File name: Pandora73s1_Islamabad-NUST_20221227_L2Fit_fout2c3d20221020p1-8.txt File generation date: 20241114T123930.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 73 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora73_OF_v2d20210913.txt Instrument calibration file used: Pandora73s1_CF_v3d20221020.txt Level 1 file used: Pandora73s1_Islamabad-NUST_20221227_L1_smca1c3d20221020p1-8.txt Full location name: National University of Sciences and Technology (NUST) Islamabad, Pakistan Short location name: Islamabad-NUST Country of location: Pakistan Location latitude [deg]: 33.6479 Location longitude [deg]: 72.9896 Location altitude [m]: 555 Local noon date: 20221227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 2 "Field Cal on 1.8" First and last pixel inside fitting window: 225 366 Nominal wavelengths inside fitting window [nm]: 305.1404 305.2815 305.4226 305.5637 305.7047 305.8458 305.9869 306.1279 306.2689 306.4100 306.5510 306.6920 306.8330 306.9739 307.1149 307.2559 307.3968 307.5377 307.6787 307.8196 307.9605 308.1014 308.2422 308.3831 308.5240 308.6648 308.8057 308.9465 309.0873 309.2281 309.3689 309.5097 309.6504 309.7912 309.9319 310.0727 310.2134 310.3541 310.4948 310.6355 310.7762 310.9169 311.0575 311.1982 311.3388 311.4795 311.6201 311.7607 311.9013 312.0418 312.1824 312.3230 312.4635 312.6041 312.7446 312.8851 313.0256 313.1661 313.3066 313.4471 313.5875 313.7280 313.8684 314.0088 314.1493 314.2897 314.4301 314.5704 314.7108 314.8512 314.9915 315.1319 315.2722 315.4125 315.5528 315.6931 315.8334 315.9737 316.1139 316.2542 316.3944 316.5346 316.6749 316.8151 316.9553 317.0954 317.2356 317.3758 317.5159 317.6561 317.7962 317.9363 318.0764 318.2165 318.3566 318.4966 318.6367 318.7767 318.9168 319.0568 319.1968 319.3368 319.4768 319.6168 319.7568 319.8967 320.0367 320.1766 320.3165 320.4564 320.5963 320.7362 320.8761 321.0160 321.1558 321.2957 321.4355 321.5753 321.7151 321.8549 321.9947 322.1345 322.2742 322.4140 322.5537 322.6935 322.8332 322.9729 323.1126 323.2523 323.3919 323.5316 323.6712 323.8109 323.9505 324.0901 324.2297 324.3693 324.5089 324.6485 324.7880 324.9276 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221227T030620.9Z 8396.129409 65 1 49.60 2 81.07 125.89 121.66 90.74 0.00 1 0.00 1 0 33 4.487e-01 2.116e-02 3.741e-01 1.481e-02 6.723512e-01 8.385712e-03 9.045558e-03 -6.000000e+00 2.576599e-01 223.85 -2.00 3.34 -2.00 321.69 0.00e+00 1.462917e-02 4.393978e-03 7.863116e-03 -6.000000e+00 1.219406e-02 279.47 -2.00 20.00 -2.00 321.19 0.00e+00 6.103 0.003 302.00 328.00 3 3.5679e+00 3.0013e-02 7.2171e-02 -6.0000e+00 6.3553e-01 3.1905e-01 4.1341e-02 4.7988e-02 -6.0000e+00 6.9410e-01 -4.4671e-01 4.1230e-02 3.3144e-02 -6.0000e+00 4.1352e-01 1.7469e-01 1.9378e-02 1.5143e-02 -6.0000e+00 1.8014e-01 2.4695e-05 -3.7747e-04 4.5551e-04 2.7888e-04 -6.0000e+00 1.2614e-02 3.1434e-03 -8.4525e-05 12 9 8 11 8 0 51.68 22.33 0.69 0.00314 0.00031 21 4 1 5 0 2361.810 25.58 20.00 22.33 14.43 20.0 890.35 900000 900000 -200475 -15633 900000 73789 -148477 -104692 -184710 -86729 -199783 900000 900000 900000 -34753 -37450 900000 -18949 7239 -25361 -118735 900000 -95673 21979 -32042 77245 -17126 -208 75824 33659 900000 80799 63554 -1185 -27356 900000 1944 131360 12026 -13668 34381 692 77975 5850 36474 2771 -2498 31935 23998 74963 40225 15945 24963 -3292 17440 26997 10735 -1142 5287 -6122 30 1285 7697 4801 1958 17400 -2130 3288 9638 3034 7859 6443 8504 -794 -6139 -2905 -7431 8524 4504 -1335 1618 -3395 229 -143 5291 -69 865 1306 -2195 2317 -1984 3301 -7308 -3634 -2343 -2460 3845 -1193 -2380 -479 -1412 -3558 -5394 959 -3098 -2879 -5156 -2607 205 730 1542 255 1781 272 -1477 909 -280 1291 1130 793 -1049 2643 1070 2487 750 -468 1205 1587 1196 1070 121 132 -1793 -952 -132 -390 868 -85 370 -405 -573 -358 900000 900000 -5780 -225 900000 1064 -2209 -1509 -4203 -1250 -5706 900000 900000 900000 -576 -744 900000 -385 120 -587 -6421 900000 -4163 323 -798 1113 -374 -4 1093 592 900000 1311 1339 -45 -1266 900000 80 1893 616 -993 1728 50 2902 438 2124 229 -226 2196 1883 4008 3286 1781 2752 -498 2219 3183 1468 -170 730 -971 5 237 1522 1052 440 3329 -498 784 2463 917 2380 1971 2429 -228 -1676 -714 -1917 2093 1356 -502 676 -1650 114 -76 2844 -41 530 803 -1360 1295 -1079 1640 -4084 -2176 -1616 -1977 3364 -1210 -2491 -470 -1267 -2964 -4486 797 -2854 -2797 -5482 -2966 255 1004 2257 383 2583 381 -2030 1221 -397 1904 1747 1228 -1608 3787 1507 3342 991 -608 1596 2354 2010 1982 242 277 -4060 -2284 -330 -1000 2238 -221 931 -974 -1305 -785 SS 20221227T031834.9Z 8396.137904 70 1 49.85 2 79.03 127.85 119.21 92.29 0.00 1 0.00 1 0 17 3.110e-01 9.307e-03 2.085e-01 4.804e-03 6.000778e-01 2.591003e-03 6.584518e-03 -6.000000e+00 1.765058e-01 223.85 -2.00 3.34 -2.00 321.30 0.00e+00 1.398679e-03 1.215220e-03 2.852158e-03 -6.000000e+00 7.790240e-03 279.47 -2.00 20.00 -2.00 320.77 0.00e+00 5.068 0.002 302.00 328.00 3 2.9623e+00 8.7277e-03 5.7282e-02 -6.0000e+00 4.3507e-01 2.6675e-02 1.1810e-02 3.4857e-02 -6.0000e+00 4.7370e-01 -9.5001e-02 1.1873e-02 1.8411e-02 -6.0000e+00 2.8243e-01 3.1778e-02 5.7143e-03 5.4951e-03 -6.0000e+00 1.2119e-01 1.3286e-04 -4.0885e-04 1.4613e-04 8.6159e-05 -6.0000e+00 8.5676e-03 1.4310e-03 -1.2702e-05 11 8 0 10 0 0 33.00 22.33 0.37 0.00143 -0.00164 73 15 1 5 0 682.850 25.58 20.00 22.33 14.96 20.1 893.27 3500 70109 -88957 -158277 -111932 -141236 -99127 49194 -86533 -72797 -73383 -97447 -26321 -95573 -44205 2913 33154 42123 -20927 -23886 -16094 -3738 -17131 -23207 -28188 -31435 -25715 -7125 -1139 228 14933 6930 -9075 -11446 2021 2701 -5861 -2478 1543 -2611 3874 -148 -1933 4628 6094 -33 -1142 246 4352 8740 4434 -825 3157 3361 5498 124 -151 2121 -1857 1561 2787 3880 5774 4454 578 -1771 2636 997 3803 2360 2612 436 -412 -1471 620 -410 -2645 -2545 -2331 -3095 -1119 -1298 -2121 -897 -255 1560 342 2213 1425 646 430 -1702 -912 -1777 -674 538 1220 862 -97 -892 -1563 -1375 -257 -658 -2446 -1901 -1067 -541 718 741 738 358 293 -557 -1029 194 31 634 106 223 117 1534 529 918 509 -855 444 400 -231 215 -734 -550 -645 -218 -89 182 987 585 -168 46 -526 -630 16 328 -758 -2494 -1049 -1864 -971 230 -958 -744 -812 -1660 -280 -2350 -866 41 381 484 -481 -590 -370 -78 -445 -702 -960 -1055 -876 -194 -30 7 458 269 -422 -541 88 124 -313 -157 114 -233 354 -15 -205 466 616 -4 -130 29 513 1081 642 -128 514 586 983 24 -30 402 -358 320 562 874 1442 1212 162 -494 713 295 1254 887 1040 179 -163 -544 202 -134 -871 -906 -894 -1405 -571 -737 -1295 -577 -175 1110 255 1634 1032 442 274 -1056 -564 -1211 -522 474 1225 957 -111 -975 -1567 -1254 -229 -627 -2527 -2058 -1224 -670 977 1116 1184 582 461 -836 -1477 273 45 981 173 365 187 2330 785 1302 698 -1148 603 601 -392 400 -1470 -1153 -1430 -514 -221 465 2548 1520 -425 111 -1199 -1390 SS 20221227T032428.7Z 8396.141999 73 1 50.06 2 78.07 128.82 118.02 93.03 0.00 1 0.00 1 0 17 2.436e-01 8.609e-03 1.523e-01 3.419e-03 5.600287e-01 1.816040e-03 6.154207e-03 -6.000000e+00 1.382843e-01 223.85 -2.00 3.34 -2.00 321.00 0.00e+00 2.172841e-03 8.033720e-04 2.192302e-03 -6.000000e+00 6.102773e-03 279.47 -2.00 20.00 -2.00 320.45 0.00e+00 4.691 0.001 302.00 328.00 3 2.8241e+00 5.8986e-03 5.2378e-02 -6.0000e+00 3.4086e-01 -2.1873e-02 7.7990e-03 3.0175e-02 -6.0000e+00 3.7111e-01 -1.8875e-02 7.7753e-03 1.6593e-02 -6.0000e+00 2.2127e-01 -1.0265e-03 3.7992e-03 5.4780e-03 -6.0000e+00 9.4951e-02 2.2230e-04 -1.3926e-04 1.0360e-04 7.7792e-05 -6.0000e+00 6.7118e-03 1.1352e-03 -9.9463e-06 11 8 0 10 0 0 37.05 22.33 0.25 0.00114 0.00009 99 20 1 5 0 505.570 25.58 20.00 22.33 15.11 20.1 894.11 -81574 -128888 -71707 -100390 37698 -40622 -83837 -47692 -81578 20660 -93631 19140 -85021 -26359 18471 -35112 9419 -25043 -3177 8184 2168 16605 -25336 11107 -11387 3674 -2522 -12909 21 -24675 4194 1831 8233 -5958 -8105 7956 -8883 6863 -1841 1333 3512 -1471 4408 -8433 8198 2853 1887 990 -2987 5541 -900 4635 2807 1268 1950 183 2439 -1695 -665 -1114 782 3184 3784 2756 -527 702 -521 1232 1820 -753 3500 515 1993 -160 -1496 -2270 -3821 -249 -2567 -1388 -1494 -2442 -1353 -1007 347 -192 1503 1464 1394 1421 -259 -718 -1522 -132 -790 183 1734 706 239 -624 -966 -1501 -447 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