File name: Pandora246s1_IowaCityIA-WHS_20240610_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20240611T061114.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20240610_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20240610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240610T143516.7Z 8927.607833 5 1 54.67 2 47.37 96.08 88.31 62.46 0.00 1 0.00 1 0 17 7.910e-03 5.827e-03 1.400e-04 8.935e-05 2.458623e-01 4.676949e-05 2.988439e-03 -6.000000e+00 4.627865e-03 232.56 -2.00 3.52 -2.00 315.30 0.00e+00 1.771590e-04 4.209608e-06 2.684492e-05 -6.000000e+00 2.014304e-04 284.71 -2.00 20.00 -2.00 314.66 0.00e+00 1.474 0.000 302.00 328.00 3 -2.9824e-02 1.2119e-04 1.9506e-02 -6.0000e+00 1.1632e-02 1.3564e-02 1.3388e-04 1.2867e-02 -6.0000e+00 1.2533e-02 -8.2762e-03 7.6750e-05 6.2608e-03 -6.0000e+00 7.4420e-03 -2.5695e-04 3.4748e-05 1.7284e-03 -6.0000e+00 3.2011e-03 9.4618e-02 -1.9527e-04 2.4562e-06 2.1356e-05 -6.0000e+00 2.1134e-04 -3.4618e-02 6.4610e-05 10 0 0 10 0 0 16.39 23.73 0.35 -0.03462 -0.03609 4260 416 1 5 0 12.830 31.25 20.01 23.73 31.06 3.6 1022.63 -1009 -757 -1467 -2800 -2470 -1839 -666 331 216 -1096 -1320 -557 -550 -17 465 -233 320 578 1001 1171 644 1172 1486 958 707 435 32 -31 262 1346 1436 1823 1177 -1166 -1436 -1261 -1232 -437 -251 -720 -981 -790 -915 -682 -244 -548 -616 -521 -581 384 670 555 835 645 659 937 528 374 472 682 1141 1146 1380 661 -444 -145 -433 264 736 105 110 -128 60 108 -81 79 -186 63 72 -661 -782 -1556 -1898 -1353 -1048 -696 -448 -3 126 86 355 138 596 846 461 327 645 306 -233 -331 -300 -270 206 -41 -881 -707 -694 -486 9 143 116 36 182 124 362 648 403 457 208 -230 -243 129 184 355 543 222 1041 955 383 283 -45 60 -59 -43 -137 -317 204 -70 -303 -272 -444 -535 -287 -233 -460 -825 -682 -485 -185 96 70 -354 -420 -180 -200 -7 195 -102 144 256 459 554 311 556 721 472 352 224 16 -15 127 635 687 935 629 -620 -739 -641 -663 -263 -162 -507 -726 -606 -700 -523 -185 -416 -471 -386 -435 287 512 440 676 534 560 808 451 317 403 579 974 1026 1301 629 -428 -134 -384 228 667 103 111 -131 63 107 -78 72 -163 54 62 -617 -777 -1629 -2059 -1495 -1215 -823 -544 -3 155 103 407 151 623 868 497 372 762 384 -300 -421 -370 -320 238 -48 -1086 -893 -900 -643 12 199 166 51 255 167 464 803 507 592 281 -318 -340 180 249 474 701 279 1289 1187 494 381 -63 82 -83 -61 -203 -474 311 -108 -464 -411 -659 -780 SS 20240610T144027.0Z 8927.611424 8 1 54.67 2 46.41 97.05 87.49 63.28 0.00 1 0.00 1 0 17 7.801e-03 5.812e-03 1.357e-04 8.787e-05 2.416010e-01 4.596524e-05 2.938093e-03 -6.000000e+00 4.565044e-03 232.56 -2.00 3.52 -2.00 315.25 0.00e+00 1.799144e-04 4.077913e-06 2.543939e-05 -6.000000e+00 1.986808e-04 284.71 -2.00 20.00 -2.00 314.61 0.00e+00 1.448 0.000 302.00 328.00 3 -3.1692e-02 1.1907e-04 1.9164e-02 -6.0000e+00 1.1474e-02 1.3663e-02 1.3150e-04 1.2640e-02 -6.0000e+00 1.2362e-02 -8.1855e-03 7.5390e-05 6.1512e-03 -6.0000e+00 7.3402e-03 -3.8887e-04 3.4079e-05 1.7001e-03 -6.0000e+00 3.1585e-03 9.7902e-02 -2.0728e-04 2.4103e-06 2.0936e-05 -6.0000e+00 2.0838e-04 -3.6200e-02 9.4353e-05 10 0 0 10 0 0 28.00 24.25 0.36 -0.03620 -0.03776 4300 420 1 5 0 12.710 32.25 20.01 24.25 31.33 3.6 1026.04 -982 -750 -1311 -2779 -2433 -1711 -571 350 271 -948 -1330 -485 -486 80 568 -183 286 572 988 1218 680 1187 1509 879 560 540 -7 11 272 1332 1392 1739 1257 -1146 -1480 -1216 -1237 -448 -267 -703 -996 -781 -909 -695 -247 -527 -609 -495 -561 405 669 571 832 651 692 953 540 389 465 699 1161 1155 1317 717 -399 -132 -413 239 732 122 125 -171 33 108 -78 75 -160 46 68 -644 -764 -1525 -1906 -1362 -1039 -686 -467 -20 82 98 319 134 572 794 482 291 631 329 -214 -316 -319 -250 159 -13 -866 -697 -687 -483 11 135 145 46 177 139 348 643 383 475 220 -216 -261 133 201 346 570 237 1011 946 403 288 -45 61 -86 -24 -142 -316 212 -81 -301 -261 -437 -553 -291 -241 -406 -858 -704 -471 -165 106 86 -319 -441 -163 -173 31 234 -79 127 262 468 569 324 556 722 447 288 287 -4 5 129 646 683 876 659 -624 -781 -632 -679 -265 -176 -505 -753 -594 -710 -544 -192 -408 -460 -374 -414 298 504 447 684 547 579 811 469 335 392 586 1005 1048 1226 692 -380 -120 -361 209 668 118 128 -178 33 108 -76 70 -137 39 59 -605 -763 -1605 -2081 -1514 -1186 -817 -570 -25 100 118 370 148 603 819 521 332 748 413 -276 -404 -388 -291 180 -15 -1072 -884 -894 -642 15 188 208 66 245 188 448 798 481 615 296 -298 -365 182 273 455 738 298 1228 1176 519 387 -60 85 -119 -34 -210 -473 323 -124 -462 -394 -649 -807 SS 20240610T144533.8Z 8927.614975 11 1 54.66 2 45.46 98.02 86.67 64.08 0.00 1 0.00 1 0 17 7.677e-03 5.803e-03 1.316e-04 8.643e-05 2.375649e-01 4.522937e-05 2.890169e-03 -6.000000e+00 4.493203e-03 232.56 -2.00 3.52 -2.00 315.18 0.00e+00 1.801558e-04 3.979942e-06 2.502190e-05 -6.000000e+00 1.955439e-04 284.71 -2.00 20.00 -2.00 314.55 0.00e+00 1.424 0.000 302.00 328.00 3 -3.3237e-02 1.1709e-04 1.8845e-02 -6.0000e+00 1.1294e-02 1.3439e-02 1.2920e-04 1.2432e-02 -6.0000e+00 1.2166e-02 -7.9616e-03 7.4088e-05 6.0497e-03 -6.0000e+00 7.2241e-03 -4.3591e-04 3.3455e-05 1.6726e-03 -6.0000e+00 3.1093e-03 1.0110e-01 -1.8208e-04 2.3726e-06 2.0709e-05 -6.0000e+00 2.0505e-04 -3.7250e-02 1.1398e-04 10 0 0 10 0 0 18.19 24.62 0.36 -0.03725 -0.03862 4386 428 1 5 0 12.460 32.50 20.00 24.62 31.82 3.6 1029.42 -928 -716 -1215 -2699 -2321 -1588 -569 327 357 -919 -1228 -442 -447 26 540 -209 342 613 1015 1194 615 1175 1471 833 573 500 11 21 253 1303 1383 1681 1292 -1080 -1494 -1256 -1253 -480 -342 -725 -993 -789 -892 -694 -237 -558 -630 -515 -570 398 666 595 766 658 679 961 553 394 499 709 1134 1167 1330 716 -405 -136 -390 227 728 135 122 -148 23 122 -79 82 -155 51 87 -652 -782 -1509 -1894 -1378 -1033 -696 -483 0 103 95 332 123 551 770 478 300 628 351 -198 -317 -328 -263 137 -9 -847 -695 -691 -496 9 140 151 48 172 123 338 639 396 477 225 -210 -255 129 196 332 558 236 971 953 431 306 -24 59 -100 -16 -140 -290 196 -67 -312 -266 -442 -550 -286 -225 -390 -865 -655 -452 -170 102 117 -320 -420 -153 -164 10 229 -92 156 288 471 572 301 565 720 415 301 261 6 11 123 617 692 862 689 -598 -803 -663 -698 -288 -229 -528 -739 -608 -685 -535 -186 -438 -483 -395 -426 296 506 470 618 558 574 824 484 343 424 599 989 1067 1247 696 -389 -126 -342 199 667 131 125 -154 24 124 -75 76 -134 43 76 -613 -782 -1589 -2070 -1533 -1179 -829 -592 0 126 115 385 136 582 794 515 342 742 440 -255 -405 -397 -307 156 -10 -1047 -881 -897 -659 13 195 216 68 237 166 433 790 495 615 301 -289 -356 176 266 435 720 297 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