File name: Pandora246s1_IowaCityIA-WHS_20250705_L2Fit_fout2c2d20230109p1-8.txt File generation date: 20250706T061744.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Charles Stanier Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 246 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora246_OF_v2d20221122.txt Instrument calibration file used: Pandora246s1_CF_v2d20230109.txt Level 1 file used: Pandora246s1_IowaCityIA-WHS_20250705_L1_smca1c2d20230109p1-8.txt Full location name: West High School, Iowa City, IA Short location name: IowaCityIA-WHS Country of location: United States Location latitude [deg]: 41.6548 Location longitude [deg]: -91.5827 Location altitude [m]: 235 Local noon date: 20250705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 198 339 Nominal wavelengths inside fitting window [nm]: 305.1105 305.2516 305.3926 305.5337 305.6748 305.8158 305.9568 306.0979 306.2389 306.3799 306.5209 306.6618 306.8028 306.9438 307.0847 307.2256 307.3666 307.5075 307.6484 307.7892 307.9301 308.0710 308.2118 308.3527 308.4935 308.6343 308.7751 308.9159 309.0567 309.1974 309.3382 309.4789 309.6197 309.7604 309.9011 310.0418 310.1825 310.3232 310.4638 310.6045 310.7451 310.8858 311.0264 311.1670 311.3076 311.4482 311.5887 311.7293 311.8699 312.0104 312.1509 312.2914 312.4319 312.5724 312.7129 312.8534 312.9938 313.1343 313.2747 313.4151 313.5555 313.6959 313.8363 313.9767 314.1171 314.2574 314.3977 314.5381 314.6784 314.8187 314.9590 315.0993 315.2395 315.3798 315.5200 315.6603 315.8005 315.9407 316.0809 316.2211 316.3613 316.5015 316.6416 316.7817 316.9219 317.0620 317.2021 317.3422 317.4823 317.6224 317.7624 317.9025 318.0425 318.1825 318.3225 318.4625 318.6025 318.7425 318.8825 319.0224 319.1624 319.3023 319.4422 319.5821 319.7220 319.8619 320.0018 320.1417 320.2815 320.4213 320.5612 320.7010 320.8408 320.9806 321.1204 321.2601 321.3999 321.5396 321.6794 321.8191 321.9588 322.0985 322.2382 322.3779 322.5175 322.6572 322.7968 322.9364 323.0761 323.2157 323.3552 323.4948 323.6344 323.7740 323.9135 324.0530 324.1926 324.3321 324.4716 324.6110 324.7505 324.8900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250705T113638.6Z 9317.483780 78 1 54.40 2 81.16 67.36 144.97 298.54 0.00 1 0.00 1 0 37 2.274e+00 1.232e-01 3.107e-01 6.314e-03 9.792105e-01 3.732856e-03 2.309634e-02 -6.000000e+00 1.373382e+00 232.81 -2.00 3.52 -2.00 320.87 0.00e+00 -3.051206e-01 1.363250e-03 6.176869e-03 -6.000000e+00 7.305366e-02 286.98 -2.00 20.00 -2.00 319.88 0.00e+00 6.147 0.004 302.00 328.00 3 3.8745e+00 1.2848e-02 2.5273e-01 -6.0000e+00 3.4740e+00 9.5422e-02 1.9096e-02 3.3629e-01 -6.0000e+00 3.7705e+00 -1.6809e+00 1.8689e-02 4.2881e-01 -6.0000e+00 2.2191e+00 8.5336e-01 8.7223e-03 4.3211e-01 -6.0000e+00 9.5105e-01 3.4410e-05 -1.4115e-03 1.6671e-04 3.6057e-03 -6.0000e+00 6.5583e-02 -4.2871e-02 2.9568e-04 12 8 8 10 0 0 48.39 25.71 0.92 -0.04287 -0.05348 24 2 1 5 0 2266.260 33.25 20.00 25.71 35.58 2.7 1045.27 298092 172182 900000 116874 900000 488575 239441 900000 657239 981394 900000 853124 900000 900000 461381 900000 900000 406507 900000 90604 900000 900000 149265 900000 540197 650016 900000 900000 900000 900000 213047 900000 900000 122988 304705 176147 436060 233536 387834 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1514 2919 5634 12928 13339 17943 19714 23584 19834 16975 14656 10190 3758 -3612 -6806 -960 -602 5447 5981 16778 13381 12687 5376 5837 5459 11934 12090 16234 15885 1947 -10718 -19419 -29882 -26219 -21485 -11718 -5487 -825 2730 502 1939 -6891 -4812 -11387 -8196 2754 12468 17819 20030 14655 6798 -3029 -6194 -8860 -6036 -2828 -1993 6904 8314 5366 3670 -950 -7676 -13917 -10604 -7672 -3931 3908 8501 11745 15968 8327 4067 -3720 -10370 -13609 SS 20250705T114948.0Z 9317.492917 83 1 55.01 2 78.87 69.39 147.03 302.37 0.00 1 0.00 1 0 25 3.985e-01 1.227e-02 1.560e-01 2.901e-03 6.234856e-01 1.583762e-03 7.261291e-03 -6.000000e+00 2.353375e-01 232.81 -2.00 3.52 -2.00 320.43 0.00e+00 5.041792e-03 6.056970e-04 1.168590e-03 -6.000000e+00 1.098293e-02 286.98 -2.00 20.00 -2.00 319.79 0.00e+00 4.997 0.002 302.00 328.00 3 2.8366e+00 4.8622e-03 5.9297e-02 -6.0000e+00 5.9227e-01 7.1180e-02 6.1855e-03 3.3917e-02 -6.0000e+00 6.3817e-01 -1.1978e-01 5.8492e-03 1.8680e-02 -6.0000e+00 3.7732e-01 4.0976e-02 2.9529e-03 7.8040e-03 -6.0000e+00 1.6282e-01 1.2299e-04 -3.3487e-04 7.8329e-05 8.0341e-05 -6.0000e+00 1.1002e-02 -4.1701e-02 1.7510e-04 12 8 8 10 0 0 20.63 25.73 0.60 -0.04170 -0.04422 46 4 1 5 0 1195.720 33.25 20.00 25.73 36.26 2.7 1050.62 -162466 -180471 -27482 -134424 900000 98306 -146172 900000 -142782 20590 900000 -96070 99705 900000 -26479 39228 49310 -25100 50684 -72422 -9917 10377 -77871 73807 21145 -12945 41938 14985 162644 23376 -26485 33513 26552 -12084 -3170 -14526 8955 -11520 13644 4393 -3729 1281 14329 11091 12265 -2684 -2914 -4159 21360 14065 -4619 6952 -358 1562 6230 99 380 -6289 1710 1527 1776 1197 6852 5309 1945 2879 638 101 -439 3399 -960 -77 -370 1403 -2883 -1208 212 942 -398 -1308 -1678 227 -1777 -1392 -2862 791 188 517 -153 429 512 1948 -364 67 2041 -291 -617 199 -889 -448 -258 -390 34 -804 -1851 -2018 -178 -1218 625 -224 12 445 520 214 -298 385 606 -145 334 -294 -177 531 68 1303 750 -301 489 800 192 -317 207 450 13 50 108 -504 452 -145 -334 -190 -159 -481 -2505 -3941 -155 -2166 900000 278 -2561 900000 -3067 93 900000 -1656 310 900000 -479 443 571 -681 702 -3643 -275 235 -4446 1001 520 -472 901 411 1011 641 -1437 1193 1178 -844 -194 -989 537 -1009 1141 482 -497 175 1810 1492 1664 -435 -486 -728 3031 2302 -926 1388 -84 392 1575 28 109 -1913 468 416 505 381 2349 2075 818 1161 260 43 -191 1644 -533 -44 -209 733 -1433 -530 94 424 -189 -746 -1120 156 -1357 -1120 -2513 664 167 470 -139 372 444 1557 -287 54 1844 -290 -666 243 -1108 -548 -313 -425 36 -899 -2117 -2434 -223 -1554 860 -327 19 742 856 338 -446 551 883 -224 547 -476 -299 855 107 1942 1146 -448 700 1215 313 -548 388 843 26 99 231 -1078 978 -320 -736 -418 -330 -947 SS 20250705T115540.0Z 9317.496991 86 1 54.78 2 77.84 70.29 147.92 304.19 0.00 1 0.00 1 0 25 2.184e-01 7.285e-03 3.767e-02 1.524e-03 5.815366e-01 8.093967e-04 6.743785e-03 -6.000000e+00 1.280844e-01 232.81 -2.00 3.52 -2.00 319.83 0.00e+00 2.713282e-03 2.547081e-04 5.702359e-04 -6.000000e+00 5.620035e-03 286.98 -2.00 20.00 -2.00 319.13 0.00e+00 4.606 0.002 302.00 328.00 3 2.0997e+00 2.3538e-03 5.4742e-02 -6.0000e+00 3.2191e-01 3.5182e-02 2.8520e-03 3.1269e-02 -6.0000e+00 3.4644e-01 -7.8872e-02 2.4728e-03 1.5945e-02 -6.0000e+00 2.0595e-01 2.2122e-02 1.2880e-03 5.6001e-03 -6.0000e+00 8.8887e-02 3.9097e-04 -1.8600e-04 4.0514e-05 5.2502e-05 -6.0000e+00 5.8339e-03 -4.2247e-02 1.8370e-04 11 8 0 10 0 0 41.81 25.75 0.42 -0.04225 -0.04365 117 11 1 5 0 468.170 33.25 20.01 25.75 36.57 2.7 1053.63 -104804 -82717 -71336 -90539 -56686 -56952 -90858 22110 -81501 -62398 -2589 -61779 -11967 16557 -9202 587 201 -11304 3443 -30477 -4752 -5767 -32049 8553 -16191 -10986 1101 -4577 13457 2333 -11719 2501 6729 -4594 -2716 -5169 -225 -4621 2178 2097 -2182 -792 4090 2940 3855 -1479 -1739 718 4196 3435 -594 2521 185 1027 2194 801 410 1154 -363 -209 991 1293 2511 3128 1168 2103 86 421 313 1112 381 345 -568 -253 -1781 -1016 -1191 -924 -839 -1080 -1277 -956 -1699 -1162 -1005 364 252 772 381 663 819 548 636 59 682 -16 399 223 -571 -453 -526 -393 -97 -501 -1074 -1396 -866 -724 119 117 165 75 278 161 114 485 295 162 180 -159 -278 447 168 579 476 -78 763 694 235 -41 141 131 -60 28 -122 -399 304 119 -352 -83 -206 -324 -1807 -1340 -1113 -1669 -682 -677 -1648 148 -1744 -1196 -28 -1377 -203 268 -241 17 6 -445 127 -1672 -208 -255 -1939 376 -984 -671 61 -259 622 130 -885 193 575 -468 -260 -505 -23 -598 295 340 -414 -159 821 612 807 -335 -402 166 975 857 -172 722 59 354 789 304 161 447 -139 -79 388 558 1120 1546 609 1044 43 215 177 671 255 240 -393 -165 -1077 -589 -647 -508 -518 -734 -942 -798 -1454 -1046 -972 350 254 797 393 653 795 497 552 53 646 -18 475 287 -753 -587 -668 -475 -108 -582 -1289 -1770 -1097 -980 167 174 267 120 441 254 169 724 450 248 294 -259 -449 724 265 873 722 -114 1074 1037 380 -70 251 236 -113 54 -243 -835 646 249 -762 -170 -418 -622 SS 20250705T120052.1Z 9317.500603 89 1 54.57 2 76.93 71.08 148.69 305.87 0.00 1 0.00 1 0 25 1.663e-01 6.739e-03 2.285e-02 1.287e-03 5.506294e-01 6.782976e-04 6.415479e-03 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