File name: Pandora246s1_IowaCityIA-WHS_20241217_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20241218T061018.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20241217_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20241217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241217T141744.6Z 9117.595655 302 1 54.57 2 83.27 129.78 75.49 290.93 0.00 1 0.00 1 0 25 6.677e-01 2.678e-02 2.205e-01 4.752e-03 9.293753e-01 2.677777e-03 1.066909e-02 -6.000000e+00 3.835606e-01 222.64 -2.00 3.52 -2.00 321.72 0.00e+00 1.935796e-02 1.340127e-03 1.210781e-03 -6.000000e+00 1.718157e-02 275.02 -2.00 20.00 -2.00 321.33 0.00e+00 7.788 0.009 302.00 328.00 3 6.0885e-01 9.1759e-03 9.2157e-02 -6.0000e+00 9.4793e-01 1.0681e+00 1.2020e-02 6.0026e-02 -6.0000e+00 1.0338e+00 -1.3777e+00 1.1607e-02 2.7618e-02 -6.0000e+00 6.1224e-01 5.6703e-01 5.5946e-03 2.0598e-02 -6.0000e+00 2.6383e-01 5.4230e-05 -2.4695e-03 1.1798e-04 2.4750e-04 -6.0000e+00 1.8405e-02 -3.5458e-02 9.3887e-05 12 8 8 10 0 0 17.48 23.78 0.78 -0.03546 -0.05402 69 7 1 5 0 790.840 32.25 20.75 23.78 9.93 3.0 848.21 -168119 -79499 5378 -101556 -22050 -146509 -112861 900000 -28123 87922 154686 -113142 -43146 900000 4370 29914 900000 107603 900000 -93925 -1918 900000 -67392 900000 -69183 -42147 900000 -17340 900000 185575 -12377 441430 113344 -9689 67559 -31950 37133 -2842 33985 111160 52007 181917 103232 147869 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-1981 -1959 -790 -2396 -4315 -91 -4015 887 -780 2258 -3134 -3706 -4099 -3816 -3414 -3005 -1878 360 -876 -389 995 -4032 -570 -70 1257 -651 53 1645 4485 4568 2080 3075 3916 1049 3753 1728 -58 994 1222 2377 2057 1263 -605 -1274 2208 -1167 -2838 -1128 -3323 -2326 SS 20241217T142835.2Z 9117.603185 305 1 54.50 2 81.73 131.76 77.32 292.46 0.00 1 0.00 1 0 25 6.474e-01 1.632e-02 1.069e-01 2.120e-03 8.171397e-01 1.122689e-03 9.460433e-03 -6.000000e+00 3.648743e-01 222.64 -2.00 3.52 -2.00 321.04 0.00e+00 7.496964e-03 4.937768e-04 2.141858e-03 -6.000000e+00 1.583274e-02 275.02 -2.00 20.00 -2.00 320.61 0.00e+00 6.536 0.005 302.00 328.00 3 6.6589e-01 3.5492e-03 7.6355e-02 -6.0000e+00 8.9906e-01 3.0889e-01 4.9589e-03 4.3889e-02 -6.0000e+00 9.7716e-01 -3.9994e-01 5.3898e-03 2.7172e-02 -6.0000e+00 5.8144e-01 1.6055e-01 2.6191e-03 1.2431e-02 -6.0000e+00 2.5335e-01 2.1382e-04 -9.3543e-04 5.1696e-05 1.3605e-04 -6.0000e+00 1.7245e-02 -3.5875e-02 1.1284e-04 12 8 8 10 0 0 9.82 23.81 0.56 -0.03588 -0.04290 153 15 1 5 0 356.170 32.25 19.38 23.81 10.75 3.0 855.14 -284297 -204619 -162638 -243565 -163613 -266910 -224106 -60047 -199401 -161591 -132035 -169539 -154871 18716 -87052 -58613 73419 -34420 44770 -116418 -4104 38187 -83205 -9249 -84507 -75019 -11677 -52066 39079 -29231 -48003 395 8185 -30813 -9736 -32980 -19009 -14988 -9855 10696 8028 23976 19142 13140 21333 15139 7622 3332 19220 15806 6145 16768 11345 5660 15344 10845 1250 -1143 5960 5536 9340 8951 6607 12110 8425 6191 6968 3625 3477 6416 3821 3552 1407 2619 -608 -981 -116 -490 -1321 -433 110 -443 -2597 -2485 -3113 -440 -1153 -169 -589 -556 -1160 -217 -1560 -1397 -884 -1113 -1142 -89 -976 10 -416 -138 -900 -1165 -2052 -1763 -1910 -1164 -169 67 2 257 583 -487 143 382 704 249 114 325 699 1152 569 835 1733 79 1579 943 367 268 440 356 30 -97 -364 -486 491 -163 -574 -271 -480 -533 -6250 -2664 -1513 -4933 -1353 -6013 -3474 -199 -2926 -1737 -1119 -2488 -2657 77 -1367 -860 334 -519 333 -4548 -53 316 -2408 -138 -2829 -2388 -200 -1313 404 -689 -1736 11 249 -1484 -362 -1534 -849 -762 -583 615 533 1462 1298 975 1490 1167 662 322 1704 1594 777 2159 1705 986 2572 1975 256 -236 1101 1010 1716 1861 1495 2988 2294 1712 1947 1110 1202 2493 1666 1600 628 1069 -230 -334 -38 -169 -542 -197 59 -276 -1671 -1692 -2277 -332 -915 -135 -471 -424 -828 -145 -1053 -1016 -746 -1037 -1171 -105 -1177 13 -485 -152 -907 -1199 -2142 -1930 -2229 -1470 -223 96 3 414 942 -773 228 590 1108 391 189 550 1136 1870 897 1267 2519 112 2324 1439 622 492 851 740 64 -219 -844 -1174 1190 -384 -1397 -619 -1068 -1107 SS 20241217T143959.1Z 9117.611100 308 1 54.53 2 80.17 133.88 79.23 294.09 0.00 1 0.00 1 0 25 4.803e-01 1.189e-02 5.227e-02 1.496e-03 7.238639e-01 7.763417e-04 8.407970e-03 -6.000000e+00 2.707316e-01 222.64 -2.00 3.52 -2.00 320.44 0.00e+00 4.558396e-03 2.902164e-04 1.086621e-03 -6.000000e+00 1.174723e-02 275.02 -2.00 20.00 -2.00 319.97 0.00e+00 5.602 0.003 302.00 328.00 3 1.0289e+00 2.3035e-03 6.5771e-02 -6.0000e+00 6.6709e-01 1.6723e-01 2.9763e-03 3.7861e-02 -6.0000e+00 7.2501e-01 -1.9652e-01 3.0405e-03 2.1472e-02 -6.0000e+00 4.3140e-01 7.3200e-02 1.5419e-03 8.8321e-03 -6.0000e+00 1.8800e-01 3.8850e-04 -6.2088e-04 3.7336e-05 8.7734e-05 -6.0000e+00 1.2794e-02 -3.6822e-02 1.1265e-04 12 8 8 10 0 0 70.71 23.87 0.42 -0.03682 -0.04149 175 17 1 5 0 311.550 32.25 20.06 23.87 11.71 3.0 863.66 -225655 -166220 -159837 -161490 -149564 -201120 -166790 -7033 -154463 -119322 -105274 -101960 -92954 -17963 -49632 -43504 -6530 -27426 2835 -71858 -35002 3765 -54358 -12421 -43024 -37892 -14148 -30291 -6395 -19042 -29899 -715 -1988 -17740 -3290 -16042 -11942 -9684 -2062 1433 4330 7692 4549 7521 7407 6179 2143 -775 8496 6102 3088 9559 6948 4244 8273 4236 171 991 2097 4075 5077 3721 4973 5804 3826 3066 2443 1924 541 1701 816 93 -448 -83 -1309 -1414 -1542 -973 -1784 -1903 76 -1520 -2519 -1839 -1922 -411 -470 -64 -128 134 291 256 -583 -498 -93 -369 -286 378 -389 -277 -328 -86 -422 -684 -1434 -1325 -932 -564 -45 356 188 153 352 -91 148 568 685 289 -57 12 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