File name: Pandora246s1_IowaCityIA-WHS_20241204_L2Fit_fwvt1c2d20230109p1-8.txt File generation date: 20241205T062908.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20241204_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20241204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.0802 492.2014 492.3225 492.4437 492.5648 492.6859 492.8070 492.9281 493.0491 493.1702 493.2912 493.4122 493.5332 493.6542 493.7751 493.8961 494.0170 494.1379 494.2588 494.3797 494.5005 494.6214 494.7422 494.8630 494.9838 495.1046 495.2253 495.3461 495.4668 495.5875 495.7082 495.8289 495.9495 496.0702 496.1908 496.3114 496.4320 496.5526 496.6731 496.7937 496.9142 497.0347 497.1552 497.2757 497.3961 497.5166 497.6370 497.7574 497.8778 497.9982 498.1185 498.2389 498.3592 498.4795 498.5998 498.7201 498.8403 498.9606 499.0808 499.2010 499.3212 499.4414 499.5615 499.6817 499.8018 499.9219 500.0420 500.1621 500.2821 500.4022 500.5222 500.6422 500.7622 500.8822 501.0021 501.1221 501.2420 501.3619 501.4818 501.6017 501.7215 501.8414 501.9612 502.0810 502.2008 502.3205 502.4403 502.5600 502.6798 502.7995 502.9192 503.0388 503.1585 503.2781 503.3977 503.5173 503.6369 503.7565 503.8761 503.9956 504.1151 504.2346 504.3541 504.4736 504.5930 504.7125 504.8319 504.9513 505.0707 505.1900 505.3094 505.4287 505.5480 505.6673 505.7866 505.9059 506.0251 506.1443 506.2636 506.3828 506.5019 506.6211 506.7403 506.8594 506.9785 507.0976 507.2167 507.3357 507.4548 507.5738 507.6928 507.8118 507.9308 508.0498 508.1687 508.2876 508.4065 508.5254 508.6443 508.7632 508.8820 509.0008 509.1196 509.2384 509.3572 509.4760 509.5947 509.7134 509.8321 509.9508 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241204T152645.4Z 9104.643581 118 1 1.00 2 72.82 143.88 102.19 115.15 0.00 1 0.00 1 0 15 2.218e-03 2.222e-03 2.756e-04 2.753e-04 2.260698e+03 1.646685e+01 1.620814e+02 -6.000000e+00 1.240887e+02 276.33 -2.00 20.00 -2.00 505.28 0.00e+00 3.484250e-04 7.562571e-06 2.251241e-05 -6.000000e+00 6.213359e-05 276.33 -2.00 20.00 -2.00 500.52 0.00e+00 1.844182e-01 5.484670e-03 1.850647e-02 -6.000000e+00 4.459946e-02 222.70 -2.00 3.52 -2.00 502.10 0.00e+00 3.337 0.001 489.00 513.00 1 1.1822e+00 4.2040e-04 4.9293e-03 -6.0000e+00 3.4199e-03 -3.2239e-04 1.0732e-04 5.0172e-04 -6.0000e+00 8.7897e-04 3.7060e-01 2.1421e-03 3.0095e-05 2.1593e-05 -6.0000e+00 2.5001e-04 -3.4102e-02 9.3894e-05 12 1 1 12 1 1 96.62 24.00 1.63 -0.03410 -0.01924 94 55 1 4 0 10.450 32.25 20.58 24.00 12.01 2.9 864.13 -61 -97 -3 -133 -113 302 468 305 178 124 137 -23 -200 -65 -63 -179 -224 60 -93 -276 10 175 127 318 195 115 213 133 -350 -223 30 -141 72 418 -156 -457 -122 12 -59 81 249 130 138 185 192 168 130 206 70 -238 -365 -404 -436 -100 11 -153 -289 -251 -118 172 372 449 232 236 134 56 20 28 -109 -213 -119 -164 -199 -10 -140 -389 -287 -52 -79 -244 -233 -334 -406 24 -44 -307 -286 -170 -88 55 226 396 325 -62 71 123 -13 -55 -51 -202 -402 -364 -131 -119 -470 -274 -97 -101 77 187 24 31 244 201 255 379 352 271 280 357 277 178 295 158 -120 98 231 171 328 117 -255 -167 -17 -177 -74 143 -282 -441 -187 -105 -49 137 294 193 134 -75 -194 -211 32 20 -59 -95 -3 -134 -115 310 483 318 186 128 140 -24 -202 -65 -63 -179 -226 61 -96 -286 10 181 132 331 204 120 220 137 -358 -224 30 -140 73 426 -162 -475 -127 13 -60 83 254 132 142 190 199 174 134 211 71 -239 -360 -394 -424 -97 11 -153 -292 -256 -120 175 378 457 235 240 135 56 20 27 -107 -209 -116 -160 -196 -10 -138 -385 -280 -50 -76 -235 -225 -326 -395 23 -43 -304 -284 -168 -87 55 225 395 327 -62 71 122 -13 -53 -49 -193 -382 -349 -128 -117 -469 -274 -97 -99 75 184 24 31 245 204 258 384 358 275 282 357 276 176 291 156 -119 98 229 169 323 115 -249 -162 -17 -170 -71 138 -277 -437 -186 -105 -49 137 295 194 135 -75 -192 -206 32 19 SQ 20241204T153431.3Z 9104.648973 124 1 5.95 2 71.99 145.55 100.92 116.27 0.00 1 0.00 1 0 15 2.047e-03 2.051e-03 1.616e-04 1.615e-04 2.162670e+03 9.635325e+00 1.586389e+02 -6.000000e+00 1.145146e+02 276.33 -2.00 20.00 -2.00 505.27 0.00e+00 3.093654e-04 4.431312e-06 2.004746e-05 -6.000000e+00 5.734946e-05 276.33 -2.00 20.00 -2.00 500.50 0.00e+00 1.719501e-01 3.216125e-03 1.657612e-02 -6.000000e+00 4.118606e-02 222.70 -2.00 3.52 -2.00 502.08 0.00e+00 3.191 0.001 489.00 513.00 1 1.9339e+00 2.4648e-04 4.6849e-03 -6.0000e+00 3.1578e-03 3.3011e-03 6.3003e-05 4.6674e-04 -6.0000e+00 8.1237e-04 1.7861e-01 3.3939e-03 1.7641e-05 2.1277e-05 -6.0000e+00 2.3074e-04 -3.0159e-02 1.1482e-05 10 0 0 10 0 0 99.96 24.01 1.64 -0.03016 -0.00662 522 51 1 4 0 11.380 32.50 19.93 24.01 12.17 3.0 866.36 -62 -51 -21 -116 -103 351 398 221 157 116 168 -25 -159 -8 -67 -243 -152 64 -84 -271 13 115 83 252 224 97 178 82 -309 -160 77 -139 139 390 -171 -488 -137 16 -54 81 247 189 122 172 138 126 124 140 36 -246 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-125 -41 147 288 186 97 -65 -184 -86 63 51 SQ 20241204T153437.4Z 9104.649044 124 2 5.95 2 71.98 145.57 100.91 116.28 0.00 1 0.00 1 0 15 2.071e-03 2.074e-03 1.830e-04 1.828e-04 2.162334e+03 1.090842e+01 1.579475e+02 -6.000000e+00 1.158542e+02 276.33 -2.00 20.00 -2.00 505.27 0.00e+00 2.994453e-04 5.019212e-06 1.956584e-05 -6.000000e+00 5.801824e-05 276.33 -2.00 20.00 -2.00 500.49 0.00e+00 1.784430e-01 3.645827e-03 1.676875e-02 -6.000000e+00 4.166129e-02 222.70 -2.00 3.52 -2.00 502.08 0.00e+00 3.189 0.001 489.00 513.00 1 2.1800e+00 2.7945e-04 4.6856e-03 -6.0000e+00 3.1943e-03 3.9885e-03 7.1372e-05 4.6898e-04 -6.0000e+00 8.2157e-04 1.3963e-01 3.1209e-03 1.9975e-05 2.1184e-05 -6.0000e+00 2.3345e-04 -3.1354e-02 3.2835e-05 10 0 0 10 0 0 99.74 24.01 1.65 -0.03135 -0.00971 522 51 1 4 0 11.380 32.50 20.37 24.01 12.17 3.0 866.36 -65 -78 29 -99 -94 342 423 230 121 80 166 -4 -179 -34 -44 -191 -135 53 -70 -304 -7 124 83 203 247 72 181 111 -294 -153 84 -108 132 427 -186 -487 -138 35 -88 58 248 153 152 120 126 95 140 152 20 -264 -355 -391 -322 -54 57 -173 -271 -246 -139 122 376 363 204 222 130 54 33 75 -115 -234 -22 -115 -211 -15 -106 -403 -212 17 -61 -172 -184 -360 -355 49 -85 -357 -249 -117 -2 22 204 399 229 -62 80 168 1 -18 -41 -165 -337 -342 -119 -122 -487 -284 -19 -39 120 150 -58 42 197 196 219 303 334 246 194 385 278 143 279 107 -223 55 155 156 278 152 -235 -109 -5 -231 -30 195 -248 -470 -216 -100 -72 163 268 171 96 -59 -233 -115 114 84 -63 -77 28 -100 -97 352 437 240 126 82 171 -4 -182 -34 -44 -192 -137 53 -73 -316 -8 130 87 213 259 76 188 114 -299 -154 84 -107 134 439 -194 -506 -142 36 -90 58 255 156 157 124 131 98 143 156 20 -263 -349 -382 -312 -53 57 -174 -274 -251 -142 124 382 370 206 227 131 54 33 74 -113 -229 -21 -113 -208 -14 -105 -396 -208 17 -59 -166 -176 -349 -347 48 -83 -350 -245 -115 -2 22 203 397 230 -63 79 166 1 -17 -39 -157 -322 -329 -116 -120 -489 -285 -19 -38 118 147 -58 42 198 197 221 307 339 249 195 385 275 141 275 106 -220 54 152 155 274 149 -230 -106 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