File name: Pandora246s1_IowaCityIA-WHS_20250202_L2Fit_fwvt1c2d20230109p1-8.txt File generation date: 20250203T062829.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora246_OF_v1d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20250202_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20250202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.0802 492.2014 492.3225 492.4437 492.5648 492.6859 492.8070 492.9281 493.0491 493.1702 493.2912 493.4122 493.5332 493.6542 493.7751 493.8961 494.0170 494.1379 494.2588 494.3797 494.5005 494.6214 494.7422 494.8630 494.9838 495.1046 495.2253 495.3461 495.4668 495.5875 495.7082 495.8289 495.9495 496.0702 496.1908 496.3114 496.4320 496.5526 496.6731 496.7937 496.9142 497.0347 497.1552 497.2757 497.3961 497.5166 497.6370 497.7574 497.8778 497.9982 498.1185 498.2389 498.3592 498.4795 498.5998 498.7201 498.8403 498.9606 499.0808 499.2010 499.3212 499.4414 499.5615 499.6817 499.8018 499.9219 500.0420 500.1621 500.2821 500.4022 500.5222 500.6422 500.7622 500.8822 501.0021 501.1221 501.2420 501.3619 501.4818 501.6017 501.7215 501.8414 501.9612 502.0810 502.2008 502.3205 502.4403 502.5600 502.6798 502.7995 502.9192 503.0388 503.1585 503.2781 503.3977 503.5173 503.6369 503.7565 503.8761 503.9956 504.1151 504.2346 504.3541 504.4736 504.5930 504.7125 504.8319 504.9513 505.0707 505.1900 505.3094 505.4287 505.5480 505.6673 505.7866 505.9059 506.0251 506.1443 506.2636 506.3828 506.5019 506.6211 506.7403 506.8594 506.9785 507.0976 507.2167 507.3357 507.4548 507.5738 507.6928 507.8118 507.9308 508.0498 508.1687 508.2876 508.4065 508.5254 508.6443 508.7632 508.8820 509.0008 509.1196 509.2384 509.3572 509.4760 509.5947 509.7134 509.8321 509.9508 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250202T165205.7Z 9164.702844 171 1 30.77 2 61.70 155.94 75.70 97.48 0.00 1 0.00 1 0 15 2.599e-03 2.602e-03 1.153e-03 1.152e-03 1.413773e+03 6.654742e+01 1.005383e+02 -6.000000e+00 1.437059e+02 273.25 -2.00 20.00 -2.00 505.25 0.00e+00 1.966503e-04 3.130139e-05 1.498082e-05 -6.000000e+00 7.225145e-05 273.25 -2.00 20.00 -2.00 500.43 0.00e+00 1.758981e-02 2.308101e-02 1.199732e-02 -6.000000e+00 5.249290e-02 224.26 -2.00 3.52 -2.00 502.02 0.00e+00 2.099 0.000 489.00 513.00 1 7.4841e+00 1.7669e-03 3.1041e-03 -6.0000e+00 4.0195e-03 1.3930e-02 4.5325e-04 3.2015e-04 -6.0000e+00 1.0351e-03 8.1993e-04 4.1906e-03 1.2629e-04 1.3897e-05 -6.0000e+00 2.9291e-04 -3.8870e-02 8.0582e-05 12 1 1 12 1 1 99.28 24.54 1.81 -0.03887 -0.00980 7 1 1 4 0 3846.080 32.50 20.04 24.54 22.54 2.9 950.39 -19 71 107 -162 -228 319 462 367 414 81 326 -322 -148 -173 -293 -70 -365 13 -102 -407 22 -59 84 133 199 -71 277 -16 -75 -54 142 -264 51 486 -189 -382 -471 162 8 320 397 186 167 61 196 124 147 199 184 -377 -387 -525 -296 -84 119 -393 39 -1 -272 -38 398 303 383 -46 246 66 -61 188 -400 -313 325 -14 -126 192 -428 -498 -256 10 231 -117 -122 -250 -360 -68 -15 -315 -417 13 -41 69 -203 189 48 56 -23 483 -79 -286 119 -7 -272 -120 16 14 -552 -245 258 -130 379 251 -71 155 193 -70 5 320 156 234 166 427 549 111 146 -175 -304 6 158 159 154 105 -371 -175 16 -101 55 323 -212 -511 -636 -276 190 -20 395 249 20 421 -373 -299 15 410 -19 69 106 -166 -235 334 481 385 433 84 339 -332 -150 -178 -299 -70 -374 14 -106 -432 24 -62 88 139 208 -74 291 -17 -76 -55 141 -265 52 500 -196 -399 -490 169 9 327 406 191 174 63 203 128 152 206 186 -381 -382 -517 -290 -83 118 -393 40 -1 -279 -39 407 311 393 -46 250 66 -61 187 -394 -306 314 -13 -124 190 -419 -494 -250 10 224 -112 -117 -241 -351 -67 -14 -309 -411 13 -40 68 -204 187 48 56 -23 478 -76 -277 113 -6 -256 -115 15 14 -550 -243 252 -129 371 248 -70 154 195 -71 5 322 158 236 165 426 540 109 143 -171 -300 6 155 155 150 102 -358 -169 15 -95 52 311 -204 -503 -623 -272 187 -20 393 248 19 412 -367 -288 14 395 SQ 20250202T170213.6Z 9164.709880 175 1 3.81 2 60.97 158.58 73.85 99.15 0.00 1 0.00 1 0 15 2.020e-03 2.020e-03 6.474e-04 6.464e-04 1.419615e+03 3.729789e+01 1.051016e+02 -6.000000e+00 1.116602e+02 273.25 -2.00 20.00 -2.00 505.26 0.00e+00 1.863884e-04 1.759947e-05 1.200350e-05 -6.000000e+00 5.612900e-05 273.25 -2.00 20.00 -2.00 500.45 0.00e+00 3.115812e-02 1.296072e-02 1.146685e-02 -6.000000e+00 4.075022e-02 224.26 -2.00 3.52 -2.00 502.04 0.00e+00 2.051 0.000 489.00 513.00 1 4.3803e+00 9.9265e-04 3.0235e-03 -6.0000e+00 3.1208e-03 1.3841e-02 2.5439e-04 3.1545e-04 -6.0000e+00 8.0273e-04 1.8376e-02 2.3657e-03 7.0790e-05 1.4320e-05 -6.0000e+00 2.2757e-04 -3.4595e-02 1.3345e-04 12 1 1 12 1 1 98.66 24.52 1.70 -0.03460 -0.01819 20 30 1 4 0 180.280 32.50 19.99 24.52 22.83 2.8 950.89 114 -60 0 -122 -132 206 276 167 13 129 136 -59 -142 14 73 -213 -142 113 -192 -295 -22 137 50 138 219 36 196 92 -413 54 246 -25 313 431 -230 -478 -190 125 -33 34 161 25 146 -92 142 81 120 17 38 -129 -362 -155 -337 30 136 -228 -293 -299 -193 219 431 398 216 199 135 -40 44 87 -34 -202 -23 -88 -272 96 -156 -487 -272 48 104 -148 -244 -400 -238 -1 32 -300 -114 -28 36 11 244 369 135 -124 11 156 67 -13 -24 -58 -263 -346 -135 -53 -480 -348 -53 46 228 173 -74 54 129 120 198 232 206 25 155 443 246 108 328 -32 -180 20 220 171 245 185 -210 -189 55 -165 49 178 -218 -403 -240 -125 -36 121 134 9 142 -138 -339 80 137 163 112 -59 0 -124 -136 214 288 175 13 134 140 -61 -145 15 74 -215 -146 117 -200 -309 -23 144 53 146 231 38 204 96 -426 54 245 -25 317 443 -240 -498 -198 129 -34 35 164 26 150 -96 147 84 124 17 39 -129 -358 -151 -328 30 135 -227 -298 -304 -196 221 435 404 220 202 136 -41 44 86 -34 -198 -22 -85 -266 95 -154 -479 -266 46 101 -143 -234 -388 -232 -1 31 -295 -112 -28 35 11 243 368 136 -124 11 154 66 -12 -23 -55 -252 -334 -131 -52 -476 -344 -53 44 223 169 -74 54 130 120 199 235 209 25 155 440 242 106 321 -31 -176 20 216 168 240 180 -204 -182 53 -158 47 171 -211 -394 -237 -124 -36 120 134 9 141 -136 -332 77 131 156 SQ 20250202T170554.0Z 9164.712430 178 1 1.55 2 60.72 159.54 73.18 99.76 0.00 1 0.00 1 0 15 2.468e-03 2.468e-03 1.615e-03 1.612e-03 1.498667e+03 9.341085e+01 1.021465e+02 -6.000000e+00 1.364542e+02 273.25 -2.00 20.00 -2.00 505.27 0.00e+00 1.991324e-04 4.387205e-05 1.521996e-05 -6.000000e+00 6.854013e-05 273.25 -2.00 20.00 -2.00 500.50 0.00e+00 -1.987907e-02 3.231346e-02 1.500484e-02 -6.000000e+00 4.955591e-02 224.27 -2.00 3.52 -2.00 502.09 0.00e+00 2.036 0.000 489.00 513.00 1 5.0722e+00 2.4750e-03 3.1062e-03 -6.0000e+00 3.7982e-03 1.6141e-02 6.3353e-04 3.6467e-04 -6.0000e+00 9.7094e-04 9.2538e-03 -4.9315e-03 1.7672e-04 1.2467e-05 -6.0000e+00 2.7726e-04 -7.5770e-02 7.5168e-04 12 1 1 12 1 1 35.08 24.52 1.72 -0.07577 -0.10998 3 14 1 4 0 385.440 32.50 19.87 24.52 22.64 2.8 947.99 -118 176 -320 -83 -81 212 61 123 32 405 354 -28 -33 35 -52 -340 -267 -141 -139 -465 -2 -127 164 -94 129 -32 37 227 -249 24 262 -81 164 257 -79 -557 -100 6 -80 96 434 262 157 249 312 192 29 217 225 60 -23 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