File name: Pandora246s1_IowaCityIA-WHS_20240222_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240313T183146.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20240222_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20240222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240222T141732.8Z 8818.595518 291 1 26.39 2 75.94 117.91 106.97 320.13 0.00 1 0.00 1 0 25 3.612e-01 9.516e-03 2.452e-02 1.237e-03 7.121873e-01 6.358957e-04 8.296272e-03 -6.000000e+00 2.053038e-01 225.06 -2.00 3.52 -2.00 319.80 0.00e+00 2.723942e-03 1.932501e-04 4.681111e-04 -6.000000e+00 8.786017e-03 273.77 -2.00 20.00 -2.00 319.32 0.00e+00 4.026 0.001 302.00 328.00 3 1.4556e+00 1.7905e-03 5.3732e-02 -6.0000e+00 5.0878e-01 1.0562e-01 2.1750e-03 3.6825e-02 -6.0000e+00 5.5239e-01 -1.3128e-01 2.0406e-03 1.9353e-02 -6.0000e+00 3.2786e-01 5.0371e-02 1.0746e-03 6.8220e-03 -6.0000e+00 1.4179e-01 1.0599e-03 -6.3240e-04 3.0543e-05 6.5375e-05 -6.0000e+00 9.6312e-03 -2.8670e-02 1.1168e-04 12 9 9 12 1 1 82.13 24.23 0.39 -0.02867 -0.03342 104 21 1 5 0 251.230 32.50 19.87 24.23 19.50 4.0 932.89 -153442 -128890 -121816 -134299 -114013 -143984 -120615 -103413 -111020 -86564 -88505 -62831 -62562 -36470 -43456 -30138 -2647 -22989 -14999 -27139 -11010 -10416 -19234 -9482 -26394 -20175 -14336 -16206 -9494 -7652 -15573 -3937 831 -6075 -3870 -6550 -3066 -3153 -2890 1624 1772 2477 3124 2629 4047 3836 2835 973 3895 3842 3593 2752 3541 2807 3244 1907 1497 300 -3 929 1371 1674 3458 2675 1838 1599 368 320 681 1373 729 496 111 -184 -784 -1118 -1583 -1358 -1194 -1101 -709 -1486 -2113 -1730 -1442 -585 -340 58 542 669 514 191 -76 -28 -139 -256 108 185 -346 -452 -460 -337 -70 -691 -1337 -1127 -651 -304 -183 224 105 225 457 308 374 544 389 250 44 -170 42 431 277 437 376 318 1115 939 382 382 33 71 -52 -159 -254 -433 299 -62 -227 -135 -403 -427 -2850 -2207 -2101 -2543 -1623 -2761 -2007 -1659 -2182 -1451 -1612 -1038 -1343 -792 -1295 -952 -72 -862 -564 -1218 -429 -404 -868 -428 -1528 -1163 -792 -885 -485 -430 -1163 -316 74 -618 -368 -643 -326 -366 -414 267 326 486 641 554 854 764 588 215 888 953 1010 809 1136 991 1207 750 563 121 -1 355 545 688 1607 1320 952 811 190 173 388 895 491 344 75 -116 -477 -652 -884 -790 -752 -780 -553 -1263 -1863 -1606 -1359 -580 -335 58 557 652 488 172 -67 -27 -142 -279 131 235 -473 -603 -588 -398 -79 -811 -1628 -1378 -839 -405 -260 333 167 363 752 486 576 808 591 386 73 -274 68 684 425 665 550 464 1579 1392 608 661 58 129 -98 -309 -515 -910 633 -129 -478 -276 -792 -810 SS 20240222T142723.7Z 8818.602358 294 1 54.62 2 74.32 119.78 108.11 322.12 0.00 1 0.00 1 0 25 2.307e-01 8.031e-03 7.483e-03 4.920e-04 6.480251e-01 2.506503e-04 7.650431e-03 -6.000000e+00 1.310956e-01 225.06 -2.00 3.52 -2.00 319.37 0.00e+00 1.616561e-03 6.600887e-05 3.581389e-04 -6.000000e+00 5.611638e-03 273.77 -2.00 20.00 -2.00 318.87 0.00e+00 3.636 0.001 302.00 328.00 3 8.0667e-01 6.9180e-04 4.8683e-02 -6.0000e+00 3.2487e-01 7.3860e-02 8.1339e-04 3.3342e-02 -6.0000e+00 3.5278e-01 -9.3104e-02 6.9811e-04 1.7065e-02 -6.0000e+00 2.0939e-01 3.4839e-02 3.7452e-04 5.3302e-03 -6.0000e+00 9.0513e-02 3.1350e-03 -1.0655e-03 1.2422e-05 5.4415e-05 -6.0000e+00 6.1547e-03 -2.7766e-02 1.5643e-05 11 8 0 10 0 0 99.46 24.25 0.34 -0.02777 -0.03577 602 59 1 5 0 90.720 32.50 20.03 24.25 19.54 4.0 936.10 -92478 -76994 -76597 -78001 -86067 -85216 -86258 -67004 -67804 -64442 -57060 -50124 -42829 -24704 -21071 -14291 -6781 -11493 -7251 -11270 -6919 -7268 -8999 -5635 -9023 -10821 -8600 -8315 -8106 -6319 -6319 -812 295 -1896 -4415 -4474 -3663 -2398 -149 1348 1176 1520 1763 2232 2696 2435 2087 1455 1578 2382 2651 2374 2365 2199 1629 1694 869 524 284 527 1440 1617 2403 1886 1087 898 339 404 665 657 501 164 139 -104 -693 -591 -1187 -922 -754 -1140 -698 -1559 -2018 -1624 -1195 -773 -576 13 306 339 528 233 247 299 27 -167 353 116 -360 -424 -456 -345 -33 -491 -1232 -932 -758 -404 -28 116 177 183 413 209 443 607 470 343 -8 -234 -38 434 411 357 507 195 1133 887 278 356 46 85 -8 -135 -283 -396 252 -59 -274 -265 -319 -384 -1792 -1489 -1580 -1572 -1726 -1693 -1904 -1402 -1627 -1623 -1410 -1332 -1348 -833 -861 -651 -323 -635 -415 -707 -424 -449 -601 -401 -720 -931 -732 -681 -655 -551 -602 -87 36 -251 -570 -581 -529 -411 -28 301 294 374 454 582 708 656 576 419 476 769 889 891 972 919 723 782 415 248 130 238 671 785 1319 1096 656 526 198 246 428 461 364 123 102 -75 -480 -366 -741 -560 -523 -849 -572 -1397 -1880 -1591 -1196 -785 -609 14 323 354 509 220 227 289 29 -188 424 154 -492 -564 -579 -420 -38 -572 -1505 -1189 -986 -544 -39 174 282 294 654 325 667 907 716 533 -12 -375 -60 682 625 537 731 279 1617 1278 432 597 79 151 -15 -254 -554 -787 505 -121 -550 -515 -611 -712 SS 20240222T143351.9Z 8818.606851 298 1 54.67 2 73.28 121.04 108.83 323.45 0.00 1 0.00 1 0 25 1.722e-01 7.832e-03 4.015e-03 3.293e-04 6.119084e-01 1.670572e-04 7.265713e-03 -6.000000e+00 9.784170e-02 225.06 -2.00 3.52 -2.00 319.09 0.00e+00 1.735134e-03 4.022399e-05 3.119613e-04 -6.000000e+00 4.187668e-03 273.77 -2.00 20.00 -2.00 318.58 0.00e+00 3.423 0.001 302.00 328.00 3 2.6577e-01 4.5627e-04 4.5867e-02 -6.0000e+00 2.4247e-01 6.2469e-02 5.2777e-04 3.1396e-02 -6.0000e+00 2.6328e-01 -8.3296e-02 4.2471e-04 1.5996e-02 -6.0000e+00 1.5626e-01 3.2031e-02 2.2949e-04 5.0477e-03 -6.0000e+00 6.7561e-02 6.8410e-03 -8.6188e-04 8.3960e-06 5.1031e-05 -6.0000e+00 4.5920e-03 -2.8305e-02 4.4485e-05 11 8 0 10 0 0 98.17 24.27 0.34 -0.02831 -0.03478 1083 106 1 5 0 50.470 32.50 19.77 24.27 20.08 4.1 942.05 -67405 -56514 -56386 -56475 -64556 -67550 -58082 -53035 -53334 -46681 -44963 -39956 -32157 -20164 -15719 -10359 -5835 -5962 -3960 -6232 -4037 -4637 -5280 -4229 -5240 -5883 -6057 -7313 -6902 -4987 -2727 356 1033 -913 -3238 -3784 -2144 -1332 468 913 969 1210 1659 1951 2468 1917 1792 1280 1090 1757 1704 1843 1972 1917 1738 1537 809 439 158 538 1227 1649 2321 1817 878 852 231 527 746 473 501 59 103 -87 -507 -557 -1080 -838 -673 -943 -809 -1574 -2157 -1874 -1396 -755 -539 31 210 261 420 158 236 150 16 -66 408 90 -321 -433 -485 -311 14 -398 -1147 -932 -802 -425 10 143 131 176 332 266 450 734 494 410 10 -284 -82 418 401 479 550 331 1108 967 357 349 97 159 -56 -169 -279 -367 201 -52 -316 -257 -404 -445 -1558 -1357 -1443 -1389 -1575 -1690 -1447 -1439 -1646 -1457 -1447 -1396 -1310 -928 -863 -638 -384 -433 -303 -468 -332 -385 -424 -369 -498 -595 -620 -729 -675 -521 -331 49 164 -142 -535 -632 -361 -267 105 242 286 353 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