File name: Pandora106s1_Innsbruck_20241121_L2Fit_fout2c9d20221125p1-8.txt File generation date: 20241121T231223.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v9d20221125.txt Level 1 file used: Pandora106s1_Innsbruck_20241121_L1_smca1c9d20221125p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20241121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 "based on session5: fieldCal for IAO 2022" fieldcal Nov 2022 new refday First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0714 305.2123 305.3533 305.4943 305.6352 305.7761 305.9171 306.0580 306.1989 306.3398 306.4807 306.6215 306.7624 306.9032 307.0441 307.1849 307.3257 307.4666 307.6074 307.7481 307.8889 308.0297 308.1705 308.3112 308.4519 308.5927 308.7334 308.8741 309.0148 309.1555 309.2962 309.4368 309.5775 309.7181 309.8588 309.9994 310.1400 310.2806 310.4212 310.5618 310.7024 310.8430 310.9835 311.1241 311.2646 311.4051 311.5456 311.6861 311.8266 311.9671 312.1076 312.2481 312.3885 312.5290 312.6694 312.8098 312.9502 313.0906 313.2310 313.3714 313.5118 313.6521 313.7925 313.9328 314.0732 314.2135 314.3538 314.4941 314.6344 314.7747 314.9149 315.0552 315.1955 315.3357 315.4759 315.6161 315.7564 315.8966 316.0367 316.1769 316.3171 316.4573 316.5974 316.7375 316.8777 317.0178 317.1579 317.2980 317.4381 317.5782 317.7182 317.8583 317.9983 318.1384 318.2784 318.4184 318.5584 318.6984 318.8384 318.9784 319.1184 319.2583 319.3983 319.5382 319.6781 319.8180 319.9579 320.0978 320.2377 320.3776 320.5174 320.6573 320.7971 320.9370 321.0768 321.2166 321.3564 321.4962 321.6360 321.7758 321.9155 322.0553 322.1950 322.3347 322.4745 322.6142 322.7539 322.8936 323.0332 323.1729 323.3126 323.4522 323.5918 323.7315 323.8711 324.0107 324.1503 324.2899 324.4294 324.5690 324.7086 324.8481 324.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Zenith motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241121T080741.0Z 9091.338669 340 1 6.72 2 77.70 138.85 55.17 264.17 0.00 1 0.00 1 0 25 3.124e-01 2.554e-02 2.014e-01 1.086e-02 6.032865e-01 6.428967e-03 7.271774e-03 -6.000000e+00 2.121610e-01 221.55 -2.00 3.66 -2.00 320.03 0.00e+00 1.997810e-03 2.091236e-03 5.899406e-04 -6.000000e+00 9.169182e-03 271.17 -2.00 20.00 -2.00 319.57 0.00e+00 4.562 0.002 302.00 328.00 3 3.6146e+00 1.8356e-02 5.2762e-02 -6.0000e+00 5.2024e-01 2.5735e-01 2.1702e-02 3.2121e-02 -6.0000e+00 5.6421e-01 -3.0537e-01 1.7526e-02 1.6644e-02 -6.0000e+00 3.3563e-01 1.3732e-01 8.8143e-03 5.3251e-03 -6.0000e+00 1.3677e-01 1.0159e-04 -7.0636e-04 4.1183e-04 1.0492e-04 -6.0000e+00 1.3266e-02 3.4167e-02 0.0000e+00 12 9 9 12 33 1 999.00 18.37 -0.22 0.03417 0.02886 2 4 1 5 0 2240.260 22.40 15.00 18.37 7.52 38.30 35.60 33.2 386.59 -111779 23959 70506 -117852 -120599 -131512 50960 -31358 145144 -104847 -62783 -43980 -9653 -16122 -55297 5444 20972 -45997 47813 1700 -10511 -8167 8450 -60878 11738 -6181 11598 -9742 -32320 -2592 3528 43338 1855 43519 61887 -10561 39593 -863 -20711 10820 18613 5681 -4106 7494 -4742 25912 -391 12404 7434 20581 4201 6877 8763 8877 -92 10082 7805 1195 9853 2572 -4411 8552 -2877 4566 8587 -2016 5842 4075 4596 440 -2711 -2126 4327 -873 -2188 -1582 -900 4768 -5951 -11650 -695 -1600 -1372 2289 -1240 -4007 -1178 -654 -3418 -88 635 3565 -1137 2972 -1513 1969 381 -1705 434 -1403 -872 -536 449 -1556 -1366 948 -791 36 1413 -43 -6735 554 261 944 2439 -374 200 115 1738 -1282 2447 1495 -174 1689 -1271 3353 271 2132 -408 1700 1646 296 129 365 166 -756 -393 -1119 -1401 -209 -683 -185 900000 -3944 273 746 -4823 -4936 -6032 593 -640 1536 -4883 -2278 -1529 -285 -609 -3395 222 809 -3473 1590 86 -616 -478 466 -6572 683 -410 693 -674 -2896 -187 266 2621 171 2961 3603 -1252 3382 -119 -4019 1733 3021 1114 -864 1528 -1038 4516 -91 2608 1726 4487 1098 1902 2562 2754 -33 3315 2649 432 3252 929 -1794 3292 -1265 1976 3678 -973 2666 1994 2418 261 -1655 -1311 2592 -522 -1234 -834 -462 2416 -3701 -8200 -495 -1275 -1123 1933 -1150 -3804 -1120 -623 -3292 -83 568 2993 -1003 2659 -1482 2090 435 -2149 554 -1802 -1064 -618 522 -1865 -1618 1159 -1052 49 2058 -66 -11132 910 427 1494 3691 -575 308 183 2780 -2138 3894 2341 -268 2572 -1931 4791 406 3313 -674 2858 2975 552 256 729 346 -1584 -833 -2383 -2929 -433 -1363 -374 900000 SS 20241121T081154.1Z 9091.341598 343 1 50.12 2 77.23 139.75 55.87 264.96 0.00 1 0.00 1 0 25 2.513e-01 2.553e-02 5.220e-02 2.967e-03 5.830339e-01 1.757548e-03 7.209770e-03 -6.000000e+00 1.704993e-01 221.55 -2.00 3.66 -2.00 320.03 0.00e+00 1.303951e-02 5.611331e-04 1.073968e-03 -6.000000e+00 7.374181e-03 271.17 -2.00 20.00 -2.00 319.57 0.00e+00 4.407 0.002 302.00 328.00 3 3.4994e+00 5.0095e-03 5.2424e-02 -6.0000e+00 4.1807e-01 3.0468e-01 5.8311e-03 3.6727e-02 -6.0000e+00 4.5356e-01 -3.6738e-01 4.5351e-03 1.7280e-02 -6.0000e+00 2.6981e-01 1.7006e-01 2.2799e-03 1.2838e-02 -6.0000e+00 1.0981e-01 1.2750e-04 -2.8780e-03 1.1277e-04 1.9331e-04 -6.0000e+00 1.0672e-02 4.1445e-02 0.0000e+00 12 9 8 11 32 0 99.70 18.38 -0.09 0.04144 0.01982 37 7 1 5 0 1354.510 22.40 15.00 18.38 7.53 37.30 35.30 33.2 386.57 -39470 -185789 -17726 -33791 -103764 -76601 -29235 78330 37968 -36356 -20567 -57597 14908 -12858 571 -4500 44421 11415 55086 58817 -20983 19177 -8157 -11692 9486 -8687 10857 -1713 -5593 -7674 15283 -1324 11423 37133 32293 16999 31125 12545 -18467 3588 17162 3879 3299 8240 11998 13676 11142 11837 14245 23029 7830 12189 6883 7748 953 7267 4658 -4565 7272 -2744 2299 6104 4160 7897 6764 5029 3013 5883 2493 -3 -3425 -562 1410 -1675 -1639 -2641 2936 -548 -2967 -8398 -1839 -2241 -3370 7 -3505 -4697 -1397 -1605 -2635 -1003 709 1448 -623 13 -1231 496 -1835 -1621 -849 935 160 981 -188 -828 -1254 600 -359 -429 1290 -219 -3453 -196 315 505 1109 749 863 205 342 171 367 1130 686 900 452 2453 1159 3079 -227 1749 963 1029 509 495 80 -524 -990 -805 -986 -761 -739 -1059 900000 -897 -18956 -374 -817 -4803 -2596 -657 661 456 -963 -508 -2238 372 -489 23 -222 1621 583 2060 2173 -1604 975 -543 -807 531 -583 601 -109 -393 -611 1102 -128 1055 2762 2569 1637 2824 1540 -3499 608 2763 759 680 1676 2420 2789 2404 2632 3247 5125 2040 3277 2082 2437 330 2397 1577 -1684 2386 -1021 863 2395 1812 3529 3157 2415 1408 2791 1313 -2 -2170 -351 846 -982 -895 -1370 1504 -285 -1741 -5896 -1284 -1740 -2869 6 -3194 -4542 -1349 -1570 -2566 -926 649 1267 -555 12 -1207 537 -2152 -2060 -1057 1193 197 1132 -212 -946 -1493 740 -477 -585 1874 -332 -5711 -321 511 794 1682 1123 1304 321 549 279 594 1770 1044 1384 675 3534 1716 4711 -369 3029 1722 1953 979 1000 163 -1104 -2131 -1727 -2079 -1611 -1503 -2104 900000 SS 20241121T081630.7Z 9091.344799 346 1 49.93 2 76.73 140.73 56.64 265.80 0.00 1 0.00 1 0 25 1.895e-01 7.835e-03 9.880e-03 5.070e-04 5.811677e-01 3.004292e-04 7.194308e-03 -6.000000e+00 1.286155e-01 221.55 -2.00 3.66 -2.00 319.94 0.00e+00 2.042397e-03 9.761525e-05 1.563504e-03 -6.000000e+00 5.559991e-03 271.17 -2.00 20.00 -2.00 319.50 0.00e+00 4.252 0.001 302.00 328.00 3 2.8750e-01 8.5422e-04 5.0466e-02 -6.0000e+00 3.1538e-01 9.8832e-02 1.0130e-03 3.2742e-02 -6.0000e+00 3.4207e-01 -8.0175e-02 8.6955e-04 1.6100e-02 -6.0000e+00 2.0349e-01 2.5676e-02 4.4384e-04 4.8720e-03 -6.0000e+00 8.2883e-02 3.9156e-03 -1.8881e-03 1.9445e-05 9.1476e-05 -6.0000e+00 8.0449e-03 3.6720e-02 0.0000e+00 11 8 0 10 0 0 99.90 18.38 0.18 0.03672 0.02253 1266 256 1 5 0 39.430 22.40 15.00 18.38 7.63 37.60 37.30 33.4 387.01 -80721 -83122 -62553 -62040 -66405 -67606 -62578 -53275 -51213 -51478 -44912 -39309 -27056 -23861 -17299 -13016 -10622 -9710 -7360 -5230 -7746 -6528 -7122 -8160 -8030 -7851 -7365 -7662 -4941 -5212 -3389 -3572 -1588 -441 -1518 -909 581 -878 -1915 -812 -90 -371 -179 538 811 1210 1171 1458 1894 2354 1860 2323 2165 1789 1528 906 706 969 1685 1744 1787 1186 727 553 1157 1825 1945 1709 662 75 -845 -1110 -780 -635 -273 700 1173 881 325 -674 -976 -1201 -1076 -893 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