File name: Pandora246s1_IowaCityIA-WHS_20240314_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240315T062112.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20240314_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20240314 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240314T200050.0Z 8839.833912 324 1 56.01 2 49.86 215.51 32.81 116.66 0.00 1 0.00 1 0 58 7.240e-01 2.440e-01 5.785e-02 1.027e-02 5.882379e-01 5.358357e-03 1.818809e-02 -6.000000e+00 4.210583e-01 225.99 -2.00 3.52 -2.00 317.17 0.00e+00 -1.411130e-01 6.941175e-04 8.730879e-03 -6.000000e+00 1.787590e-02 275.20 -2.00 20.00 -2.00 316.53 0.00e+00 1.548 0.000 302.00 328.00 3 8.0719e+00 1.4321e-02 7.7907e-02 -6.0000e+00 1.0460e+00 2.6718e-01 1.6178e-02 1.6078e-01 -6.0000e+00 1.1273e+00 8.2965e-02 1.0220e-02 5.8699e-02 -6.0000e+00 6.6845e-01 -1.9368e-01 5.1161e-03 1.0425e-01 -6.0000e+00 2.9892e-01 2.2442e-05 2.0932e-02 2.0302e-04 9.2122e-04 -6.0000e+00 1.9402e-02 -7.5315e-02 4.5083e-03 12 8 8 10 0 0 99.08 24.70 2.23 -0.07531 0.08198 14 1 2 5 0 4000.000 32.75 20.02 24.70 23.24 4.0 965.88 900000 900000 -166333 -233941 -98823 -177154 -134679 61738 40146 173371 280131 257264 132763 209347 9592 -30666 54856 -41406 -60615 -118317 -50059 -54428 -29528 55227 106693 161439 202272 185099 234617 85028 -14620 15337 -9749 -43694 -5807 -28332 -8100 8608 44045 98533 108554 115187 122462 86785 54935 22586 3435 -30171 -1029 -2286 -17285 1267 -3570 17913 46754 54415 76359 -76007 87661 55497 32676 8799 7461 -1173 1693 -9991 12269 5846 2005 13764 18067 23214 27927 32223 26334 31680 26753 22646 6498 -5061 7478 1237 4321 6631 2855 22095 9858 16961 2706 2543 1165 18530 11166 13719 18427 3871 -4199 -2615 -7869 -6025 -7214 -3015 -7339 -4649 -7814 -4318 -5802 -8635 -3109 -415 -993 1260 7493 4250 10934 8973 6930 -5927 -1821 -4699 -5232 -6431 -10262 -4304 -4650 -10103 -2336 -6779 -6114 -4301 -4635 -728 2791 5491 5127 2786 9035 6311 735 996 -4183 -2444 900000 900000 -17258 -40455 -4254 -19155 -18203 3029 6029 13886 11779 13908 16615 6916 1517 -5710 3680 -6384 -10620 -36720 -8369 -10953 -6770 11390 29588 43639 41514 34097 14798 13450 -4245 2748 -2186 -14392 -1302 -8226 -2344 3094 18652 39163 53579 59390 52842 41531 26784 11577 1685 -17429 -415 -964 -9500 670 -2273 10903 26634 33875 47745 -187791 53798 37226 21853 6030 5080 -885 1214 -7402 7702 4143 1536 11137 16065 21360 25112 26864 21259 23026 17677 13943 4496 -4150 6057 1117 4263 6971 3402 23166 12005 19095 3359 2921 1244 17383 11000 13323 17876 4132 -5094 -3323 -10850 -7853 -8857 -3268 -7935 -5170 -9822 -5471 -7694 -12221 -4406 -623 -1624 2095 11635 6509 14500 11286 8654 -8550 -2632 -7194 -7938 -9529 -15317 -5802 -5972 -12929 -2613 -8132 -7941 -5950 -6872 -1085 4208 8656 8796 5139 15970 11585 1395 1778 -7420 -4057 SS 20240314T201902.4Z 8839.846556 340 1 54.64 2 51.96 220.72 29.88 122.20 0.00 1 0.00 1 0 17 8.240e-03 5.622e-03 2.667e-04 1.413e-04 2.869632e-01 7.183511e-05 3.520905e-03 -6.000000e+00 4.700318e-03 225.99 -2.00 3.52 -2.00 315.95 0.00e+00 2.189350e-04 7.328161e-06 3.974375e-05 -6.000000e+00 2.016086e-04 275.20 -2.00 20.00 -2.00 315.43 0.00e+00 1.619 0.000 302.00 328.00 3 7.0665e-01 1.8503e-04 2.1599e-02 -6.0000e+00 1.1667e-02 1.1528e-02 2.0602e-04 1.4577e-02 -6.0000e+00 1.2656e-02 -1.2547e-02 1.1944e-04 7.2567e-03 -6.0000e+00 7.5125e-03 2.2204e-03 5.6271e-05 2.0795e-03 -6.0000e+00 3.2466e-03 3.7097e-02 -1.0250e-04 3.8750e-06 2.4469e-05 -6.0000e+00 2.1975e-04 -2.8713e-02 1.2952e-04 10 0 0 10 0 0 99.99 24.76 0.34 -0.02871 -0.02948 3145 307 1 5 0 17.370 32.75 20.00 24.76 23.75 3.9 967.77 -1597 -1109 -1703 -2993 -2621 -1968 -1062 -278 -236 -1623 -1799 -1049 -990 -374 251 -292 358 626 981 1068 669 1122 1384 875 581 580 54 -85 134 1118 1129 1788 1191 -1100 -1471 -1266 -1202 -505 -346 -629 -908 -656 -769 -475 -113 -403 -452 -404 -434 510 697 553 791 692 734 953 551 446 485 717 1188 1194 1385 716 -357 -78 -325 324 691 132 137 -155 25 37 -93 90 -184 102 -6 -670 -814 -1581 -1907 -1394 -1051 -682 -482 0 117 101 328 138 573 756 469 289 630 259 -289 -379 -369 -303 177 -92 -879 -697 -669 -420 29 134 107 28 166 120 345 659 425 460 231 -231 -197 179 208 373 535 260 1019 912 373 283 -18 78 -51 -14 -134 -287 219 -51 -313 -309 -465 -543 -342 -258 -405 -669 -519 -375 -215 -63 -55 -402 -441 -266 -285 -115 83 -106 135 231 376 424 270 446 566 360 253 262 24 -36 56 460 471 807 557 -534 -666 -600 -597 -265 -209 -404 -609 -457 -551 -341 -81 -287 -316 -276 -304 346 504 413 600 554 582 771 455 364 387 569 975 1024 1249 667 -330 -68 -275 280 605 128 135 -158 25 36 -87 81 -156 83 -5 -632 -808 -1639 -2041 -1557 -1224 -800 -592 0 142 119 375 152 599 784 511 332 761 330 -376 -489 -464 -358 205 -110 -1092 -905 -887 -568 40 190 156 41 236 165 456 849 556 618 319 -330 -284 251 289 505 705 334 1279 1153 499 396 -26 111 -75 -20 -205 -448 348 -81 -507 -482 -715 -821 SS 20240314T202317.5Z 8839.849508 343 1 54.64 2 52.48 221.89 29.22 123.61 0.00 1 0.00 1 0 17 8.597e-03 5.606e-03 2.915e-04 1.504e-04 2.910043e-01 7.643865e-05 3.570412e-03 -6.000000e+00 4.904087e-03 225.99 -2.00 3.52 -2.00 316.04 0.00e+00 2.058568e-04 7.928684e-06 4.145421e-05 -6.000000e+00 2.103490e-04 275.20 -2.00 20.00 -2.00 315.51 0.00e+00 1.638 0.000 302.00 328.00 3 8.0202e-01 1.9683e-04 2.1883e-02 -6.0000e+00 1.2173e-02 1.0229e-02 2.1920e-04 1.4788e-02 -6.0000e+00 1.3204e-02 -1.2698e-02 1.2764e-04 7.3602e-03 -6.0000e+00 7.8382e-03 2.3771e-03 6.0391e-05 2.1101e-03 -6.0000e+00 3.3873e-03 3.2915e-02 -1.0426e-04 4.1206e-06 2.4913e-05 -6.0000e+00 2.2928e-04 -2.8703e-02 1.2939e-04 10 0 0 10 0 0 100.00 24.76 0.35 -0.02870 -0.02949 3134 306 1 5 0 17.430 32.75 20.00 24.76 23.79 4.0 969.42 -1789 -1335 -1759 -3361 -2749 -2340 -1412 -394 -465 -1557 -1947 -1165 -1046 -233 388 -215 281 683 1053 1175 672 1146 1361 869 671 553 120 -99 165 1082 1209 1795 1150 -1173 -1472 -1258 -1196 -506 -390 -599 -833 -673 -763 -490 -116 -399 -406 -412 -440 500 661 594 792 712 752 997 589 413 481 708 1178 1176 1375 682 -371 -89 -313 355 656 115 136 -171 33 56 -94 62 -157 83 3 -704 -771 -1556 -1907 -1421 -1037 -683 -459 3 106 85 323 161 592 737 471 260 610 267 -282 -368 -366 -288 142 -73 -846 -709 -689 -425 19 154 118 22 149 139 342 636 432 451 239 -215 -234 192 230 364 516 246 1043 912 364 279 -16 46 -46 -21 -136 -282 220 -43 -319 -299 -447 -544 -353 -286 -386 -695 -545 -447 -286 -82 -108 -383 -476 -295 -279 -71 127 -73 99 250 400 461 268 451 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