File name: Pandora246s1_IowaCityIA-WHS_20240221_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240313T183220.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20240221_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20240221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240221T151334.8Z 8817.634430 305 1 3.30 2 67.51 129.38 112.66 344.07 0.00 1 0.00 1 0 17 2.414e-02 6.707e-03 1.100e-02 3.053e-03 3.851048e-01 1.537966e-03 4.674825e-03 -6.000000e+00 1.371464e-02 225.02 -2.00 3.52 -2.00 317.41 0.00e+00 9.396679e-04 2.220582e-04 9.012667e-05 -6.000000e+00 5.868841e-04 273.70 -2.00 20.00 -2.00 316.86 0.00e+00 2.593 0.000 302.00 328.00 3 2.8264e+00 4.0296e-03 3.1928e-02 -6.0000e+00 3.3985e-02 2.5238e-02 4.5190e-03 1.9610e-02 -6.0000e+00 3.6901e-02 -2.8399e-02 2.8099e-03 9.8001e-03 -6.0000e+00 2.1902e-02 1.0639e-02 1.4397e-03 2.9421e-03 -6.0000e+00 9.4719e-03 1.5486e-03 -4.8263e-04 8.3177e-05 3.1275e-05 -6.0000e+00 6.4365e-04 -3.0544e-02 1.6905e-06 12 9 1 12 1 1 29.95 24.41 0.38 -0.03054 -0.03417 6 11 1 5 0 471.260 32.50 19.83 24.41 20.84 4.0 944.21 -8952 -7120 -10340 -11629 -10317 -4775 -6504 1144 -6129 -3162 -6197 -4010 -4409 -2432 -1390 -1179 1964 108 785 -157 1551 678 1561 3103 -551 1064 332 -2060 2196 1289 804 3270 1932 -2108 -2678 -1787 -407 552 -838 -77 -392 -680 -89 -482 1013 595 559 -226 -1025 423 1228 1000 462 524 1483 703 256 323 -182 738 1239 1070 1766 1367 -33 -167 212 -350 527 770 466 83 -115 -448 -1083 456 -275 63 -381 -856 -821 -1497 -2307 -1534 -1272 -1007 -620 549 -213 333 549 412 113 668 427 208 513 421 -175 -358 -626 85 222 127 -947 -959 -708 -617 140 100 121 -214 330 142 523 662 434 452 2 -520 -181 638 663 371 5 344 1250 877 91 363 -224 356 258 -40 -252 -377 214 -33 -112 -505 -480 -505 -790 -686 -1063 -1136 -894 -383 -572 106 -680 -359 -731 -497 -646 -382 -255 -242 418 23 174 -37 362 159 376 790 -155 306 96 -575 559 341 237 977 648 -705 -903 -597 -139 221 -365 -39 -205 -375 -48 -262 544 323 301 -122 -560 236 735 619 307 353 1024 503 179 223 -129 516 858 810 1402 1125 -28 -135 162 -271 427 682 431 77 -109 -404 -934 377 -211 48 -317 -758 -792 -1501 -2399 -1664 -1431 -1167 -726 650 -253 385 603 431 114 682 463 238 638 550 -235 -478 -801 102 259 152 -1198 -1234 -955 -853 200 147 183 -329 499 207 720 895 597 637 3 -786 -272 951 959 528 7 471 1632 1200 130 544 -348 554 414 -66 -423 -644 370 -59 -196 -873 -813 -839 SS 20240221T160010.9Z 8817.666793 338 1 0.75 2 61.31 140.07 114.27 355.01 0.00 1 0.00 1 0 17 1.355e-02 7.257e-03 8.955e-03 4.351e-03 3.063279e-01 2.196438e-03 3.739134e-03 -6.000000e+00 7.701264e-03 225.02 -2.00 3.52 -2.00 316.24 0.00e+00 1.673775e-04 2.380536e-04 5.437243e-05 -6.000000e+00 3.294994e-04 273.71 -2.00 20.00 -2.00 315.73 0.00e+00 2.074 0.000 302.00 328.00 3 2.4254e+00 5.6645e-03 2.5433e-02 -6.0000e+00 1.9084e-02 2.1939e-02 6.3196e-03 1.5484e-02 -6.0000e+00 2.0718e-02 -1.4361e-02 3.6929e-03 7.7109e-03 -6.0000e+00 1.2296e-02 4.1828e-03 1.7676e-03 2.2275e-03 -6.0000e+00 5.3209e-03 4.2334e-03 9.3060e-05 1.1903e-04 2.5548e-05 -6.0000e+00 3.6118e-04 -3.1768e-02 1.1458e-04 12 9 1 12 1 1 999.00 24.55 0.30 -0.03177 -0.03107 2 21 1 5 0 248.170 32.75 20.00 24.55 21.55 4.0 951.10 -2479 -4075 -5368 -4780 -1508 -4166 -4138 -2011 472 -2630 -2067 -1603 386 2252 1175 120 1363 -243 2389 2192 885 3462 745 440 -707 524 -454 -1678 3420 390 3180 1014 1040 -747 -526 -2341 -215 404 -275 -539 -644 -639 -989 -1334 -595 -30 -1413 -137 979 153 701 238 582 140 645 1038 776 1053 957 -116 1905 862 1376 453 -213 49 -1164 69 -280 279 177 96 -269 194 87 -1263 21 375 457 -1050 -321 -1183 -1710 -2050 -1225 -718 -456 454 682 194 1204 911 1286 192 94 448 654 -215 -340 -669 -654 -498 290 -31 -1168 -740 -852 -617 224 404 -345 -37 418 -4 108 841 383 921 613 -301 -53 -149 52 291 618 273 1038 266 422 559 142 -448 192 -30 380 -566 805 -443 -251 -216 -378 -891 -458 -838 -1142 -941 -256 -763 -751 -404 103 -577 -448 -362 98 607 346 39 464 -83 828 789 327 1236 282 168 -289 220 -191 -668 1285 152 1230 439 465 -346 -227 -1020 -101 202 -160 -335 -418 -433 -665 -906 -400 -20 -940 -92 642 103 484 171 427 109 497 815 621 832 739 -90 1509 723 1214 416 -194 43 -988 58 -247 261 174 95 -264 186 82 -1107 18 307 390 -974 -313 -1212 -1818 -2297 -1389 -844 -547 553 824 229 1361 997 1335 201 104 519 805 -274 -454 -866 -825 -587 333 -36 -1486 -959 -1131 -839 314 579 -513 -56 604 -6 146 1101 498 1227 862 -430 -76 -214 74 402 827 358 1322 345 566 784 205 -654 285 -45 592 -908 1302 -727 -408 -345 -593 -1376 SS 20240221T162700.6Z 8817.685424 351 1 54.63 2 58.32 146.87 114.48 1.43 0.00 1 0.00 1 0 17 1.014e-02 5.533e-03 1.933e-03 8.142e-04 2.846496e-01 4.113819e-04 3.513166e-03 -6.000000e+00 5.765008e-03 225.02 -2.00 3.52 -2.00 316.50 0.00e+00 2.998556e-04 4.774833e-05 4.940298e-05 -6.000000e+00 2.466619e-04 273.71 -2.00 20.00 -2.00 315.98 0.00e+00 1.897 0.000 302.00 328.00 3 3.8526e+00 1.0661e-03 2.3494e-02 -6.0000e+00 1.4286e-02 3.1482e-02 1.1899e-03 1.4526e-02 -6.0000e+00 1.5509e-02 -8.6782e-03 7.0253e-04 7.2529e-03 -6.0000e+00 9.2051e-03 -8.7489e-04 3.4269e-04 2.1052e-03 -6.0000e+00 3.9828e-03 1.2334e-03 -1.9746e-04 2.2522e-05 2.4087e-05 -6.0000e+00 2.7039e-04 -3.1059e-02 1.2556e-04 10 0 0 10 0 0 99.99 24.62 0.34 -0.03106 -0.03254 273 27 1 5 0 200.100 32.75 19.96 24.62 22.29 4.0 958.50 -3598 -2111 -1846 -5371 -2030 -3013 -1876 -445 -2366 -1139 -1163 -153 -795 987 -76 -587 1836 242 1038 128 494 1496 798 1353 3 105 463 28 883 1708 157 1879 1376 -1405 -888 -1931 -1098 -1195 -582 -652 -1051 -734 -741 -606 120 -260 -368 -818 -321 603 404 833 735 465 951 934 516 228 402 533 1174 1252 1490 877 -67 -50 -385 132 576 325 239 -23 78 -88 -307 131 -394 -40 -4 -722 -688 -1449 -1789 -1356 -1067 -531 -504 283 108 164 323 408 421 637 534 333 487 225 -232 -460 -300 -234 91 -207 -942 -790 -690 -460 48 280 238 103 268 -5 289 455 282 337 121 -311 -185 246 49 334 512 53 938 993 351 406 -38 27 -41 132 -6 -304 225 8 -328 -279 -442 -528 -549 -347 -309 -864 -281 -447 -268 -70 -425 -212 -214 -29 -172 243 -20 -170 542 75 335 43 168 500 276 495 1 39 171 11 307 589 59 698 559 -597 -349 -760 -473 -563 -328 -399 -657 -477 -495 -406 80 -173 -240 -525 -202 381 273 601 528 354 740 742 418 183 315 416 947 1031 1334 795 -60 -43 -315 106 501 305 231 -23 77 -88 -282 113 -330 -32 -3 -641 -685 -1522 -1901 -1505 -1212 -641 -610 349 133 200 378 435 434 651 589 390 606 297 -307 -591 -374 -279 108 -249 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