File name: Pandora246s1_IowaCityIA-WHS_20250126_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20250127T062341.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20250126_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20250126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250126T143655.5Z 9157.608976 127 1 54.59 2 79.06 127.26 72.78 164.55 0.00 1 0.00 1 0 33 1.232e+00 1.088e-01 2.104e-01 5.172e-03 9.493811e-01 2.857184e-03 1.379657e-02 -6.000000e+00 7.262786e-01 224.00 -2.00 3.52 -2.00 320.78 0.00e+00 -1.792427e-01 9.262464e-04 3.441992e-02 -6.000000e+00 3.582577e-02 273.26 -2.00 20.00 -2.00 320.18 0.00e+00 5.083 0.002 302.00 328.00 3 4.0281e+00 8.8487e-03 3.1991e-01 -6.0000e+00 1.8120e+00 4.6260e-01 1.2048e-02 4.8700e-01 -6.0000e+00 1.9888e+00 -1.0631e+00 1.2273e-02 7.9385e-02 -6.0000e+00 1.1670e+00 4.1133e-01 6.0590e-03 2.1551e-01 -6.0000e+00 4.9246e-01 4.2428e-05 -1.3260e-03 1.3307e-04 1.2468e-03 -6.0000e+00 3.4694e-02 -3.0269e-02 6.5767e-05 12 8 8 10 0 0 97.30 23.16 0.53 -0.03027 -0.04023 14 1 1 5 0 3898.690 31.75 20.57 23.16 2.84 3.0 788.94 -30455 85642 93761 -63885 119853 -102424 99626 900000 312538 457050 900000 900000 475412 900000 245956 900000 900000 900000 900000 -46811 900000 900000 91262 900000 253310 370145 900000 356580 900000 299640 66642 212644 156321 21248 900000 39350 193037 91929 196380 330449 283415 330328 248340 206569 194360 112563 110099 1468 99921 60007 17852 88180 54642 61026 113261 116897 133225 -58385 135786 106258 66723 44186 42079 32150 18556 -920 23620 11452 16542 42474 33159 35605 38555 47043 35115 40681 35588 29306 -169 -6270 -4919 166 552 9029 4931 18203 9062 11643 143 -1059 146 12634 13069 14301 12720 1587 -11521 -14129 -18748 -18367 -14777 -11937 -9507 -2916 -3381 -2099 -2506 -4576 -2040 -275 -159 3476 8174 8429 10055 9392 5466 1200 -1303 -1045 -1400 543 -162 2833 5265 -10 682 -1595 -5143 -6937 -5683 -3858 -2578 114 2941 2427 4215 3513 -2 -259 -2706 -2325 -1183 744 557 -1402 603 -4729 1640 900000 5187 3448 900000 900000 2391 900000 2226 900000 900000 900000 900000 -3413 900000 900000 4268 900000 15159 10238 900000 5738 900000 2110 3351 2139 2751 1464 900000 2414 3398 7397 10172 7312 13255 9801 13113 11323 8113 7585 5814 198 4975 4919 2648 7716 7969 10527 15664 21692 26598 -63286 22603 17046 12046 8911 8697 7615 4955 -259 5999 3440 5717 13690 13507 15366 16287 17227 12811 13216 10864 8946 -63 -2740 -2478 96 370 6200 3559 12205 6786 8339 108 -749 105 8000 8669 10219 9281 1390 -12346 -15605 -22642 -21508 -15646 -12237 -9088 -2781 -3570 -2305 -2683 -5361 -2594 -366 -241 5552 12972 13282 14892 13276 7890 1840 -2120 -1712 -2218 803 -234 3868 7276 -13 906 -2307 -8164 -11814 -10570 -7613 -5075 239 6565 5392 9328 7839 -4 -569 -5578 -4727 SS 20250126T144247.4Z 9157.613048 130 1 54.36 2 78.20 128.37 72.51 165.82 0.00 1 0.00 1 0 25 4.972e-01 1.140e-02 1.350e-01 2.423e-03 7.435255e-01 1.276098e-03 8.614484e-03 -6.000000e+00 2.829923e-01 224.00 -2.00 3.52 -2.00 320.51 0.00e+00 5.457718e-03 4.846539e-04 6.171348e-04 -6.000000e+00 1.275937e-02 273.26 -2.00 20.00 -2.00 320.07 0.00e+00 4.739 0.002 302.00 328.00 3 2.6629e+00 3.7947e-03 6.0254e-02 -6.0000e+00 7.0113e-01 1.6071e-01 5.0141e-03 3.9862e-02 -6.0000e+00 7.6266e-01 -1.5342e-01 5.3731e-03 2.1738e-02 -6.0000e+00 4.5090e-01 5.3002e-02 2.7092e-03 9.4244e-03 -6.0000e+00 1.9513e-01 1.5756e-04 -1.4763e-03 6.1267e-05 8.2189e-05 -6.0000e+00 1.3573e-02 -2.9618e-02 -3.6813e-05 12 8 8 10 0 0 99.42 23.18 0.46 -0.02962 -0.04071 61 6 1 5 0 890.950 31.75 19.97 23.18 2.98 3.0 790.56 -227012 -124259 -90973 -154578 220106 -206898 -131014 900000 -161613 -150364 900000 -88272 -21282 900000 -30941 58964 44453 -31816 114456 -93969 -9651 54808 -74240 20217 -67121 -32926 29084 -1975 115746 6856 -30696 2948 6882 -24213 14179 -20053 5925 -17238 -2276 3985 3362 9029 1782 7201 11587 5483 3927 -5298 14208 6232 -3123 10819 3672 2236 9267 815 -2810 3005 1056 1002 1065 1537 4776 6044 4222 205 2449 352 -778 4380 683 -672 -551 537 -1750 -1422 -820 204 -3448 -1349 498 -729 -2415 -1327 -2763 110 -129 1050 -372 -380 324 1038 145 7 964 -20 -412 341 -496 -130 77 290 -546 -617 -1799 -1194 -678 -1049 266 825 -87 228 638 -228 -131 577 432 195 -274 -170 -165 618 76 652 1081 -399 1163 762 -173 121 -178 107 165 -202 -122 -626 466 284 -423 5 -344 -211 -3654 -939 -537 -1679 520 -3468 -1114 900000 -2366 -2130 900000 -854 -141 900000 -394 376 378 -654 595 -4149 -187 556 -2892 334 -2853 -1049 508 -46 847 170 -1384 116 307 -1572 599 -1198 305 -1339 -188 369 352 961 216 850 1338 696 526 -822 1936 1005 -570 1934 777 524 2144 213 -781 777 269 252 281 453 1577 2240 1531 76 896 139 -348 2149 379 -389 -309 276 -829 -602 -330 86 -1743 -805 316 -536 -1823 -1046 -2362 96 -119 973 -345 -335 263 791 109 6 887 -20 -461 433 -641 -164 95 316 -585 -679 -2020 -1398 -838 -1323 369 1220 -137 374 1041 -361 -206 875 669 301 -448 -283 -266 993 118 971 1543 -589 1657 1118 -279 209 -338 206 335 -418 -258 -1380 1031 637 -936 12 -698 -419 SS 20250126T144737.5Z 9157.616406 133 1 54.42 2 77.49 129.30 72.30 166.88 0.00 1 0.00 1 0 25 4.263e-01 1.244e-02 9.638e-02 2.290e-03 7.068637e-01 1.188593e-03 8.237085e-03 -6.000000e+00 2.425709e-01 224.00 -2.00 3.52 -2.00 320.26 0.00e+00 4.833773e-03 4.149253e-04 4.487125e-04 -6.000000e+00 1.036387e-02 273.26 -2.00 20.00 -2.00 319.81 0.00e+00 4.491 0.002 302.00 328.00 3 2.8471e+00 3.4548e-03 5.6909e-02 -6.0000e+00 6.0087e-01 1.6249e-01 4.3822e-03 3.7131e-02 -6.0000e+00 6.5347e-01 -1.6716e-01 4.4354e-03 2.0010e-02 -6.0000e+00 3.8638e-01 6.2070e-02 2.2801e-03 8.1584e-03 -6.0000e+00 1.6673e-01 1.7112e-04 -1.5949e-03 5.7960e-05 7.6199e-05 -6.0000e+00 1.1526e-02 -2.9581e-02 -5.7023e-05 12 8 8 10 0 0 99.75 23.20 0.38 -0.02958 -0.04157 45 4 1 5 0 1209.160 31.75 19.85 23.20 3.10 3.0 791.35 -194484 -142986 -129050 -158684 -102855 -174486 -142126 900000 -142219 -128715 59966 -38860 -78487 74198 -41432 -2018 -976 318 67939 -75763 13361 54093 75900 10571 -53567 -32695 4477 -15721 -928 -16724 -31605 -6439 3827 -20567 5621 -21974 1824 -14800 -3302 3851 849 10567 3349 7059 -3672 5284 7411 -2756 12350 8798 -715 8456 3050 2556 7522 2829 -674 3143 1209 2095 3113 1734 5563 4775 3858 -604 3936 648 -630 3684 882 -67 26 513 -2131 -3238 -967 228 -2609 -405 88 -698 -2345 -2059 -2807 -143 -608 483 -344 113 256 1164 -43 413 540 -453 -722 576 -278 -278 -34 129 -414 -1003 -1505 -1646 -793 -981 158 222 29 -85 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