File name: Pandora246s1_IowaCityIA-WHS_20231207_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240313T201307.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20231207_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20231207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231207T135458.2Z 8741.579841 231 1 54.49 2 85.29 126.13 45.54 184.13 0.00 1 0.00 1 0 80 2.410e+00 1.574e-01 3.085e-01 1.636e-02 1.390031e+00 1.112716e-02 6.494246e-02 -6.000000e+00 1.541673e+00 222.67 -2.00 3.52 -2.00 319.44 0.00e+00 -4.759516e-01 3.305009e-03 7.771029e-02 -6.000000e+00 9.470330e-02 276.11 -2.00 20.00 -2.00 317.64 0.00e+00 10.283 0.020 302.00 328.00 3 1.0265e+00 4.0293e-02 9.9321e-01 -6.0000e+00 3.8198e+00 1.7233e+00 4.7148e-02 1.5366e+00 -6.0000e+00 4.2036e+00 -2.3509e+00 2.9082e-02 3.7727e-02 -6.0000e+00 2.4880e+00 6.0725e-01 1.6403e-02 4.9461e-01 -6.0000e+00 1.0997e+00 8.0467e-06 -3.7419e-04 3.6054e-04 4.9207e-03 -6.0000e+00 7.3800e-02 -2.7491e-02 1.0649e-04 12 8 8 10 0 0 27.75 23.79 1.75 -0.02749 -0.03030 25 2 1 5 0 2179.450 32.25 20.21 23.79 15.12 4.1 901.33 153742 140424 74039 -35825 2540 -5057 499330 900000 961945 900000 900000 900000 900000 900000 424221 900000 900000 900000 900000 -5834 900000 900000 312578 900000 750082 944465 900000 900000 900000 900000 189645 900000 900000 63004 900000 71942 271710 303544 523176 900000 900000 915969 900000 900000 900000 900000 900000 -10806 900000 900000 96093 900000 900000 276290 900000 644809 371664 -6229 900000 302806 900000 142679 900000 900000 900000 95224 900000 127634 131218 900000 176611 157239 148618 175653 102938 247481 383266 217003 54794 30444 82067 64576 19572 62872 22142 148470 53160 134438 24550 26594 56939 181984 76264 81747 78910 28614 -17500 -14268 -30121 -32032 -14644 -3491 -14085 7487 12481 14616 6593 1610 8321 11681 -1521 13133 20275 16509 22964 12880 14790 -8209 -6319 -7505 -6380 -506 -6668 -3372 12022 -12514 -3950 -8595 -22715 -14927 -16776 -15338 -7002 -1634 6003 3802 11173 9793 -1135 1019 -2480 5058 17000 6050 2658 -2109 102 -813 7888 900000 16577 900000 900000 900000 900000 900000 11575 900000 900000 900000 900000 -654 900000 900000 17955 900000 51704 23057 900000 900000 900000 900000 10077 900000 900000 4705 900000 6612 6243 14821 9767 900000 900000 14469 900000 900000 900000 900000 900000 -1257 900000 900000 5768 900000 900000 7856 900000 10186 31116 -19272 900000 14350 900000 9692 900000 900000 900000 6318 900000 9476 12851 900000 17576 22106 23946 20533 20976 9382 6054 7199 7444 5098 9593 11731 7142 17976 10843 21577 19482 19963 9501 8780 13312 13511 19275 22340 22562 12656 -11610 -9173 -22601 -23478 -8628 -1776 -8099 3903 6980 8381 4228 1149 6244 10038 -1623 14107 22768 20318 25788 14723 15398 -10456 -7930 -9398 -7494 -532 -7354 -3603 11851 -13658 -4187 -9307 -32685 -22893 -29921 -30441 -14591 -3436 13419 9403 26328 23295 -2853 2269 -5637 9908 SS 20231207T140731.5Z 8741.588559 234 1 54.88 2 83.43 128.36 45.84 188.42 0.00 1 0.00 1 0 25 5.750e-01 2.282e-02 1.963e-01 3.605e-03 8.696740e-01 2.001024e-03 1.002253e-02 -6.000000e+00 3.295715e-01 222.67 -2.00 3.52 -2.00 321.57 0.00e+00 1.473889e-02 1.012588e-03 1.447470e-03 -6.000000e+00 1.525864e-02 276.11 -2.00 20.00 -2.00 321.15 0.00e+00 7.944 0.009 302.00 328.00 3 1.8122e-01 6.8880e-03 9.0140e-02 -6.0000e+00 8.1564e-01 6.7918e-01 9.7477e-03 4.9766e-02 -6.0000e+00 8.8971e-01 -9.0371e-01 1.0253e-02 2.8401e-02 -6.0000e+00 5.2667e-01 3.8006e-01 4.8155e-03 1.7755e-02 -6.0000e+00 2.2783e-01 8.5585e-05 -1.8516e-03 9.1147e-05 2.0801e-04 -6.0000e+00 1.5837e-02 -2.8216e-02 9.7409e-05 12 8 8 10 0 0 31.18 23.85 0.63 -0.02822 -0.04213 106 10 1 5 0 517.670 32.25 20.52 23.85 16.16 4.0 909.77 -256013 -162527 -122099 -158321 -204029 -262553 -170862 900000 -69603 35132 900000 53586 -113878 900000 11656 9281 900000 130154 900000 -77701 900000 900000 -67346 17103 -80144 -60293 22725 -1882 900000 45900 -27872 124257 24479 -915 153072 -42504 -17603 -16494 5415 75354 50341 10515 47196 27593 82551 35686 49446 4190 74179 43491 19494 60685 38182 31693 46381 28319 11823 11567 23735 8041 11211 7774 23633 20498 26227 15368 13414 13982 8952 17762 8234 5479 3978 5244 -4866 3326 4252 -108 -1801 1437 1641 2329 -3701 -1328 -5217 525 -2643 2723 -1346 650 -275 1207 -4610 -3641 -3606 -3225 -2956 -741 -1557 -735 104 639 -2715 -3248 -2625 -2787 -1728 -1493 -708 -139 -130 62 499 -657 -211 -1016 724 10 497 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8.982514e-03 -6.000000e+00 3.265499e-01 222.67 -2.00 3.52 -2.00 320.87 0.00e+00 4.540038e-03 3.733432e-04 2.389701e-03 -6.000000e+00 1.423546e-02 276.11 -2.00 20.00 -2.00 320.41 0.00e+00 6.655 0.005 302.00 328.00 3 2.0086e-01 2.7265e-03 7.6198e-02 -6.0000e+00 8.0434e-01 2.3370e-01 3.7158e-03 4.1995e-02 -6.0000e+00 8.7437e-01 -2.9560e-01 3.9709e-03 2.4120e-02 -6.0000e+00 5.2062e-01 1.1752e-01 1.9508e-03 8.9946e-03 -6.0000e+00 2.2676e-01 3.2829e-04 -8.4963e-04 4.1518e-05 1.1028e-04 -6.0000e+00 1.5450e-02 -2.9032e-02 7.9620e-05 12 8 8 10 0 0 26.27 23.92 0.52 -0.02903 -0.03542 219 21 1 5 0 249.500 32.25 20.26 23.92 17.13 4.0 917.56 -259086 -218932 -180501 -190489 -217606 -253485 -200883 -91939 -148316 -145087 -56808 -116793 -129308 -26695 -51296 -51825 1114 -18695 -5796 -79627 -24358 -3386 -64237 -13707 -60970 -54660 -37506 -37525 -873 -27954 -37084 -8178 -5062 -23833 1965 -28508 -15440 -15148 -4226 5055 3452 -2250 7063 3155 14624 3579 5103 -2081 13364 8169 5233 8216 8188 4950 11090 8296 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