File name: Pandora246s1_IowaCityIA-WHS_20240518_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240519T060747.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20240518_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20240518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240518T112953.9Z 8904.479096 139 1 55.20 2 82.91 69.86 122.81 305.68 0.00 1 0.00 1 0 33 7.864e-01 2.867e-02 2.487e-01 5.721e-03 9.975100e-01 3.488450e-03 1.134313e-02 -6.000000e+00 4.767775e-01 231.18 -2.00 3.52 -2.00 321.96 0.00e+00 1.483308e-02 1.939510e-03 1.128945e-03 -6.000000e+00 2.357970e-02 282.35 -2.00 20.00 -2.00 321.53 0.00e+00 7.444 0.008 302.00 328.00 3 1.0940e+00 1.2904e-02 9.2620e-02 -6.0000e+00 1.2021e+00 1.2637e+00 1.6858e-02 6.2534e-02 -6.0000e+00 1.3086e+00 -1.6712e+00 1.4808e-02 2.8632e-02 -6.0000e+00 7.6942e-01 6.8322e-01 6.9785e-03 1.7726e-02 -6.0000e+00 3.2581e-01 3.9548e-05 -2.5156e-03 1.4515e-04 2.3217e-04 -6.0000e+00 2.2707e-02 -2.6336e-02 1.0685e-04 12 8 8 10 0 0 28.06 24.78 0.76 -0.02634 -0.04524 51 5 1 5 0 1082.240 32.75 20.00 24.78 30.39 3.7 1018.87 -136122 -64611 67298 -120095 -61565 -54992 -86152 900000 213477 -58307 900000 -85183 900000 900000 900000 900000 900000 156959 900000 -42833 88679 900000 -4092 900000 -96238 -21455 900000 900000 900000 900000 -56484 900000 110472 32911 900000 39678 232253 28907 74557 209091 120244 900000 230793 479590 900000 158837 55952 54604 104219 177837 41408 169926 58777 33073 77565 67348 26602 68624 55832 41436 53328 45393 49770 42423 41130 23352 54391 9480 16270 30992 9968 15487 12612 14667 -12112 6475 15748 -11743 1110 1629 11420 7551 883 4633 -4277 5754 -4192 4621 -5486 1379 -5073 9585 -4556 -5064 647 -3280 -6405 -1153 -2981 -2736 241 -738 -2944 -3786 -5449 -5194 -2832 -4663 -668 1110 -2195 -1385 1038 -1115 -479 -1252 59 -139 960 1296 2785 2896 940 1880 3448 2899 2187 568 -106 362 761 935 723 1012 -73 -726 826 -330 -884 1 -1685 -1620 -7633 -1958 544 -5582 -1306 -945 -1872 900000 1186 -854 900000 -1807 900000 900000 900000 900000 900000 1047 900000 -2095 1084 900000 -109 900000 -6097 -620 900000 900000 900000 900000 -3076 900000 1596 1061 900000 1014 1291 964 1823 1511 2272 900000 1539 2665 900000 2207 2239 2337 2896 2570 2623 3305 3756 2922 4526 4379 2572 4157 3599 2970 3497 3607 4425 4692 4914 3322 5803 1681 3020 5684 2432 3623 2888 2975 -2820 1108 2372 -2525 252 455 3459 2757 378 2016 -1960 2509 -2094 2148 -2785 622 -2271 3888 -2147 -2405 346 -2211 -5346 -1075 -2845 -2589 223 -605 -2204 -2877 -4518 -4524 -2580 -4379 -692 1326 -3117 -1954 1465 -1587 -655 -1695 81 -203 1460 1985 4013 4240 1350 2587 4530 3724 2804 825 -170 677 1483 1981 1539 2312 -182 -1883 2126 -866 -2275 3 -3722 -3521 SS 20240518T114033.9Z 8904.486504 142 1 54.84 2 81.02 71.54 124.38 308.13 0.00 1 0.00 1 0 17 6.526e-01 1.905e-02 1.060e-01 2.295e-03 8.469436e-01 1.250580e-03 1.017476e-02 -6.000000e+00 3.796134e-01 231.18 -2.00 3.52 -2.00 321.13 0.00e+00 7.966240e-03 5.819566e-04 5.118688e-03 -6.000000e+00 1.644962e-02 282.35 -2.00 20.00 -2.00 320.61 0.00e+00 6.071 0.004 302.00 328.00 3 1.1032e+00 4.1168e-03 7.7369e-02 -6.0000e+00 9.5163e-01 3.9272e-01 5.6625e-03 5.1815e-02 -6.0000e+00 1.0272e+00 -5.4916e-01 5.7070e-03 2.9527e-02 -6.0000e+00 6.0976e-01 2.2508e-01 2.7250e-03 1.0657e-02 -6.0000e+00 2.6219e-01 1.9319e-04 -8.1401e-04 5.5583e-05 1.6950e-04 -6.0000e+00 1.7433e-02 -2.7156e-02 1.1760e-04 12 8 8 10 0 0 17.54 24.84 0.57 -0.02716 -0.03327 127 12 1 5 0 431.770 32.75 20.00 24.84 30.96 3.7 1023.31 -293739 -198683 -169493 -237116 -227613 -227327 -228304 -76358 -204181 -189885 -52457 -193568 -96341 7460 -60688 -50920 -27824 -56389 -17768 -92678 -38038 98608 -63159 -4017 -93683 -57328 10950 -38123 117487 -1527 -58336 16897 -1194 -13843 1479 -28146 9246 -16281 7488 25752 15732 22282 26440 38322 30240 14984 9793 10285 15843 25996 9407 23027 15690 16409 18085 15232 5326 -427 5956 7294 11128 11339 12217 10466 11324 8373 8129 4331 4600 5858 3794 5738 2541 3330 -2942 1057 -923 -3992 -1705 -969 491 -303 -2284 -1859 -3007 97 -1064 227 -783 -270 -1101 58 -2614 -2845 -906 -1745 -1557 -261 -466 -1243 -761 -855 -1396 -2078 -2407 -2369 -1235 -1626 -150 106 405 119 497 -92 -5 441 465 510 482 706 1068 1450 945 1057 1451 573 1487 933 511 444 218 286 -3 -45 -257 -440 508 -266 -535 -340 -662 -751 -9202 -2829 -2124 -5065 -4380 -4222 -4496 -359 -3746 -3187 -235 -4245 -1078 40 -842 -786 -392 -1186 -274 -3152 -749 485 -1625 -61 -3668 -1616 157 -870 578 -29 -2467 416 -41 -576 50 -1272 319 -860 380 1291 972 1381 1657 2187 1908 1140 817 909 1425 2327 1133 2731 2208 2504 2865 2573 1012 -84 1058 1260 1942 2230 2527 2527 2861 2161 2148 1265 1519 2208 1589 2419 1068 1281 -1078 334 -287 -1373 -679 -467 253 -182 -1525 -1311 -2116 70 -812 174 -601 -196 -751 40 -1859 -2035 -744 -1596 -1678 -300 -579 -1531 -859 -917 -1373 -2112 -2642 -2550 -1403 -2026 -194 158 637 188 788 -152 -8 672 728 842 793 1178 1708 2321 1466 1579 2216 854 2168 1419 863 811 443 591 -7 -102 -595 -1060 1227 -655 -1294 -768 -1459 -1622 SS 20240518T115216.6Z 8904.494637 147 1 54.63 2 78.94 73.37 126.04 310.92 0.00 1 0.00 1 0 17 4.540e-01 9.917e-03 2.861e-02 1.036e-03 7.299124e-01 5.508728e-04 8.406619e-03 -6.000000e+00 2.641114e-01 231.18 -2.00 3.52 -2.00 320.32 0.00e+00 2.553798e-03 2.045129e-04 1.449379e-03 -6.000000e+00 1.144381e-02 282.35 -2.00 20.00 -2.00 319.74 0.00e+00 5.026 0.002 302.00 328.00 3 7.9724e-01 1.6526e-03 6.2883e-02 -6.0000e+00 6.6209e-01 1.1732e-01 2.1034e-03 3.9450e-02 -6.0000e+00 7.1460e-01 -1.6358e-01 2.0308e-03 2.0611e-02 -6.0000e+00 4.2421e-01 6.0732e-02 1.0266e-03 6.7096e-03 -6.0000e+00 1.8244e-01 8.0660e-04 -3.3347e-04 2.5863e-05 7.4797e-05 -6.0000e+00 1.2126e-02 -2.7852e-02 1.3304e-04 12 8 8 10 0 0 -0.09 24.91 0.44 -0.02785 -0.03036 298 29 1 5 0 183.300 32.75 20.00 24.91 31.57 3.7 1027.23 -202108 -158318 -145700 -170870 -161265 -161471 -152329 -82378 -108166 -134518 -83445 -119235 -84036 -60450 -53503 -34187 -24786 -38289 -25720 -48026 -32931 -23709 -35582 -17774 -43971 -34169 -16666 -22057 -6894 -17765 -24511 -7344 -6646 -11429 -7065 -13782 -10546 -7991 -2635 5 714 4193 2269 5032 4652 3460 1862 651 2426 4809 2355 5577 4611 4434 4624 4423 1809 2557 2187 1548 2769 3999 3787 4070 3008 2671 1679 1025 1360 1716 1008 597 195 115 -1169 -1124 -1372 -1817 -1381 -1508 -976 -1650 -2203 -1606 -1248 -541 -270 402 182 380 234 112 -341 -383 -371 -232 178 274 -249 -265 -573 -627 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