File name: Pandora106s1_Innsbruck_20250824_L2Fit_fout2c9d20221125p1-8.txt File generation date: 20250824T232937.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Martin Tiefengraber Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 106 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora106_OF_v2d20210701.txt Instrument calibration file used: Pandora106s1_CF_v9d20221125.txt Level 1 file used: Pandora106s1_Innsbruck_20250824_L1_smca1c9d20221125p1-8.txt Full location name: Innsbruck Atmospheric Observatory Short location name: Innsbruck Country of location: Austria Location latitude [deg]: 47.2643 Location longitude [deg]: 11.3852 Location altitude [m]: 616 Local noon date: 20250824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 "based on session5: fieldCal for IAO 2022" fieldcal Nov 2022 new refday First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0714 305.2123 305.3533 305.4943 305.6352 305.7761 305.9171 306.0580 306.1989 306.3398 306.4807 306.6215 306.7624 306.9032 307.0441 307.1849 307.3257 307.4666 307.6074 307.7481 307.8889 308.0297 308.1705 308.3112 308.4519 308.5927 308.7334 308.8741 309.0148 309.1555 309.2962 309.4368 309.5775 309.7181 309.8588 309.9994 310.1400 310.2806 310.4212 310.5618 310.7024 310.8430 310.9835 311.1241 311.2646 311.4051 311.5456 311.6861 311.8266 311.9671 312.1076 312.2481 312.3885 312.5290 312.6694 312.8098 312.9502 313.0906 313.2310 313.3714 313.5118 313.6521 313.7925 313.9328 314.0732 314.2135 314.3538 314.4941 314.6344 314.7747 314.9149 315.0552 315.1955 315.3357 315.4759 315.6161 315.7564 315.8966 316.0367 316.1769 316.3171 316.4573 316.5974 316.7375 316.8777 317.0178 317.1579 317.2980 317.4381 317.5782 317.7182 317.8583 317.9983 318.1384 318.2784 318.4184 318.5584 318.6984 318.8384 318.9784 319.1184 319.2583 319.3983 319.5382 319.6781 319.8180 319.9579 320.0978 320.2377 320.3776 320.5174 320.6573 320.7971 320.9370 321.0768 321.2166 321.3564 321.4962 321.6360 321.7758 321.9155 322.0553 322.1950 322.3347 322.4745 322.6142 322.7539 322.8936 323.0332 323.1729 323.3126 323.4522 323.5918 323.7315 323.8711 324.0107 324.1503 324.2899 324.4294 324.5690 324.7086 324.8481 324.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Zenith motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250824T051008.6Z 9367.215378 57 1 50.68 2 83.07 81.27 94.08 75.78 0.00 1 0.00 1 0 25 8.133e-01 7.422e-02 2.810e-01 1.494e-02 9.143153e-01 1.002294e-02 1.245808e-02 -6.000000e+00 5.915388e-01 230.99 -2.00 3.66 -2.00 321.68 0.00e+00 1.203414e-02 4.351659e-03 1.229080e-02 -6.000000e+00 2.711584e-02 282.23 -2.00 20.00 -2.00 321.13 0.00e+00 7.593 0.009 302.00 328.00 3 2.3691e+00 3.3134e-02 1.0463e-01 -6.0000e+00 1.4892e+00 1.7981e+00 3.8732e-02 8.5966e-02 -6.0000e+00 1.6147e+00 -1.9708e+00 2.3694e-02 3.5564e-02 -6.0000e+00 9.4258e-01 7.1829e-01 1.1769e-02 7.4443e-03 -6.0000e+00 3.7358e-01 1.1712e-05 -1.6068e-03 5.1502e-04 4.0812e-04 -6.0000e+00 3.5766e-02 4.2806e-02 0.0000e+00 12 9 8 11 32 0 39.59 17.63 0.27 0.04281 0.03073 17 3 1 5 0 2980.640 21.79 15.00 17.63 18.76 51.90 47.10 42.1 905.89 361548 900000 900000 221340 -25789 -31280 900000 900000 -74768 175819 128950 -185 900000 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1.1895e-02 6.2055e-02 -6.0000e+00 6.7550e-01 -1.3946e+00 8.0226e-03 2.7246e-02 -6.0000e+00 4.0159e-01 5.6217e-01 3.8731e-03 2.9253e-02 -6.0000e+00 1.6236e-01 7.9284e-05 -4.6583e-03 1.5554e-04 7.4304e-04 -6.0000e+00 1.5258e-02 4.1653e-02 0.0000e+00 12 8 8 10 0 0 35.65 17.65 0.35 0.04165 0.00665 73 15 1 5 0 685.920 21.88 15.00 17.65 19.70 49.40 50.60 42.0 909.30 10720 -133007 30389 -18263 -56438 -55230 -11632 108029 893 -71411 -76795 -80733 14454 29350 -7715 23558 87167 38532 153920 53297 -3053 42836 -12000 -29056 -1157 -5056 -17908 10548 -30164 -2069 20090 12261 43056 92414 115494 35410 104602 44332 -30726 29167 60514 26464 8275 35010 33790 58285 32878 41064 57268 72919 38642 43433 38257 34480 16853 39963 27603 5427 23217 4057 9205 27820 18929 26520 31572 20550 17936 23547 19905 9633 1476 9280 11743 5820 -3092 -304 7490 -863 -4628 -16045 762 -1614 -1887 1689 -3590 -7149 -1314 207 -6467 -1478 -1383 -714 -5169 -4259 -6043 -1224 -8918 -3913 -1887 212 69 727 -1871 -2306 -4784 -577 -4082 -2404 -387 -1408 2808 -1317 73 -81 1294 -379 398 156 1004 1206 1170 2475 1944 1513 228 4068 1093 2736 85 1788 1282 1527 1041 1269 307 -116 -1056 -4072 -418 357 -140 -1629 900000 284 -16506 742 -672 -2661 -2193 -255 688 14 -2156 -2573 -3340 329 761 -335 897 2182 1530 2171 2013 -173 1540 -611 -1732 -47 -200 -782 355 -1688 -104 978 759 2155 2902 2838 1917 2903 2380 -3406 2084 3332 2143 840 2836 2891 4084 3127 3812 4821 5641 4536 5198 5066 4864 2837 5237 3969 946 3349 727 1680 4658 3859 5466 6537 4900 4530 5915 5047 2893 501 2914 3459 1695 -907 -90 2031 -248 -1579 -7155 331 -803 -1025 943 -2226 -4791 -854 134 -4406 -926 -831 -416 -3205 -2833 -4654 -1043 -8660 -4022 -2012 221 69 675 -1696 -2078 -4553 -557 -4408 -2808 -493 -2015 4190 -1989 111 -122 1900 -566 600 244 1594 1925 1839 3720 3064 2313 344 5868 1676 4455 146 3368 2672 3194 2342 3024 776 -304 -2647 -10478 -1084 880 -330 -3744 900000 SS 20250824T053427.6Z 9367.232264 66 1 49.99 2 78.98 85.67 90.24 80.21 0.00 1 0.00 1 0 25 4.492e-01 1.477e-02 3.788e-02 1.620e-03 7.100817e-01 1.018100e-03 8.441649e-03 -6.000000e+00 3.155829e-01 230.99 -2.00 3.66 -2.00 320.85 0.00e+00 8.681689e-03 4.599153e-04 1.996126e-03 -6.000000e+00 1.377031e-02 282.23 -2.00 20.00 -2.00 320.29 0.00e+00 5.043 0.003 302.00 328.00 3 1.5125e+00 3.2939e-03 6.3748e-02 -6.0000e+00 7.8807e-01 2.6072e-01 4.1420e-03 4.6017e-02 -6.0000e+00 8.4784e-01 -3.3987e-01 3.5451e-03 2.0560e-02 -6.0000e+00 5.0404e-01 1.3715e-01 1.6868e-03 1.1716e-02 -6.0000e+00 2.0380e-01 4.6770e-04 -2.3510e-03 5.8573e-05 1.6020e-04 -6.0000e+00 1.9149e-02 4.1048e-02 0.0000e+00 12 8 8 10 0 0 23.82 17.65 0.18 0.04105 0.02338 231 47 1 5 0 216.390 21.79 15.00 17.65 20.90 52.60 51.60 41.6 913.38 -153541 -228366 -122406 -157676 -155621 -177871 -98144 -116842 -108630 -126535 -128277 -83303 -73799 -45899 -70029 -32224 -32296 -26506 1448 -17416 -30715 -40433 -28920 -44147 -24252 -14472 -27106 -7759 -35502 -13610 -18695 -8701 -2145 10331 12842 -1809 16393 -3262 -7169 450 9038 6437 636 8512 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