File name: Pandora246s1_IowaCityIA-WHS_20240214_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240313T184534.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20240214_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20240214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240214T133715.2Z 8810.567537 51 1 55.94 2 84.90 112.53 110.12 52.54 0.00 1 0.00 1 0 45 1.937e+00 2.248e-01 2.897e-01 1.860e-02 1.662419e+00 1.312444e-02 5.706385e-02 -6.000000e+00 1.204378e+00 224.71 -2.00 3.52 -2.00 318.75 0.00e+00 -4.127561e-01 2.986656e-03 5.344474e-02 -6.000000e+00 7.057384e-02 273.23 -2.00 20.00 -2.00 317.00 0.00e+00 9.705 0.017 302.00 328.00 3 3.2269e-01 4.0289e-02 7.2523e-01 -6.0000e+00 2.9672e+00 3.1219e+00 4.6713e-02 1.1428e+00 -6.0000e+00 3.2411e+00 -2.2383e+00 2.7332e-02 4.2334e-02 -6.0000e+00 1.9318e+00 2.0924e-01 1.5075e-02 3.7290e-01 -6.0000e+00 8.5586e-01 7.1361e-06 -6.5570e-03 3.1724e-04 3.7678e-03 -6.0000e+00 5.8699e-02 -2.6854e-02 2.2531e-04 12 8 8 10 0 0 23.89 23.57 1.96 -0.02685 -0.07613 21 2 1 5 0 2663.260 32.00 20.01 23.57 12.31 4.1 877.59 39300 -28214 -146592 -213873 900000 -128622 43247 303625 544633 900000 900000 900000 690960 900000 282323 351109 900000 212292 900000 -87975 900000 900000 212811 900000 490340 685221 900000 900000 900000 900000 165140 360963 900000 62406 900000 67455 359531 122896 352758 900000 900000 900000 900000 900000 900000 900000 900000 -32143 900000 900000 144392 900000 197806 202575 900000 242027 354661 -10981 392973 317681 900000 158069 454358 900000 900000 129300 900000 51475 85771 409463 140426 173441 187783 150624 118185 249474 148759 282535 141814 77232 113334 75733 75701 77514 35937 174780 81789 179181 59544 66307 29105 198759 71506 76408 128217 45068 3773 9693 -14202 -10318 8254 20026 -1764 16377 3832 5036 10527 -1472 8397 23041 686 9086 19919 18505 27150 21313 13401 -7336 -7030 -6683 -4594 -2639 -19780 -11 100 -19490 1744 -10795 -27550 -24102 -24747 -17333 -11368 -3671 -513 2492 11937 8599 4983 6269 4871 5647 4629 -2400 -19187 -30443 900000 -12416 5236 31792 44553 900000 900000 900000 27131 900000 20786 6319 900000 3821 900000 -18136 900000 900000 10097 900000 95467 62781 900000 900000 900000 900000 14590 6496 900000 5922 900000 6842 6470 24329 21354 900000 900000 900000 900000 900000 900000 900000 900000 -7310 900000 900000 7536 900000 10324 14583 900000 40944 34467 -39344 24046 20011 900000 13655 8177 900000 900000 9773 900000 11673 18523 7369 27042 27468 26698 29005 26375 11673 15528 6610 11485 11258 12850 15810 20163 24134 18950 23906 27378 20638 19611 17303 9900 12877 19303 23377 25613 20521 2505 6106 -11527 -7744 4783 9443 -959 7604 2220 3027 6138 -1022 5939 16835 694 10034 22519 22980 30961 24131 15172 -9770 -9179 -8430 -5239 -2945 -22524 -11 99 -22554 1554 -11501 -37411 -37816 -45873 -34426 -24458 -8504 -1219 6327 28500 21293 12330 15220 10679 11095 SS 20240214T134945.6Z 8810.576222 54 1 54.90 2 82.76 114.71 108.26 54.95 0.00 1 0.00 1 0 25 6.678e-01 2.325e-02 2.164e-01 3.735e-03 9.890796e-01 2.083951e-03 1.104152e-02 -6.000000e+00 3.832673e-01 224.71 -2.00 3.52 -2.00 321.70 0.00e+00 1.456911e-02 1.027926e-03 2.495319e-03 -6.000000e+00 1.642450e-02 273.23 -2.00 20.00 -2.00 321.31 0.00e+00 7.328 0.007 302.00 328.00 3 6.0602e-01 7.0854e-03 9.1753e-02 -6.0000e+00 9.5159e-01 9.3339e-01 9.9746e-03 6.4876e-02 -6.0000e+00 1.0364e+00 -1.2160e+00 1.0519e-02 2.9658e-02 -6.0000e+00 6.1475e-01 5.0077e-01 4.9699e-03 1.7975e-02 -6.0000e+00 2.6364e-01 8.0884e-05 -2.0598e-03 8.8696e-05 1.7538e-04 -6.0000e+00 1.8024e-02 -2.5434e-02 8.1850e-05 12 9 8 11 8 0 17.53 23.65 0.71 -0.02543 -0.04091 95 9 1 5 0 577.800 32.00 19.51 23.65 13.20 4.1 885.82 -199499 -153571 -174554 -183424 -93283 -185281 -201451 -198885 -171034 -87648 -25527 10273 -79395 900000 -79724 -60643 900000 4466 900000 -108218 239765 122754 -9108 900000 -108115 -43144 296487 25788 900000 99574 -38727 6366 79584 -1522 18578 2352 34165 -47300 7456 73395 49751 90882 100113 40424 58307 70372 63958 -22232 68145 53795 23933 81703 29253 27512 53128 13448 19253 8515 16574 17340 31472 16783 22648 32519 35630 18124 15534 5490 8683 18690 12489 10404 5880 3389 -2355 3059 493 2598 3206 3723 5028 3455 41 -2065 -5260 1069 -499 4023 -838 957 -2465 2890 -5976 -5639 -1213 -3528 -3642 -1208 -1847 -513 -204 451 -2854 -2791 -3824 -3239 -1828 -2828 -1332 -130 -902 -153 -167 -938 -286 165 268 -475 177 976 2048 3147 1041 1904 1627 674 2611 1242 -66 613 621 572 613 419 -190 -461 863 -27 -969 -533 -705 -1629 -5543 -3099 -4504 -4732 -833 -3739 -4598 -4408 -2885 -702 -111 37 -982 900000 -1828 -1412 900000 68 900000 -5355 872 536 -146 900000 -4642 -958 1079 272 900000 616 -1254 164 1158 -52 480 68 771 -2754 296 1736 1629 2083 2186 1633 1994 2202 2234 -1974 2653 2662 1811 3894 2576 2663 4137 1581 2130 1007 1707 1722 2829 1979 2975 4508 5134 3126 2837 1185 2047 4577 3513 3032 1707 914 -592 649 105 591 877 1256 1821 1475 20 -1078 -3006 603 -297 2322 -501 534 -1325 1409 -3224 -3363 -827 -2735 -3391 -1191 -1999 -542 -214 411 -2399 -2363 -3506 -3103 -1848 -2944 -1570 -178 -1325 -241 -269 -1499 -438 247 412 -776 282 1660 3273 4663 1514 2659 2211 968 3656 1834 -110 1184 1265 1267 1370 1010 -467 -1174 2183 -68 -2447 -1319 -1598 -3640 SS 20240214T140022.9Z 8810.583598 57 1 54.61 2 80.97 116.60 106.65 56.95 0.00 1 0.00 1 0 17 6.857e-01 1.509e-02 5.605e-02 1.627e-03 8.603030e-01 8.635371e-04 9.850722e-03 -6.000000e+00 3.890458e-01 224.71 -2.00 3.52 -2.00 320.97 0.00e+00 6.745418e-03 3.696400e-04 2.066353e-03 -6.000000e+00 1.663863e-02 273.23 -2.00 20.00 -2.00 320.56 0.00e+00 6.045 0.004 302.00 328.00 3 5.7964e-01 2.6754e-03 7.4067e-02 -6.0000e+00 9.6352e-01 3.2632e-01 3.7035e-03 4.6187e-02 -6.0000e+00 1.0466e+00 -4.2184e-01 4.0641e-03 2.7805e-02 -6.0000e+00 6.2119e-01 1.6981e-01 1.9857e-03 1.2331e-02 -6.0000e+00 2.6859e-01 3.4368e-04 -8.5730e-04 3.8771e-05 1.3639e-04 -6.0000e+00 1.8286e-02 -2.6053e-02 8.3885e-05 12 8 8 10 0 0 17.91 23.72 0.52 -0.02605 -0.03249 214 21 1 5 0 255.150 32.25 19.74 23.72 13.97 4.1 890.95 -254279 -238075 -235924 -240731 -193434 -242455 -237948 -222726 -219696 -188107 -154852 -110188 -145116 -47396 -104003 -69458 27549 -45285 -21274 -105599 -7984 -12798 -63844 -17286 -82938 -60313 -20318 -33659 -12238 -18698 -43795 -14469 -5029 -19557 -11300 -29128 -1317 -27077 -10437 6645 6980 15544 16528 5141 10399 9674 10347 -6258 13986 11108 7706 18903 8801 8378 14082 3564 6499 6942 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