File name: Pandora106s1_Innsbruck_20250520_L2Fit_fwvt1c9d20221125p1-8.txt File generation date: 20250520T231456.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v9d20221125.txt Level 1 file used: Pandora106s1_Innsbruck_20250520_L1_smca1c9d20221125p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20250520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 "based on session5: fieldCal for IAO 2022" fieldcal Nov 2022 new refday First and last pixel inside fitting window: 1650 1798 Nominal wavelengths inside fitting window [nm]: 492.0967 492.2185 492.3402 492.4620 492.5837 492.7054 492.8271 492.9487 493.0704 493.1920 493.3137 493.4353 493.5569 493.6784 493.8000 493.9215 494.0431 494.1646 494.2861 494.4075 494.5290 494.6504 494.7719 494.8933 495.0147 495.1360 495.2574 495.3787 495.5001 495.6214 495.7427 495.8639 495.9852 496.1064 496.2277 496.3489 496.4701 496.5912 496.7124 496.8335 496.9547 497.0758 497.1969 497.3180 497.4390 497.5601 497.6811 497.8021 497.9231 498.0441 498.1650 498.2860 498.4069 498.5278 498.6487 498.7696 498.8904 499.0113 499.1321 499.2529 499.3737 499.4945 499.6153 499.7360 499.8567 499.9774 500.0981 500.2188 500.3395 500.4601 500.5808 500.7014 500.8220 500.9425 501.0631 501.1836 501.3042 501.4247 501.5452 501.6657 501.7861 501.9066 502.0270 502.1474 502.2678 502.3882 502.5085 502.6289 502.7492 502.8695 502.9898 503.1101 503.2303 503.3506 503.4708 503.5910 503.7112 503.8314 503.9515 504.0717 504.1918 504.3119 504.4320 504.5521 504.6721 504.7922 504.9122 505.0322 505.1522 505.2722 505.3921 505.5121 505.6320 505.7519 505.8718 505.9917 506.1115 506.2314 506.3512 506.4710 506.5908 506.7105 506.8303 506.9500 507.0698 507.1895 507.3091 507.4288 507.5485 507.6681 507.7877 507.9073 508.0269 508.1465 508.2660 508.3855 508.5051 508.6246 508.7440 508.8635 508.9830 509.1024 509.2218 509.3412 509.4606 509.5799 509.6993 509.8186 509.9379 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Zenith motor temperature [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250520T035644.4Z 9271.164403 144 1 4.19 2 87.23 63.09 66.10 159.00 0.00 1 0.00 1 0 22 3.900e-03 3.888e-03 2.229e-03 2.224e-03 1.299249e+04 1.702781e+02 8.640597e+02 -6.000000e+00 2.395276e+02 276.86 -2.00 20.00 -2.00 505.40 0.00e+00 2.929296e-03 6.504040e-05 1.727591e-04 -6.000000e+00 1.141677e-04 276.86 -2.00 20.00 -2.00 500.98 0.00e+00 1.254958e+00 4.620454e-02 1.008087e-01 -6.000000e+00 8.292177e-02 230.97 -2.00 3.66 -2.00 502.49 0.00e+00 14.127 0.057 489.00 513.00 1 5.3764e+00 3.5607e-03 2.2353e-02 -6.0000e+00 6.4033e-03 -4.4227e-02 8.5326e-04 2.6453e-03 -6.0000e+00 1.5886e-03 1.1996e-03 1.5945e-03 3.0247e-04 1.0913e-04 -6.0000e+00 5.9552e-04 -3.7265e-02 5.4118e-04 12 9 1 12 1 1 999.00 17.85 1.49 -0.03726 -0.02620 2 7 1 4 0 1394.510 21.98 15.00 17.85 16.50 50.10 47.10 39.2 887.80 -243 -6 -127 725 318 524 524 644 302 153 137 404 438 322 519 -62 495 -30 103 579 193 719 352 164 -317 -364 -144 -144 -37 -210 -75 -360 -716 -707 -534 -125 -113 -48 147 527 -1 127 -68 -355 -131 -59 -437 -570 -116 -578 -283 293 339 -757 -542 -240 -36 520 709 296 319 -169 -72 402 -145 78 -122 237 34 76 -240 -315 -980 -355 -239 -256 -378 -571 -499 -234 -515 -566 -53 -556 -708 -311 -500 490 444 100 -101 -10 -148 411 -117 -311 34 -679 204 -258 -565 -721 -1083 -482 -216 127 -61 206 101 96 121 473 829 536 602 398 299 147 238 640 238 103 39 363 -203 227 -125 -121 61 394 424 428 45 507 -3 259 167 302 328 585 238 -186 -678 -39 -248 -135 -104 -88 -234 -223 -6 -118 685 299 501 506 623 292 147 130 378 421 309 499 -59 475 -29 102 561 189 704 347 163 -317 -362 -141 -139 -36 -205 -74 -347 -706 -710 -541 -127 -114 -48 148 528 -1 126 -68 -361 -133 -59 -440 -566 -116 -571 -275 283 330 -757 -535 -241 -36 528 723 304 329 -175 -75 410 -148 78 -122 233 33 77 -235 -310 -976 -351 -236 -250 -377 -566 -493 -231 -512 -551 -52 -550 -705 -309 -499 485 441 101 -102 -10 -148 400 -115 -299 32 -651 193 -241 -541 -692 -1074 -486 -214 126 -61 206 102 98 125 489 862 548 620 414 312 153 246 650 240 104 39 368 -207 232 -128 -124 62 407 436 439 45 512 -3 271 173 317 349 627 258 -198 -723 -43 -266 -143 -110 -93 -248 SQ 20250520T040013.2Z 9271.166820 147 1 48.67 2 86.70 63.71 65.88 159.86 0.00 1 0.00 1 0 22 3.934e-03 3.927e-03 1.002e-03 9.994e-04 1.295225e+04 7.635655e+01 8.469402e+02 -6.000000e+00 2.415387e+02 276.86 -2.00 20.00 -2.00 505.42 0.00e+00 3.070877e-03 2.922881e-05 1.818688e-04 -6.000000e+00 1.151422e-04 276.86 -2.00 20.00 -2.00 501.04 0.00e+00 1.170639e+00 2.073981e-02 1.043050e-01 -6.000000e+00 8.366629e-02 230.97 -2.00 3.66 -2.00 502.54 0.00e+00 12.901 0.044 489.00 513.00 1 6.7595e+00 1.5970e-03 2.0557e-02 -6.0000e+00 6.4600e-03 -5.2970e-02 3.8311e-04 2.6356e-03 -6.0000e+00 1.6043e-03 3.5540e-04 1.4671e-03 1.3630e-04 1.1123e-04 -6.0000e+00 6.0057e-04 1.5740e-02 1.6561e-04 11 9 0 11 32 0 97.76 17.84 0.94 0.01574 0.02592 19 4 1 4 0 2561.430 21.98 15.00 17.84 16.73 49.60 45.90 39.0 888.14 -93 -167 149 532 709 309 458 419 95 505 326 356 407 175 318 449 212 -48 56 284 491 268 421 125 6 36 -344 -378 -292 -160 12 -142 -764 -774 -223 64 -276 55 145 245 90 134 91 140 -118 -260 -169 -266 -461 -425 -106 -90 444 -541 -684 -381 111 606 662 268 304 216 216 162 -98 -30 -175 172 69 -123 -943 -711 -617 -720 -664 -523 -608 -81 -471 -271 -160 -400 -646 -533 -267 -253 -244 121 16 -188 -223 -182 -107 53 155 -364 -189 -447 -195 -220 -709 -880 -1189 -403 -155 68 -165 258 143 -21 155 725 1150 822 735 293 266 425 392 557 588 333 373 557 303 249 434 194 130 -121 160 82 27 38 247 202 -99 328 306 221 32 -122 -98 -504 -108 -105 -48 -264 -279 -82 -151 138 505 657 293 438 402 91 478 306 331 375 161 293 419 201 -46 55 281 488 269 423 121 6 35 -345 -374 -284 -154 12 -139 -736 -759 -220 63 -273 54 143 241 90 134 93 143 -121 -266 -172 -265 -453 -410 -105 -89 440 -528 -681 -385 114 620 681 278 316 217 215 168 -101 -30 -175 170 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-6.0000e+00 3.9252e-04 2.0491e-02 1.9986e-04 11 1 0 11 32 0 97.47 17.85 0.11 0.02049 0.02480 23 5 1 4 0 2191.680 21.98 15.00 17.85 17.40 49.40 45.90 38.4 889.41 242 136 159 394 297 328 182 54 252 124 122 191 320 249 378 259 -48 -25 -88 92 153 161 198 -27 -154 -206 -300 -110 208 313 271 -34 -536 -495 -419 -220 -124 114 129 172 166 94 38 -90 -28 -448 -353 -224 -281 -96 89 165 -86 -384 -493 -299 -18 252 360 343 23 -20 -72 32 41 -48 -23 152 160 92 -312 -370 -393 -539 -415 -137 -217 38 -267 -36 -149 -269 -498 -438 -169 -82 -63 87 158 -100 -171 -196 -337 -91 -194 -175 -50 -83 212 30 -222 -739 -789 -422 -125 94 36 274 81 27 125 376 491 416 449 192 28 98 372 395 381 226 152 261 119 148 25 -143 66 -47 149 403 325 211 302 103 -79 95 238 199 -76 -124 -194 -397 -77 30 209 -45 -153 228 130 156 386 298 326 183 54 252 123 120 190 314 244 372 258 -47 -25 -90 92 154 163 201 -28 -157 -209 -302 -111 206 307 267 -34 -535 -502 -429 -225 -126 115 131 174 169 96 40 -92 -28 -457 -364 -227 -279 -96 87 160 -85 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