File name: Pandora246s1_IowaCityIA-WHS_20250605_L2Fit_fwvt1c2d20230109p1-8.txt File generation date: 20250606T061707.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Charles Stanier Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora246_OF_v2d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20250605_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20250605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.0802 492.2014 492.3225 492.4437 492.5648 492.6859 492.8070 492.9281 493.0491 493.1702 493.2912 493.4122 493.5332 493.6542 493.7751 493.8961 494.0170 494.1379 494.2588 494.3797 494.5005 494.6214 494.7422 494.8630 494.9838 495.1046 495.2253 495.3461 495.4668 495.5875 495.7082 495.8289 495.9495 496.0702 496.1908 496.3114 496.4320 496.5526 496.6731 496.7937 496.9142 497.0347 497.1552 497.2757 497.3961 497.5166 497.6370 497.7574 497.8778 497.9982 498.1185 498.2389 498.3592 498.4795 498.5998 498.7201 498.8403 498.9606 499.0808 499.2010 499.3212 499.4414 499.5615 499.6817 499.8018 499.9219 500.0420 500.1621 500.2821 500.4022 500.5222 500.6422 500.7622 500.8822 501.0021 501.1221 501.2420 501.3619 501.4818 501.6017 501.7215 501.8414 501.9612 502.0810 502.2008 502.3205 502.4403 502.5600 502.6798 502.7995 502.9192 503.0388 503.1585 503.2781 503.3977 503.5173 503.6369 503.7565 503.8761 503.9956 504.1151 504.2346 504.3541 504.4736 504.5930 504.7125 504.8319 504.9513 505.0707 505.1900 505.3094 505.4287 505.5480 505.6673 505.7866 505.9059 506.0251 506.1443 506.2636 506.3828 506.5019 506.6211 506.7403 506.8594 506.9785 507.0976 507.2167 507.3357 507.4548 507.5738 507.6928 507.8118 507.9308 508.0498 508.1687 508.2876 508.4065 508.5254 508.6443 508.7632 508.8820 509.0008 509.1196 509.2384 509.3572 509.4760 509.5947 509.7134 509.8321 509.9508 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250605T105318.4Z 9287.453685 109 1 54.24 2 87.52 61.56 127.99 301.02 0.00 1 0.00 1 0 43 1.562e-02 1.545e-02 8.716e-04 8.679e-04 8.713439e+03 5.865826e+01 5.582238e+02 -6.000000e+00 9.017632e+02 284.08 -2.00 20.00 -2.00 505.42 0.00e+00 3.422609e-03 2.456327e-05 1.782750e-04 -6.000000e+00 4.454082e-04 284.08 -2.00 20.00 -2.00 501.14 0.00e+00 5.789566e-01 1.694876e-02 7.513362e-02 -6.000000e+00 3.162687e-01 232.19 -2.00 3.52 -2.00 502.62 0.00e+00 14.771 0.060 489.00 513.00 1 5.5793e+00 1.2996e-03 2.3507e-02 -6.0000e+00 2.4295e-02 -5.7988e-02 3.2353e-04 2.0398e-03 -6.0000e+00 6.2430e-03 8.6171e-04 6.6612e-03 9.3062e-05 9.1231e-05 -6.0000e+00 1.7618e-03 -1.5540e-02 -1.0592e-05 12 9 9 12 1 1 4.10 24.92 14.15 -0.01554 0.03066 20 2 1 4 0 2582.540 32.75 19.99 24.92 26.88 2.9 982.75 -4281 -2766 -1418 -104 1191 2018 2499 2430 2077 933 441 -858 -1464 -1681 -1905 -1583 -719 510 1014 1148 1104 1141 1114 1586 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-953 -211 -789 -1345 -2009 -2026 -2282 -2278 -1793 -1750 -1406 -1138 -855 -723 -1004 -560 -550 -10 771 1386 1644 1552 1561 1042 -347 -994 -2005 -2755 -2815 -1979 -707 132 -214 -585 -793 -1684 -1100 -422 246 1317 2272 2727 3044 3386 3157 2684 1638 1160 525 388 669 916 898 949 1083 825 687 610 -578 -1202 -1718 -1871 -1691 -543 -426 -280 437 628 801 1064 1303 1181 917 373 -1339 -2271 -2415 -1838 SQ 20250605T105816.8Z 9287.457139 114 1 54.29 2 86.70 62.37 128.77 302.17 0.00 1 0.00 1 0 29 1.038e-02 1.028e-02 4.638e-04 4.623e-04 1.046759e+04 3.196329e+01 6.852795e+02 -6.000000e+00 5.992972e+02 284.08 -2.00 20.00 -2.00 505.42 0.00e+00 2.743424e-03 1.308236e-05 1.534163e-04 -6.000000e+00 2.958986e-04 284.08 -2.00 20.00 -2.00 501.09 0.00e+00 7.253265e-01 9.068760e-03 8.163609e-02 -6.000000e+00 2.098820e-01 232.19 -2.00 3.52 -2.00 502.58 0.00e+00 12.841 0.039 489.00 513.00 1 4.7088e+00 6.9551e-04 2.0283e-02 -6.0000e+00 1.6126e-02 -7.1211e-02 1.7310e-04 2.1374e-03 -6.0000e+00 4.1370e-03 2.6757e-03 2.2940e-03 4.8807e-05 9.3636e-05 -6.0000e+00 1.1702e-03 1.5809e-02 -9.5859e-05 12 8 8 10 0 0 17.84 24.92 8.93 0.01581 0.03172 61 6 1 4 0 889.790 32.75 20.01 24.92 27.13 2.9 983.74 -2393 -1760 -747 82 763 1576 1914 1796 1480 818 341 -407 -747 -987 -1164 -978 -524 322 601 596 654 833 766 1029 1087 931 732 101 -1043 -1575 -1642 -1421 -492 534 484 220 242 12 -221 -223 220 416 791 1091 1197 1259 887 485 -20 -1085 -1819 -2319 -2132 -1344 -320 136 477 747 695 1113 1363 1494 1471 1133 703 337 -171 -352 -785 -1144 -969 -997 -598 -285 -398 -850 -1283 -1399 -1446 -1608 -1367 -1297 -1055 -670 -588 -658 -799 -481 -367 63 516 1061 1248 1045 1016 756 -122 -644 -1322 -2012 -2062 -1556 -628 -133 -382 -536 -743 -975 -667 -261 123 773 1372 1756 2029 2137 2242 1643 1067 840 441 238 521 574 478 608 657 602 647 461 -437 -629 -921 -1149 -1021 -427 -382 -161 219 400 508 571 817 823 517 245 -603 -1230 -1331 -1088 -2159 -1578 -685 75 717 1471 1810 1712 1412 778 322 -382 -696 -915 -1081 -915 -498 304 578 580 640 817 740 998 1060 910 713 98 -1018 -1512 -1565 -1366 -471 523 475 218 238 12 -215 -218 215 410 788 1078 1192 1256 883 479 -20 -1066 -1760 -2266 -2079 -1296 -315 134 478 754 704 1126 1382 1493 1476 1138 704 335 -172 -350 -776 -1127 -952 -986 -595 -286 -393 -854 -1276 -1377 -1415 -1574 -1341 -1282 -1052 -660 -585 -659 -803 -482 -367 63 520 1076 1246 1057 1008 747 -119 -614 -1271 -1935 -1966 -1517 -620 -134 -386 -545 -755 -990 -676 -267 127 804 1408 1810 2102 2234 2364 1719 1118 886 460 247 537 595 499 637 690 633 681 484 -451 -655 -953 -1193 -1052 -445 -406 -171 236 428 548 620 891 899 564 265 -649 -1313 -1438 -1159 SQ 20250605T110931.0Z 9287.464942 117 1 7.34 2 84.82 64.16 130.49 304.87 0.00 1 0.00 1 0 22 5.648e-03 5.605e-03 8.489e-04 8.475e-04 9.882511e+03 5.870518e+01 6.664253e+02 -6.000000e+00 3.260828e+02 284.08 -2.00 20.00 -2.00 505.38 0.00e+00 1.786125e-03 2.390964e-05 1.048263e-04 -6.000000e+00 1.610368e-04 284.08 -2.00 20.00 -2.00 500.89 0.00e+00 7.218783e-01 1.676765e-02 6.994067e-02 -6.000000e+00 1.142778e-01 232.19 -2.00 3.52 -2.00 502.42 0.00e+00 9.563 0.016 489.00 513.00 1 4.3527e+00 1.2859e-03 1.4975e-02 -6.0000e+00 8.7796e-03 -6.0696e-02 3.2156e-04 1.8348e-03 -6.0000e+00 2.2541e-03 6.0960e-03 2.3359e-03 8.9166e-05 8.2448e-05 -6.0000e+00 6.3699e-04 2.5813e-04 -4.8831e-05 12 9 9 12 1 1 -0.00 24.93 3.79 0.00026 0.01646 13 10 1 4 0 523.640 32.75 20.01 24.93 27.72 2.8 986.74 -955 -765 -190 98 435 987 1171 1027 742 492 384 -206 -485 -383 -495 -366 -184 195 144 165 300 330 352 558 619 313 550 174 -711 -773 -764 -877 -162 288 227 -179 60 19 -212 -183 113 243 398 409 460 663 383 237 -23 -497 -1200 -1312 -1305 -683 -96 -60 35 232 35 589 878 839 803 624 424 156 -109 -50 -508 -487 -501 -557 -331 28 -235 -621 -735 -621 -864 -777 -811 -912 -713 -320 -370 -535 -540 -247 -361 199 538 692 808 423 510 547 -68 -215 -710 -1140 -1044 -1011 -611 -22 -427 -425 -407 -420 -233 -69 -32 251 717 975 1055 994 1153 854 643 565 295 353 291 344 108 304 396 298 608 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