File name: Pandora106s1_Innsbruck_20240924_L2Fit_fout2c9d20221125p1-8.txt File generation date: 20240924T231117.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v9d20221125.txt Level 1 file used: Pandora106s1_Innsbruck_20240924_L1_smca1c9d20221125p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20240924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 "based on session5: fieldCal for IAO 2022" fieldcal Nov 2022 new refday First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0714 305.2123 305.3533 305.4943 305.6352 305.7761 305.9171 306.0580 306.1989 306.3398 306.4807 306.6215 306.7624 306.9032 307.0441 307.1849 307.3257 307.4666 307.6074 307.7481 307.8889 308.0297 308.1705 308.3112 308.4519 308.5927 308.7334 308.8741 309.0148 309.1555 309.2962 309.4368 309.5775 309.7181 309.8588 309.9994 310.1400 310.2806 310.4212 310.5618 310.7024 310.8430 310.9835 311.1241 311.2646 311.4051 311.5456 311.6861 311.8266 311.9671 312.1076 312.2481 312.3885 312.5290 312.6694 312.8098 312.9502 313.0906 313.2310 313.3714 313.5118 313.6521 313.7925 313.9328 314.0732 314.2135 314.3538 314.4941 314.6344 314.7747 314.9149 315.0552 315.1955 315.3357 315.4759 315.6161 315.7564 315.8966 316.0367 316.1769 316.3171 316.4573 316.5974 316.7375 316.8777 317.0178 317.1579 317.2980 317.4381 317.5782 317.7182 317.8583 317.9983 318.1384 318.2784 318.4184 318.5584 318.6984 318.8384 318.9784 319.1184 319.2583 319.3983 319.5382 319.6781 319.8180 319.9579 320.0978 320.2377 320.3776 320.5174 320.6573 320.7971 320.9370 321.0768 321.2166 321.3564 321.4962 321.6360 321.7758 321.9155 322.0553 322.1950 322.3347 322.4745 322.6142 322.7539 322.8936 323.0332 323.1729 323.3126 323.4522 323.5918 323.7315 323.8711 324.0107 324.1503 324.2899 324.4294 324.5690 324.7086 324.8481 324.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Zenith motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240924T062034.3Z 9033.264285 269 1 50.92 2 78.05 104.30 27.66 235.60 0.00 1 0.00 1 0 33 5.448e-01 7.316e-02 1.179e-01 7.069e-03 5.776330e-01 4.223695e-03 1.033225e-02 -6.000000e+00 3.775616e-01 227.40 -2.00 3.66 -2.00 320.19 0.00e+00 4.733095e-02 1.346714e-03 7.308598e-03 -6.000000e+00 1.647326e-02 278.84 -2.00 20.00 -2.00 319.62 0.00e+00 4.684 0.002 302.00 328.00 3 4.3393e+00 1.2345e-02 5.4153e-02 -6.0000e+00 9.3575e-01 8.8583e-01 1.3964e-02 3.6406e-02 -6.0000e+00 1.0100e+00 -9.7250e-01 8.3890e-03 2.7167e-02 -6.0000e+00 6.0098e-01 4.1022e-01 4.0959e-03 3.0672e-02 -6.0000e+00 2.4362e-01 3.3128e-05 -3.4359e-03 2.5840e-04 9.5062e-04 -6.0000e+00 2.3192e-02 4.4926e-02 0.0000e+00 12 8 8 10 0 0 98.56 18.05 -0.78 0.04493 0.01911 16 3 1 5 0 3182.340 22.09 15.00 18.05 17.45 47.90 46.60 42.8 912.65 57564 -106049 116172 89519 2247 11711 89007 160977 312411 8865 31840 -32117 112564 71994 76322 77959 101283 84324 161258 172562 15926 69717 13891 -23524 47560 6604 20046 13460 -6808 5037 28240 19427 47548 193791 130796 56200 155476 33879 -26312 17952 62344 10594 -5162 22309 32680 49172 28843 49868 37090 79549 28848 34728 24072 21038 4037 25678 20305 -18893 23847 -11180 -950 23214 11689 29354 29354 19959 13331 17801 10723 285 -7325 6425 9759 -2513 -9260 -8964 5700 -1489 -8771 -24909 -1149 -2113 -9914 2127 -6024 -13137 -2229 209 -8174 -4621 -1746 753 -7566 -778 -7664 3339 -13549 -4507 -1972 3145 -224 440 -3043 -2131 -5016 3385 -3388 -1863 3149 89 42975 -1360 -223 -1192 780 -3736 -92 -390 3050 1535 1417 3701 1082 1057 -2416 5391 -1533 7427 -2055 5188 1539 1395 610 1792 321 -853 -1744 -4632 -819 560 -1378 -2295 900000 3015 -28678 4232 3966 192 748 2658 2330 2153 336 1063 -2245 3414 3154 4133 5028 5884 6268 6156 5764 2056 5011 1404 -2962 2763 530 1372 1027 -717 563 3031 2482 5360 6010 6865 5644 6265 4420 -6118 2804 6998 1957 -1184 4141 5826 8448 5977 9403 7754 12219 7211 8537 6747 6080 1350 6654 5336 -7171 5939 -4151 -347 7392 4608 10385 10709 8024 5739 7509 5099 159 -4263 3469 4910 -1339 -4889 -4436 2401 -712 -5046 -18016 -739 -1506 -8195 1647 -5317 -12993 -2037 188 -7905 -4152 -1447 583 -6316 -638 -7478 3319 -16951 -5643 -2513 3778 -266 487 -3350 -2324 -5824 3813 -4366 -2557 4470 133 49630 -2224 -358 -1874 1168 -5796 -139 -614 4792 2487 2282 5683 1647 1641 -3758 7635 -2364 11074 -3450 8806 2909 2653 1229 3743 709 -1862 -3895 -10627 -1866 1214 -2921 -4765 900000 SS 20240924T062525.4Z 9033.267655 272 1 35.58 2 77.26 105.23 28.33 237.30 0.00 1 0.00 1 0 25 2.546e-01 1.563e-02 5.963e-02 3.331e-03 5.899704e-01 2.018599e-03 7.200895e-03 -6.000000e+00 1.764422e-01 227.40 -2.00 3.66 -2.00 320.04 0.00e+00 4.416254e-03 6.889957e-04 3.665182e-04 -6.000000e+00 7.698313e-03 278.84 -2.00 20.00 -2.00 319.46 0.00e+00 4.412 0.002 302.00 328.00 3 3.3539e+00 5.9136e-03 5.2248e-02 -6.0000e+00 4.3729e-01 2.1282e-01 7.0339e-03 3.2656e-02 -6.0000e+00 4.7202e-01 -1.9891e-01 5.5581e-03 1.6387e-02 -6.0000e+00 2.8085e-01 7.6723e-02 2.7558e-03 5.7073e-03 -6.0000e+00 1.1385e-01 1.4779e-04 -2.3887e-03 1.2759e-04 1.0366e-04 -6.0000e+00 1.0838e-02 4.4970e-02 0.0000e+00 12 9 9 12 1 1 99.77 18.05 0.09 0.04497 0.02702 26 8 1 5 0 1317.770 22.09 14.99 18.05 17.54 48.90 46.40 42.8 913.03 -67819 -96340 -56533 -66383 -136390 -122929 -89572 15310 -10411 -52856 -57074 -77753 16596 -27338 -28882 -38001 -25138 -14980 13539 8693 -46000 -10505 -25328 -29660 -10896 -17180 -6356 21 -16603 -6139 -6034 -17661 -582 20404 14077 1827 21111 6206 -21450 -1329 10709 3276 -3675 5734 4938 7385 2467 5016 7532 12389 2403 7213 3666 4065 240 8343 5833 -2332 6990 -1796 853 5673 2565 3825 4887 3977 2085 5003 1615 -609 -2367 387 1411 -1154 -548 -1526 3461 -48 -1189 -6842 -964 -1545 -2155 508 -1431 -2577 -623 -653 -2233 -1059 523 1770 131 1602 414 1481 -3404 -1562 -1034 318 -428 1271 -588 -355 -1404 29 -485 -104 1017 159 -64 -604 410 418 1563 1038 584 -211 -75 -420 -448 170 -415 3 -35 2101 958 1754 -275 988 490 704 278 464 -94 -539 -838 -968 -247 -246 -16 -281 900000 -1133 -2369 -970 -1247 -5062 -4021 -2202 153 -146 -1228 -1430 -2796 303 -875 -1119 -1860 -1207 -705 509 357 -3350 -551 -1598 -2043 -647 -1112 -373 1 -1140 -414 -458 -1688 -51 1519 1153 179 1900 747 -3941 -226 1776 625 -732 1145 1015 1511 544 1116 1719 2696 627 1952 1108 1300 83 2742 1986 -861 2355 -675 329 2255 1068 1669 2174 1807 986 2419 872 -364 -1523 247 873 -695 -306 -810 1712 -25 -707 -4584 -687 -1227 -1767 434 -1324 -2530 -619 -655 -2239 -1010 468 1509 114 1439 414 1554 -4171 -1930 -1316 394 -512 1492 -684 -416 -1728 35 -633 -146 1456 247 -100 -975 650 644 2422 1595 910 -340 -119 -677 -716 276 -656 5 -52 3122 1392 2666 -440 1693 865 1318 529 930 -198 -1132 -1796 -2078 -517 -517 -33 -558 900000 SS 20240924T063445.1Z 9033.274133 275 1 27.24 2 75.74 107.06 29.64 240.40 0.00 1 0.00 1 0 25 1.555e-01 1.028e-02 4.127e-02 2.501e-03 5.443355e-01 1.506311e-03 6.663132e-03 -6.000000e+00 1.077978e-01 227.40 -2.00 3.66 -2.00 319.57 0.00e+00 1.113101e-03 4.418499e-04 4.158303e-04 -6.000000e+00 4.702116e-03 278.84 -2.00 20.00 -2.00 318.97 0.00e+00 3.972 0.001 302.00 328.00 3 3.0920e+00 4.2589e-03 4.7393e-02 -6.0000e+00 2.6717e-01 1.3681e-01 4.9709e-03 2.9841e-02 -6.0000e+00 2.8834e-01 -9.6302e-02 3.7868e-03 1.4709e-02 -6.0000e+00 1.7157e-01 3.0892e-02 1.9067e-03 4.1838e-03 -6.0000e+00 6.9582e-02 3.0426e-04 -1.9079e-03 9.7685e-05 7.7548e-05 -6.0000e+00 6.6185e-03 4.2111e-02 0.0000e+00 12 9 9 12 1 1 99.70 18.05 0.06 0.04211 0.02777 31 12 1 5 0 851.040 22.09 15.00 18.05 17.89 48.40 45.90 42.6 914.24 -31792 -60452 -37987 -63916 -89344 -66370 -44672 45041 -7399 -29378 -31692 -35851 1886 -14149 -5913 -15635 2355 -16408 5233 6413 -19818 -3209 -19421 -15175 -7585 -4202 -10177 -766 -7157 -11745 -3251 -12773 -2914 1179 7110 34 7094 6330 -9446 -709 1824 1086 -1632 804 2478 920 1019 2419 2601 5200 378 3263 818 3002 -28 3875 2094 267 2650 -748 1838 2185 430 1198 2860 1225 1896 2776 976 68 -2315 -586 2 84 -518 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