 0 99.94 23.20 0.23 0.06061 0.06784 458 97 1 5 0 108.020 26.21 19.99 23.20 35.83 0.0 1004.44 -1092 609 -1255 -3968 -3222 -3201 -917 -471 15 -2269 -3054 -2447 -1814 -757 224 270 544 802 951 1639 335 1124 844 1253 983 1063 -88 -201 -456 959 1281 1757 79 -3211 -3812 -4277 -2572 -1300 -293 -679 -487 -410 -329 136 209 67 -313 -794 -829 240 470 763 1143 908 921 1140 390 43 -52 376 1490 2098 2555 1236 -79 -721 -1417 -249 1049 966 1310 1070 1177 818 -240 -1160 -2274 -1859 -1608 -1481 -1601 -2390 -2297 -1112 -298 413 890 1283 1087 545 149 -945 -891 -696 -280 228 1167 849 27 -547 -1482 -1741 -939 -875 -1336 -964 -942 -112 685 1070 1051 585 170 -555 -587 -513 64 451 739 262 635 707 617 656 118 -526 376 290 13 85 -435 -493 -290 93 103 413 622 390 14 -220 -854 -1019 -158 91 -186 -538 -392 -392 -121 -69 2 -370 -491 -418 -349 -164 53 68 140 213 261 459 95 314 246 384 315 345 -28 -58 -126 267 379 556 27 -1079 -1208 -1426 -962 -573 -152 -394 -270 -234 -191 78 120 42 -189 -469 -481 142 297 508 724 598 616 776 268 29 -39 281 1064 1614 2094 1043 -63 -578 -1087 -194 826 846 1207 1000 1069 703 -208 -906 -1664 -1367 -1308 -1353 -1473 -2381 -2389 -1218 -348 508 1135 1646 1359 638 160 -926 -907 -664 -291 261 1468 1148 36 -703 -1775 -1964 -1071 -1085 -1773 -1332 -1361 -168 988 1620 1616 871 258 -777 -765 -658 85 640 1124 414 995 1080 907 913 157 -668 469 383 19 127 -668 -767 -466 144 170 696 1071 680 24 -366 -1381 -1614 SS 20250827T001339.3Z 9370.009482 109 1 48.33 2 55.15 90.21 98.97 97.10 0.00 1 0.00 1 0 17 1.419e-02 1.017e-02 6.645e-03 2.540e-03 1.989993e-01 1.282265e-03 2.135917e-03 -6.000000e+00 8.092184e-03 227.33 -2.00 3.11 -2.00 316.99 0.00e+00 3.558649e-04 1.764905e-04 3.245244e-04 -6.000000e+00 3.767940e-04 295.07 -2.00 20.00 -2.00 316.04 0.00e+00 1.745 0.000 302.00 328.00 3 4.4381e+00 3.3670e-03 1.9419e-02 -6.0000e+00 1.9999e-02 3.9622e-02 3.7969e-03 9.0792e-03 -6.0000e+00 2.1672e-02 3.1155e-03 2.2362e-03 4.3822e-03 -6.0000e+00 1.3011e-02 -1.0159e-02 1.0870e-03 1.2269e-03 -6.0000e+00 5.6322e-03 9.0185e-04 1.0781e-03 7.3476e-05 1.3869e-05 -6.0000e+00 3.8166e-04 6.0051e-02 1.1014e-04 12 8 8 10 0 0 99.75 23.21 0.20 0.06005 0.06815 19 4 1 5 0 2543.590 26.21 20.01 23.21 36.55 0.0 1008.12 -1593 1312 -3879 -3109 -4565 -1630 -767 1292 -808 -2526 -2886 -3671 331 -390 507 464 1674 1231 1143 -270 -340 636 2369 1357 510 1094 -496 -633 -8 1327 685 2902 97 -2991 -4137 -3264 -2115 -1931 -263 -249 -878 -646 -477 -31 776 -383 -181 -1646 -804 255 840 1322 803 1680 631 226 -159 624 -393 617 1669 1414 2105 846 128 -1058 -1365 -231 1205 1311 1391 1331 1413 850 13 -1394 -2741 -1680 -1868 -2132 -1771 -2452 -2359 -491 -191 615 888 1766 1325 600 182 -1585 -1297 -1038 -627 543 1311 690 607 -543 -1528 -2321 -1342 -800 -1253 -1335 -939 -76 842 1280 1455 1075 129 -360 -809 -677 -430 648 681 326 875 522 725 563 462 -890 568 627 187 -489 -485 -693 -377 32 53 421 749 539 -46 -351 -945 -790 -241 202 -611 -432 -581 -203 -104 192 -133 -423 -473 -645 63 -84 121 116 423 322 309 -76 -95 176 738 449 177 384 -169 -198 -2 391 216 957 35 -1053 -1379 -1129 -824 -894 -142 -136 -508 -384 -287 -18 458 -247 -113 -1005 -477 154 538 889 569 1222 471 173 -122 467 -293 464 1317 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