File name: Pandora106s1_Innsbruck_20241214_L2Fit_fout2c9d20221125p1-8.txt File generation date: 20241214T231335.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v9d20221125.txt Level 1 file used: Pandora106s1_Innsbruck_20241214_L1_smca1c9d20221125p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20241214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 "based on session5: fieldCal for IAO 2022" fieldcal Nov 2022 new refday First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0714 305.2123 305.3533 305.4943 305.6352 305.7761 305.9171 306.0580 306.1989 306.3398 306.4807 306.6215 306.7624 306.9032 307.0441 307.1849 307.3257 307.4666 307.6074 307.7481 307.8889 308.0297 308.1705 308.3112 308.4519 308.5927 308.7334 308.8741 309.0148 309.1555 309.2962 309.4368 309.5775 309.7181 309.8588 309.9994 310.1400 310.2806 310.4212 310.5618 310.7024 310.8430 310.9835 311.1241 311.2646 311.4051 311.5456 311.6861 311.8266 311.9671 312.1076 312.2481 312.3885 312.5290 312.6694 312.8098 312.9502 313.0906 313.2310 313.3714 313.5118 313.6521 313.7925 313.9328 314.0732 314.2135 314.3538 314.4941 314.6344 314.7747 314.9149 315.0552 315.1955 315.3357 315.4759 315.6161 315.7564 315.8966 316.0367 316.1769 316.3171 316.4573 316.5974 316.7375 316.8777 317.0178 317.1579 317.2980 317.4381 317.5782 317.7182 317.8583 317.9983 318.1384 318.2784 318.4184 318.5584 318.6984 318.8384 318.9784 319.1184 319.2583 319.3983 319.5382 319.6781 319.8180 319.9579 320.0978 320.2377 320.3776 320.5174 320.6573 320.7971 320.9370 321.0768 321.2166 321.3564 321.4962 321.6360 321.7758 321.9155 322.0553 322.1950 322.3347 322.4745 322.6142 322.7539 322.8936 323.0332 323.1729 323.3126 323.4522 323.5918 323.7315 323.8711 324.0107 324.1503 324.2899 324.4294 324.5690 324.7086 324.8481 324.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Zenith motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241214T085259.2Z 9114.370129 356 1 18.92 2 76.91 148.09 105.37 342.65 0.00 1 0.00 1 0 33 2.108e-01 1.726e-02 1.656e-01 7.960e-03 5.864876e-01 4.730215e-03 7.210172e-03 -6.000000e+00 1.429213e-01 221.22 -2.00 3.66 -2.00 320.04 0.00e+00 3.078020e-03 1.530303e-03 3.902878e-04 -6.000000e+00 6.238287e-03 268.52 -2.00 20.00 -2.00 319.62 0.00e+00 4.305 0.002 302.00 328.00 3 4.3899e+00 1.3420e-02 5.0400e-02 -6.0000e+00 3.5032e-01 2.1506e-01 1.5916e-02 3.1494e-02 -6.0000e+00 3.8039e-01 -1.7883e-01 1.3620e-02 1.6269e-02 -6.0000e+00 2.2585e-01 6.3475e-02 6.9458e-03 5.1028e-03 -6.0000e+00 9.1811e-02 5.9412e-05 -2.1719e-03 3.0805e-04 9.9256e-05 -6.0000e+00 8.9968e-03 4.2522e-02 0.0000e+00 12 9 9 12 33 33 48.78 18.35 0.08 0.04252 0.02620 4 3 1 5 0 3782.600 22.40 15.00 18.35 7.30 38.10 35.60 35.5 512.62 -78200 -123796 -13401 900000 -33510 49686 -45366 -30510 -41512 -20363 -56491 -66723 -73411 -31628 25434 -3344 55029 1332 3260 -43401 -13751 24703 -33912 -25122 -50780 -1012 4855 -3703 -43520 -12419 -3150 4619 4415 -15049 7223 -2573 -6317 15341 -7878 4096 -9146 12164 428 16774 1006 -387 -7657 -1399 15271 7844 18930 1630 5219 8982 2690 5810 1776 4438 914 -1113 3168 -1553 5227 2449 453 1653 3947 1976 3265 2997 -3464 643 67 -1132 1760 1043 642 -707 2769 -4223 434 -1639 -1690 -2053 -2422 -2861 -1357 -715 -1218 450 -104 -593 1454 -394 -1203 -367 -1240 -2483 -2345 -189 -13 2159 267 646 -912 -499 265 -498 -224 683 4448 -314 -168 981 2140 1984 622 -1263 -2044 -675 -517 42 -1051 -1779 568 1302 1985 982 1664 -598 634 544 151 -217 -252 247 -1101 -689 -397 -377 252 346 900000 -1416 -3906 -156 900000 -464 386 -754 -473 -782 -339 -1503 -2293 -3038 -1122 606 -122 1250 56 143 -2941 -762 958 -2298 -1637 -4466 -59 272 -228 -3872 -943 -244 371 387 -1565 665 -258 -732 1651 -1239 648 -1817 2083 86 2933 210 -83 -1814 -322 3128 1854 4348 484 1612 2839 887 1907 613 1489 317 -402 1154 -639 2178 1113 217 790 1881 1010 1778 1666 -2169 393 40 -655 979 549 332 -386 1606 -2793 309 -1245 -1395 -1819 -2284 -2690 -1295 -683 -1214 424 -94 -519 1246 -362 -1224 -393 -1487 -3093 -3017 -235 -16 2497 306 742 -1106 -604 340 -693 -321 1044 6908 -500 -264 1555 3250 2971 952 -2022 -3235 -1066 -847 66 -1633 -2687 851 1905 2928 1470 2674 -1017 1143 997 294 -426 -518 523 -2399 -1494 -843 -773 515 690 900000 SS 20241214T090254.5Z 9114.377019 359 1 50.95 2 76.04 150.26 105.80 344.80 0.00 1 0.00 1 0 25 3.250e-01 3.565e-02 1.342e-01 6.718e-03 5.566047e-01 3.962197e-03 7.204545e-03 -6.000000e+00 2.195112e-01 221.22 -2.00 3.66 -2.00 319.96 0.00e+00 7.713320e-04 1.188356e-03 2.695865e-03 -6.000000e+00 9.427952e-03 268.52 -2.00 20.00 -2.00 319.51 0.00e+00 4.056 0.001 302.00 328.00 3 5.1726e+00 1.1150e-02 4.9399e-02 -6.0000e+00 5.3830e-01 3.5719e-01 1.2900e-02 3.5038e-02 -6.0000e+00 5.8498e-01 -4.0815e-01 9.7586e-03 1.5530e-02 -6.0000e+00 3.4751e-01 1.7995e-01 4.9503e-03 5.0162e-03 -6.0000e+00 1.4066e-01 3.4431e-05 -5.2216e-03 2.6490e-04 9.1865e-05 -6.0000e+00 1.3797e-02 6.3213e-02 0.0000e+00 12 9 8 11 32 0 99.92 18.35 -0.25 0.06321 0.02398 16 3 1 5 0 3183.920 22.40 15.00 18.35 7.27 36.30 36.30 35.4 512.53 -51602 129743 29193 -49316 -17825 -105059 7086 -20470 175408 5680 -15910 -57012 142767 5729 -4555 9453 9379 -2517 -11163 43313 -63180 -910 -28069 -34792 24503 6729 20964 21412 -10676 -20490 2963 -22052 18867 100283 120679 16581 84651 22585 -45808 12796 41461 11418 -6370 10279 6361 17201 3534 8179 28437 35620 -1873 6721 1516 7846 -6593 19686 14457 -7246 21647 -8296 -5092 9424 1783 13194 13615 5071 1998 8804 2636 -4787 9551 3086 7947 408 -3916 -4969 10361 611 -7366 238 -4799 -4625 -7051 3265 -4415 -9731 452 1056 -122 -538 -464 2925 -2769 1512 -3984 3085 413 -4045 -3071 261 1567 -548 -2801 -1909 -4222 4743 -2303 -711 3611 901 1506 -739 358 -1108 1749 -1996 249 -80 2694 1631 37 2951 -166 723 -3292 4128 -2397 6213 -2660 2532 -53 327 -70 424 1477 -60 -1085 16 -1188 694 -830 -2017 900000 -2073 1046 601 -2003 -542 -7065 172 -699 1264 170 -640 -3635 1655 284 -288 579 623 -186 -931 2290 -9132 -77 -2979 -4102 1766 586 1569 1573 -1094 -2282 305 -2976 1933 4692 5047 1908 5426 3075 -13243 2313 6557 2398 -1644 2271 1467 3568 847 1907 5613 6922 -569 2016 513 2628 -2652 6224 4842 -2993 6645 -3474 -2152 3679 806 5594 5874 2392 984 4229 1446 -2857 5551 1823 4668 245 -2281 -2739 4760 319 -4548 144 -3411 -3624 -6134 2737 -4233 -9700 445 1042 -120 -509 -417 2446 -2436 1334 -4055 3258 467 -5154 -4005 325 1842 -625 -3172 -2163 -5088 5512 -3059 -999 5249 1366 2387 -1222 581 -1767 2621 -3052 374 -124 4178 2592 59 4488 -252 1109 -5081 5803 -3634 9068 -4309 4205 -97 595 -135 851 3064 -130 -2419 35 -2595 1436 -1675 -4015 900000 SS 20241214T093540.9Z 9114.399779 378 1 49.95 2 73.60 157.64 106.80 352.02 0.00 1 0.00 1 0 25 1.440e-01 1.075e-02 2.014e-02 1.725e-03 4.985238e-01 1.011405e-03 6.186062e-03 -6.000000e+00 9.758011e-02 221.22 -2.00 3.66 -2.00 319.42 0.00e+00 3.041574e-03 2.710624e-04 5.267644e-04 -6.000000e+00 4.180780e-03 268.52 -2.00 20.00 -2.00 318.99 0.00e+00 3.487 0.001 302.00 328.00 3 3.3869e+00 2.7867e-03 4.1632e-02 -6.0000e+00 2.3932e-01 1.2539e-01 3.2090e-03 2.6931e-02 -6.0000e+00 2.5978e-01 -9.7467e-02 2.4562e-03 1.3492e-02 -6.0000e+00 1.5432e-01 3.5365e-02 1.2586e-03 4.6813e-03 -6.0000e+00 6.2713e-02 3.7596e-04 -1.7059e-03 6.8955e-05 8.1173e-05 -6.0000e+00 6.1115e-03 3.8947e-02 0.0000e+00 12 8 8 10 0 0 99.88 18.35 -0.04 0.03895 0.02613 129 26 1 5 0 387.140 22.40 14.99 18.35 8.11 38.30 35.60 35.4 514.64 -30429 -118004 -33207 -32847 -66212 -47790 -32425 -9735 -11272 -20121 -27999 -24580 -268 -13830 -5739 -8506 34 -1836 12617 6038 -10608 -1250 -7410 -4275 -2382 -4715 -2836 -1579 -3398 -4914 1450 -6369 1796 7480 6539 2417 7301 3232 -7064 -503 2984 -65 -643 638 1267 1856 945 1159 4863 5799 2351 3919 2019 1828 -45 2335 742 -350 2552 -20 1488 1191 436 974 1700 2243 1932 2251 609 177 -1739 -894 -363 -757 -865 -75 2003 347 -58 -2974 -1056 -1225 -1474 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