File name: Pandora246s1_IowaCityIA-WHS_20250307_L2Fit_fwvt1c2d20230109p1-8.txt File generation date: 20250308T062227.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Charles Stanier Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora246_OF_v2d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20250307_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20250307 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.0802 492.2014 492.3225 492.4437 492.5648 492.6859 492.8070 492.9281 493.0491 493.1702 493.2912 493.4122 493.5332 493.6542 493.7751 493.8961 494.0170 494.1379 494.2588 494.3797 494.5005 494.6214 494.7422 494.8630 494.9838 495.1046 495.2253 495.3461 495.4668 495.5875 495.7082 495.8289 495.9495 496.0702 496.1908 496.3114 496.4320 496.5526 496.6731 496.7937 496.9142 497.0347 497.1552 497.2757 497.3961 497.5166 497.6370 497.7574 497.8778 497.9982 498.1185 498.2389 498.3592 498.4795 498.5998 498.7201 498.8403 498.9606 499.0808 499.2010 499.3212 499.4414 499.5615 499.6817 499.8018 499.9219 500.0420 500.1621 500.2821 500.4022 500.5222 500.6422 500.7622 500.8822 501.0021 501.1221 501.2420 501.3619 501.4818 501.6017 501.7215 501.8414 501.9612 502.0810 502.2008 502.3205 502.4403 502.5600 502.6798 502.7995 502.9192 503.0388 503.1585 503.2781 503.3977 503.5173 503.6369 503.7565 503.8761 503.9956 504.1151 504.2346 504.3541 504.4736 504.5930 504.7125 504.8319 504.9513 505.0707 505.1900 505.3094 505.4287 505.5480 505.6673 505.7866 505.9059 506.0251 506.1443 506.2636 506.3828 506.5019 506.6211 506.7403 506.8594 506.9785 507.0976 507.2167 507.3357 507.4548 507.5738 507.6928 507.8118 507.9308 508.0498 508.1687 508.2876 508.4065 508.5254 508.6443 508.7632 508.8820 509.0008 509.1196 509.2384 509.3572 509.4760 509.5947 509.7134 509.8321 509.9508 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250307T211414.7Z 9197.884892 456 1 54.79 2 61.57 232.26 50.62 84.84 0.00 1 0.00 1 0 15 1.988e-03 1.992e-03 2.587e-04 2.584e-04 1.661629e+03 1.507600e+01 1.215689e+02 -6.000000e+00 1.105429e+02 274.66 -2.00 20.00 -2.00 505.27 0.00e+00 3.396031e-04 7.061628e-06 2.101327e-05 -6.000000e+00 5.542780e-05 274.66 -2.00 20.00 -2.00 500.51 0.00e+00 5.945391e-02 5.166539e-03 1.365773e-02 -6.000000e+00 4.015398e-02 225.64 -2.00 3.52 -2.00 502.10 0.00e+00 2.090 0.000 489.00 513.00 1 5.2362e+00 3.9570e-04 3.1669e-03 -6.0000e+00 3.0760e-03 -2.3340e-03 1.0129e-04 3.5819e-04 -6.0000e+00 7.9143e-04 7.7264e-03 2.8198e-03 2.8329e-05 1.7683e-05 -6.0000e+00 2.2402e-04 -2.8022e-02 6.9095e-05 10 0 0 10 0 0 99.99 24.38 1.67 -0.02802 -0.00846 209 20 1 4 0 262.130 32.50 20.00 24.38 16.73 3.0 903.40 -47 -2 33 -130 -82 355 354 224 187 70 163 -32 -150 -14 -65 -183 -154 36 -59 -299 7 95 87 183 224 -2 178 86 -306 -89 79 -137 164 353 -241 -486 -138 33 -60 132 283 233 143 131 130 103 145 112 61 -278 -327 -329 -325 -97 49 -168 -245 -226 -137 177 361 318 187 163 115 0 4 48 -118 -141 -9 -145 -221 17 -180 -410 -188 -2 13 -146 -173 -379 -346 61 -60 -311 -271 -34 -31 57 157 336 181 -81 59 149 -24 -16 22 -145 -298 -329 -121 -137 -488 -256 -9 -13 174 142 -8 55 175 127 213 294 310 204 191 352 262 163 313 12 -181 39 189 91 272 118 -255 -8 -64 -184 12 221 -259 -474 -212 -83 -59 197 274 156 79 -64 -257 -68 87 74 -46 -2 33 -132 -84 364 369 233 194 73 167 -32 -152 -14 -64 -183 -157 37 -61 -309 8 99 90 190 234 -2 184 89 -313 -89 78 -138 166 362 -250 -508 -144 34 -62 135 288 239 146 135 134 106 150 114 62 -279 -324 -320 -314 -94 48 -168 -246 -230 -140 179 365 323 190 166 116 0 4 48 -116 -137 -8 -141 -217 16 -177 -407 -183 -2 12 -142 -169 -367 -338 59 -59 -308 -269 -33 -30 57 156 338 182 -81 59 147 -24 -15 21 -138 -286 -318 -119 -136 -488 -256 -9 -13 171 141 -8 55 175 129 217 297 314 206 193 351 261 161 308 12 -180 38 188 90 268 116 -249 -8 -61 -178 12 214 -254 -467 -211 -82 -58 197 275 157 79 -64 -253 -66 84 71 SQ 20250307T212841.8Z 9197.894928 468 1 37.16 2 63.74 235.49 48.01 86.99 0.00 1 0.00 1 0 15 2.055e-03 2.057e-03 3.687e-04 3.683e-04 1.791452e+03 2.159325e+01 1.280097e+02 -6.000000e+00 1.142643e+02 274.66 -2.00 20.00 -2.00 505.27 0.00e+00 3.804953e-04 1.006581e-05 2.267149e-05 -6.000000e+00 5.728919e-05 274.66 -2.00 20.00 -2.00 500.52 0.00e+00 6.461509e-02 7.366785e-03 1.549474e-02 -6.000000e+00 4.148956e-02 225.64 -2.00 3.52 -2.00 502.10 0.00e+00 2.248 0.000 489.00 513.00 1 5.5167e+00 5.6421e-04 3.4276e-03 -6.0000e+00 3.1785e-03 -1.0532e-03 1.4432e-04 3.9535e-04 -6.0000e+00 8.1743e-04 5.7038e-03 2.1931e-03 4.0361e-05 1.8198e-05 -6.0000e+00 2.3155e-04 -2.9954e-02 1.1085e-04 12 1 1 12 1 1 98.76 24.42 1.68 -0.02995 -0.01474 56 8 1 4 0 651.840 32.50 19.99 24.42 17.27 3.0 907.98 -28 -69 -57 -202 -144 291 373 248 141 69 192 -47 -179 -13 -78 -99 -120 54 -112 -309 33 189 77 168 162 31 230 121 -323 -135 73 -115 154 393 -199 -395 -149 58 -15 100 216 234 135 156 126 169 149 96 29 -284 -369 -301 -320 -103 77 -205 -304 -222 -165 142 382 381 271 164 133 87 63 133 -192 -129 4 -85 -177 90 -216 -398 -248 -84 -137 -211 -157 -373 -317 27 -90 -228 -297 -51 -84 68 189 356 126 -69 62 146 -57 -24 62 -157 -343 -340 -58 -156 -516 -225 14 -84 143 178 37 77 193 183 227 273 315 212 176 393 280 149 302 55 -211 137 161 81 323 219 -304 -47 -92 -143 -6 181 -261 -456 -166 -136 -115 164 273 167 70 -163 -220 -142 69 86 -27 -67 -56 -204 -148 299 388 258 145 72 196 -48 -181 -13 -79 -100 -122 55 -116 -320 34 195 80 175 169 32 237 125 -330 -136 73 -116 156 402 -207 -412 -154 59 -16 102 220 240 138 161 129 174 154 97 29 -284 -365 -292 -313 -100 76 -205 -306 -226 -168 144 387 386 276 166 134 87 63 132 -189 -125 4 -82 -174 89 -212 -394 -242 -81 -132 -204 -152 -361 -309 27 -88 -225 -294 -50 -83 67 188 358 127 -70 63 144 -56 -23 60 -149 -328 -327 -57 -155 -517 -224 14 -83 140 176 37 77 194 186 229 276 319 214 178 391 279 147 298 54 -210 135 160 81 318 215 -297 -45 -89 -138 -6 176 -255 -450 -166 -135 -115 165 275 168 70 -162 -218 -139 67 83 SQ 20250307T213335.3Z 9197.898325 471 1 29.61 2 64.50 236.55 47.12 87.73 0.00 1 0.00 1 0 15 2.050e-03 2.054e-03 1.393e-04 1.392e-04 1.786847e+03 8.162771e+00 1.284256e+02 -6.000000e+00 1.139895e+02 274.66 -2.00 20.00 -2.00 505.28 0.00e+00 3.654068e-04 3.802038e-06 2.242641e-05 -6.000000e+00 5.715299e-05 274.66 -2.00 20.00 -2.00 500.52 0.00e+00 8.006427e-02 2.781898e-03 1.526014e-02 -6.000000e+00 4.139406e-02 225.64 -2.00 3.52 -2.00 502.11 0.00e+00 2.309 0.000 489.00 513.00 1 3.3571e+00 2.1301e-04 3.4978e-03 -6.0000e+00 3.1711e-03 -2.7354e-03 5.4482e-05 3.9442e-04 -6.0000e+00 8.1564e-04 4.8981e-02 2.4144e-03 1.5265e-05 1.8221e-05 -6.0000e+00 2.3100e-04 -2.8727e-02 9.5898e-05 12 1 1 12 1 1 98.75 24.43 1.64 -0.02873 -0.01198 391 71 1 4 0 75.520 32.50 19.98 24.43 17.59 3.0 910.97 -46 -61 -9 -142 -105 377 407 219 132 105 186 -15 -134 -39 -37 -205 -138 30 -110 -290 22 149 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