File name: Pandora101s1_Izana_20181223_L2Fit_fout2c18d20181121p1-8.txt File generation date: 20240506T123638.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v4d20170928.txt Instrument calibration file used: Pandora101s1_CF_v18d20181121.txt Level 1 file used: Pandora101s1_Izana_20181223_L1_smca1c18d20181121p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20181223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 baseline redo VP first period First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0294 305.1703 305.3111 305.4519 305.5928 305.7336 305.8744 306.0151 306.1559 306.2967 306.4374 306.5782 306.7189 306.8596 307.0003 307.1410 307.2817 307.4223 307.5630 307.7036 307.8443 307.9849 308.1255 308.2661 308.4067 308.5473 308.6878 308.8284 308.9689 309.1095 309.2500 309.3905 309.5310 309.6715 309.8119 309.9524 310.0929 310.2333 310.3737 310.5141 310.6545 310.7949 310.9353 311.0757 311.2160 311.3564 311.4967 311.6370 311.7774 311.9177 312.0579 312.1982 312.3385 312.4787 312.6190 312.7592 312.8994 313.0396 313.1798 313.3200 313.4602 313.6003 313.7405 313.8806 314.0208 314.1609 314.3010 314.4411 314.5811 314.7212 314.8613 315.0013 315.1413 315.2814 315.4214 315.5614 315.7014 315.8413 315.9813 316.1212 316.2612 316.4011 316.5410 316.6809 316.8208 316.9607 317.1006 317.2404 317.3803 317.5201 317.6599 317.7997 317.9395 318.0793 318.2191 318.3589 318.4986 318.6384 318.7781 318.9178 319.0575 319.1972 319.3369 319.4766 319.6162 319.7559 319.8955 320.0351 320.1747 320.3143 320.4539 320.5935 320.7331 320.8726 321.0122 321.1517 321.2912 321.4307 321.5702 321.7097 321.8492 321.9886 322.1281 322.2675 322.4069 322.5463 322.6857 322.8251 322.9645 323.1039 323.2432 323.3826 323.5219 323.6612 323.8005 323.9398 324.0791 324.2184 324.3576 324.4969 324.6361 324.7753 324.9145 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20181223T080315.0Z 6931.335590 275 1 32.00 2 89.17 117.36 85.80 291.70 0.00 1 0.00 1 0 25 1.123e+00 5.742e-01 6.921e-01 4.061e-01 1.100771e+00 2.761769e-01 1.306926e-02 -6.000000e+00 7.614763e-01 223.10 -2.00 3.19 -2.00 312.15 0.00e+00 -1.623972e-02 1.438483e-02 1.406873e-03 -6.000000e+00 3.229771e-02 273.59 -2.00 20.00 -2.00 311.87 0.00e+00 19.482 0.076 302.00 328.00 3 -2.8518e+00 6.6604e-01 1.6066e-01 -6.0000e+00 1.9003e+00 4.4762e+00 7.4391e-01 4.0137e-02 -6.0000e+00 2.0517e+00 -1.9591e+00 4.3151e-01 2.1941e-02 -6.0000e+00 1.2209e+00 4.6922e-01 1.8837e-01 8.3239e-03 -6.0000e+00 5.3615e-01 1.6744e-07 -3.4037e-02 7.9982e-03 1.0732e-04 -6.0000e+00 3.7846e-02 -6.0054e-02 0.0000e+00 12 9 8 11 8 0 56.90 17.28 19.30 -0.06005 -0.31582 8 2 1 5 0 4000.000 21.69 15.00 17.28 900000 1250 900000 1578 900000 75573 61740 900000 57381 900000 16545 99066 -9340 900000 12180 900000 -4120 900000 -49931 900000 55178 900000 31741 122354 178045 -29927 900000 -17561 132893 -1566 900000 75267 900000 900000 900000 149882 900000 900000 900000 900000 203810 58472 286903 900000 -12744 4947 900000 900000 329406 900000 52970 900000 58509 900000 130261 900000 900000 900000 53248 131809 900000 29684 28417 82549 221809 66014 73631 30434 48550 -18021 -48419 900000 -25609 900000 900000 900000 -62464 900000 -63315 900000 900000 900000 97381 19671 52412 900000 69718 900000 90983 -16898 900000 -4741 900000 282050 8648 30269 900000 -23270 236740 900000 900000 900000 -29554 68704 47126 2810 -34918 58097 78470 58808 46363 186376 83519 141613 -8674 900000 290195 900000 -23439 121558 209948 167157 294754 115707 135461 54129 59453 137436 140656 -37322 -48297 -41412 -8502 40504 -6420 49065 34798 900000 50404 83810 54776 122393 -41974 900000 1096 900000 1677 900000 34437 25558 900000 22428 900000 10613 38720 -8055 900000 9498 900000 -4675 900000 -99383 900000 41466 900000 25767 47822 69589 -39153 900000 -23656 51941 -1510 900000 29418 900000 900000 900000 58581 900000 900000 900000 900000 79660 41668 112136 900000 -19216 5838 900000 900000 128749 900000 29869 900000 34422 900000 50913 900000 900000 900000 42580 51518 900000 22128 18991 32790 86694 36177 40351 24401 31692 -21932 -82341 900000 -42020 900000 900000 900000 -106148 900000 -78672 900000 900000 900000 38482 17953 39030 900000 46672 900000 50554 -24973 900000 -5559 900000 110240 6991 20372 900000 -32542 92530 900000 900000 900000 -59284 48797 34278 2757 -49008 35789 40498 37725 35855 72845 58935 64367 -16246 900000 113423 900000 -43436 59721 82059 65334 115205 53608 52945 38404 38431 53717 54976 -52365 -84330 -79635 -13612 45077 -11588 56226 48164 900000 63514 76376 64003 73226 -102614 SU 20181223T080742.0Z 6931.338681 280 1 32.00 2 88.30 117.89 86.67 292.18 0.00 1 0.00 1 0 49 6.970e-01 2.091e-01 4.591e-01 1.431e-01 7.306650e-01 7.544226e-02 7.873725e-03 -6.000000e+00 3.967671e-01 223.10 -2.00 3.19 -2.00 318.85 0.00e+00 -1.730392e-02 1.090652e-02 5.949317e-03 -6.000000e+00 1.978471e-02 273.59 -2.00 20.00 -2.00 317.84 0.00e+00 17.199 0.053 302.00 328.00 3 -6.2084e-01 2.0282e-01 1.4268e-01 -6.0000e+00 9.7753e-01 2.6754e+00 2.3723e-01 6.8539e-02 -6.0000e+00 1.0722e+00 -1.5545e+00 1.3112e-01 1.5250e-02 -6.0000e+00 6.2903e-01 3.0758e-01 6.4462e-02 1.7667e-02 -6.0000e+00 2.7926e-01 6.9807e-07 2.1060e-02 3.9306e-03 1.5763e-04 -6.0000e+00 1.9334e-02 -9.5389e-04 0.0000e+00 12 8 8 10 0 0 99.99 17.29 4.24 -0.00095 0.15730 8 2 1 5 0 4000.000 21.69 15.00 17.29 900000 37507 900000 -15068 900000 900000 -31251 900000 24097 34587 57943 -7614 900000 55452 88315 163491 -17367 154571 -27186 900000 152901 900000 900000 181657 77373 -34434 900000 -48158 18059 -35985 900000 900000 900000 77957 14340 45053 900000 62390 900000 900000 102992 -1113 900000 81962 1260 -13023 900000 -26509 22161 900000 78322 900000 70915 900000 84415 150561 29626 267192 22430 46187 -3229 -4282 1394 36209 59451 -9582 7403 78785 43252 -18387 -34738 252584 -4238 76327 153379 133585 -61463 -35709 -50239 4584 124967 54603 127736 -17479 45418 51933 7420 255712 -11554 -12304 75101 3292 49764 2112 -28947 17804 41530 17530 1348 53694 16410 28231 -23494 -20794 38465 -27510 -4076 5310 36222 12891 -6261 38731 4490 -12657 -21714 49017 61836 39463 -20836 13941 -12198 18811 268 20142 2216 -11816 -3179 39008 19108 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