File name: Pandora101s1_Izana_20191020_L2Fit_fout2c18d20181121p1-8.txt File generation date: 20240504T171937.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v5d20170928.txt Instrument calibration file used: Pandora101s1_CF_v18d20181121.txt Level 1 file used: Pandora101s1_Izana_20191020_L1_smca1c18d20181121p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20191020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 baseline redo VP first period First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0294 305.1703 305.3111 305.4519 305.5928 305.7336 305.8744 306.0151 306.1559 306.2967 306.4374 306.5782 306.7189 306.8596 307.0003 307.1410 307.2817 307.4223 307.5630 307.7036 307.8443 307.9849 308.1255 308.2661 308.4067 308.5473 308.6878 308.8284 308.9689 309.1095 309.2500 309.3905 309.5310 309.6715 309.8119 309.9524 310.0929 310.2333 310.3737 310.5141 310.6545 310.7949 310.9353 311.0757 311.2160 311.3564 311.4967 311.6370 311.7774 311.9177 312.0579 312.1982 312.3385 312.4787 312.6190 312.7592 312.8994 313.0396 313.1798 313.3200 313.4602 313.6003 313.7405 313.8806 314.0208 314.1609 314.3010 314.4411 314.5811 314.7212 314.8613 315.0013 315.1413 315.2814 315.4214 315.5614 315.7014 315.8413 315.9813 316.1212 316.2612 316.4011 316.5410 316.6809 316.8208 316.9607 317.1006 317.2404 317.3803 317.5201 317.6599 317.7997 317.9395 318.0793 318.2191 318.3589 318.4986 318.6384 318.7781 318.9178 319.0575 319.1972 319.3369 319.4766 319.6162 319.7559 319.8955 320.0351 320.1747 320.3143 320.4539 320.5935 320.7331 320.8726 321.0122 321.1517 321.2912 321.4307 321.5702 321.7097 321.8492 321.9886 322.1281 322.2675 322.4069 322.5463 322.6857 322.8251 322.9645 323.1039 323.2432 323.3826 323.5219 323.6612 323.8005 323.9398 324.0791 324.2184 324.3576 324.4969 324.6361 324.7753 324.9145 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191020T071802.0Z 7232.304190 215 1 32.00 2 88.98 102.24 18.38 257.19 0.00 1 0.00 1 0 65 7.575e-01 3.281e-01 4.399e-01 1.992e-01 5.894528e-01 1.146189e-01 1.091731e-02 -6.000000e+00 4.362724e-01 225.38 -2.00 3.19 -2.00 314.60 0.00e+00 -3.298332e-02 8.762126e-03 4.244521e-03 -6.000000e+00 2.065278e-02 278.22 -2.00 20.00 -2.00 313.56 0.00e+00 18.948 0.070 302.00 328.00 3 -1.5185e+00 2.8299e-01 1.5288e-01 -6.0000e+00 1.0794e+00 2.5231e+00 3.1602e-01 3.7572e-02 -6.0000e+00 1.1829e+00 -1.3506e+00 1.8512e-01 1.5733e-02 -6.0000e+00 7.0223e-01 3.6050e-01 8.3736e-02 2.1833e-02 -6.0000e+00 3.0354e-01 5.4776e-07 -2.6356e-02 4.6504e-03 2.4851e-04 -6.0000e+00 2.0699e-02 5.3600e-03 0.0000e+00 12 8 8 10 0 0 13.39 16.83 7.19 0.00536 -0.19269 8 2 1 5 0 4000.000 21.38 15.00 16.83 900000 -25291 900000 73316 900000 34875 3051 900000 -14825 65398 -14732 79621 67967 900000 51000 88834 -20875 128445 48414 900000 900000 387960 900000 64193 120562 -6825 900000 63851 900000 -60199 111396 9567 900000 -3771 44600 12967 19488 25077 100758 900000 46531 59218 -1605 900000 -37177 114539 112831 36273 -47538 900000 -2186 900000 27819 12064 254659 -22680 162115 199584 130045 59918 900000 29246 71314 98488 74332 -3862 12813 12875 -37013 -34399 -8533 900000 18723 6153 89192 900000 -41953 13206 -35155 179432 37307 48070 99092 49138 59493 12827 10010 24893 900000 31799 150722 45027 12279 120926 -24337 -24338 45785 -29880 9051 128719 25600 145640 -52003 22130 6435 60470 -23362 55941 -21172 64748 9852 28036 79535 8235 602 63189 28671 55149 -21457 7149 49549 31590 97492 14419 44326 -27405 26797 7651 15213 -28850 -28023 -13875 -26672 8203 -27043 9493 -3323 35559 -2826 14115 14929 47377 -5450 900000 -27489 900000 29030 900000 14219 1441 900000 -10765 27561 -15375 35675 32500 900000 25783 30323 -20284 29234 22631 900000 900000 75054 900000 21611 26805 -6244 900000 34074 900000 -72517 21550 4422 900000 -2089 16264 6048 7616 9264 20296 900000 23930 31249 -1588 900000 -46835 30454 27454 16785 -44694 900000 -1258 900000 13482 7247 49266 -21125 31362 38611 31876 27323 900000 14618 23089 25637 26078 -2981 8075 7447 -33285 -31264 -6817 900000 13597 5065 31890 900000 -42107 6839 -26620 34712 15493 20391 29061 25662 29972 10531 8929 20143 900000 24545 35899 27531 9356 30437 -23707 -24826 26526 -39400 9161 46322 25215 43862 -93156 17765 5733 34172 -31253 36581 -29894 43087 11965 31579 59302 12307 943 52001 30619 44343 -36058 9619 47236 36544 58976 18407 41454 -48480 27417 8957 16081 -49310 -53349 -25320 -58691 13557 -65087 17196 -7278 56250 -6502 27901 28939 64486 -11457 SU 20191020T072228.0Z 7232.307269 220 1 32.00 2 88.03 102.77 19.31 258.29 0.00 1 0.00 1 0 49 6.842e-01 1.925e-01 4.041e-01 1.101e-01 8.626665e-01 5.712457e-02 1.232987e-02 -6.000000e+00 3.867435e-01 225.38 -2.00 3.19 -2.00 318.71 0.00e+00 -2.701377e-02 8.638103e-03 1.029392e-02 -6.000000e+00 1.802665e-02 278.22 -2.00 20.00 -2.00 317.52 0.00e+00 16.383 0.045 302.00 328.00 3 -5.8261e-01 1.5151e-01 1.4466e-01 -6.0000e+00 9.5828e-01 2.8454e+00 1.7859e-01 1.0287e-01 -6.0000e+00 1.0468e+00 -1.7920e+00 1.0046e-01 2.1957e-02 -6.0000e+00 6.1734e-01 4.0568e-01 4.8300e-02 2.3487e-02 -6.0000e+00 2.6623e-01 1.0194e-06 1.7452e-02 2.7285e-03 2.7289e-04 -6.0000e+00 1.8248e-02 1.7785e-03 0.0000e+00 12 8 8 10 0 0 4.66 16.82 3.61 0.00178 0.13292 8 2 1 5 0 4000.000 21.38 15.01 16.82 259280 17989 31793 160952 89838 900000 -45707 900000 11176 -8699 -746 -37316 -706 900000 -15404 6055 19701 68069 136991 900000 900000 900000 299085 35294 120879 23050 900000 6352 -10495 -61010 900000 53829 900000 -8787 31181 -17913 87721 17277 900000 900000 45850 11695 22133 900000 -9132 -50878 138869 14650 -3287 900000 30712 62127 95882 27215 57439 -1710 84170 282469 61282 36182 129639 -23597 12899 82369 28632 18504 -33544 51591 -34525 33166 8890 183227 -29891 38592 49181 132520 -54254 45159 -39844 83603 34300 91209 148689 -10622 55955 31046 26547 30658 111098 -36632 22623 16425 2198 131859 -11385 18372 57441 -13542 2970 48850 1697 17207 -70697 1361 2196 -4038 -2196 12866 13003 30788 33216 7753 34019 -12894 -15586 6279 12016 17884 -7613 13143 7418 6082 891 13085 6335 -13007 -6156 19901 -3150 6650 -5239 814 -15511 1401 -9995 2358 6870 10542 3536 -7291 -7086 13883 146 27757 4975 6523 17231 9617 900000 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-6.000000e+00 3.479950e-01 225.38 -2.00 3.19 -2.00 321.02 0.00e+00 -2.511672e-02 4.734046e-03 5.135444e-03 -6.000000e+00 1.561850e-02 278.22 -2.00 20.00 -2.00 320.18 0.00e+00 13.916 0.028 302.00 328.00 3 1.4092e-01 6.0878e-02 1.2582e-01 -6.0000e+00 8.6092e-01 2.5383e+00 7.1404e-02 9.0301e-02 -6.0000e+00 9.3722e-01 -2.2545e+00 4.1390e-02 2.3982e-02 -6.0000e+00 5.5773e-01 6.7477e-01 2.2149e-02 2.1502e-02 -6.0000e+00 2.3938e-01 3.4261e-06 3.1548e-03 9.1891e-04 2.2873e-04 -6.0000e+00 1.5800e-02 6.9496e-03 0.0000e+00 12 8 8 10 0 0 39.75 16.82 1.09 0.00695 0.03066 14 3 1 5 0 2397.024 21.48 15.00 16.82 315078 3598 110007 27001 362633 3254 84838 25051 13097 -11589 -16727 -9699 -1153 172671 -3094 13205 5080 80954 -7106 218849 35786 170500 52307 19482 27329 11375 900000 -27780 42966 -98785 -7027 -43371 176076 15006 34080 -42861 43683 -13765 125234 156202 42063 20327 21469 73078 -9968 877 -3574 34286 -34450 96970 -13149 116584 35228 32087 39856 23173 71701 44043 62980 -5120 44513 -44003 -39 3706 20669 3100 -13481 -15419 -3133 -9604 14362 56901 1039 6610 20714 32574 -45784 -15337 -31341 11429 -3009 24234 26977 27054 3079 14680 -6048 6099 26694 -12624 3004 -11991 2171 9137 -14941 -10814 12631 -4449 7273 10753 4102 -3328 -30198 10284 -3512 2993 -582 -2617 -4756 8550 -2252 6595 5670 327 -7212 7196 -110 5297 -5336 2138 -1307 -1626 211 1342 -656 -6496 12085 4314 1803 874 637 -1937 -2710 -1310 -1677 380 -772 3582 -799 547 -129 628 360 11936 805 7577 3440 13737 370 4675 2933 1939 -2315 -3456 -1870 -214 6541 -661 2501 1032 7527 -1517 8290 4190 6459 4864 2952 4329 2154 900000 -5740 3906 -31638 -992 -9858 6670 2274 3744 -8413 4137 -2711 7590 8284 7648 4620 4554 8305 -2303 166 -663 4286 -8744 6979 -3138 8391 6139 6199 7549 5443 10593 8175 8589 -1203 5902 -14669 -9 955 4698 810 -4137 -5082 -1021 -3820 4842 12717 386 2078 4865 5799 -16477 -4183 -11398 3247 -1162 8262 9913 10454 1586 7007 -3643 3258 11225 -7365 1377 -6041 946 4015 -9735 -7262 7830 -3784 6061 8665 3263 -2487 -25999 6428 -2467 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