File name: Pandora101s1_Izana_20191205_L2Fit_fwvt1c18d20191026p1-8.txt File generation date: 20240504T165353.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v5d20170928.txt Instrument calibration file used: Pandora101s1_CF_v18d20191026.txt Level 1 file used: Pandora101s1_Izana_20191205_L1_smca1c18d20191026p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20191205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 baseline for VP20191026 First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0343 492.1552 492.2761 492.3970 492.5179 492.6388 492.7596 492.8805 493.0013 493.1221 493.2429 493.3637 493.4844 493.6052 493.7259 493.8466 493.9673 494.0879 494.2086 494.3292 494.4499 494.5705 494.6911 494.8116 494.9322 495.0527 495.1733 495.2938 495.4143 495.5348 495.6552 495.7757 495.8961 496.0165 496.1369 496.2573 496.3776 496.4980 496.6183 496.7386 496.8589 496.9792 497.0995 497.2197 497.3399 497.4602 497.5804 497.7005 497.8207 497.9409 498.0610 498.1811 498.3012 498.4213 498.5414 498.6614 498.7814 498.9015 499.0215 499.1415 499.2614 499.3814 499.5013 499.6212 499.7411 499.8610 499.9809 500.1007 500.2206 500.3404 500.4602 500.5800 500.6998 500.8195 500.9393 501.0590 501.1787 501.2984 501.4181 501.5377 501.6573 501.7770 501.8966 502.0162 502.1357 502.2553 502.3748 502.4944 502.6139 502.7334 502.8528 502.9723 503.0917 503.2112 503.3306 503.4500 503.5693 503.6887 503.8081 503.9274 504.0467 504.1660 504.2853 504.4045 504.5238 504.6430 504.7622 504.8814 505.0006 505.1197 505.2389 505.3580 505.4771 505.5962 505.7153 505.8344 505.9534 506.0724 506.1914 506.3104 506.4294 506.5484 506.6673 506.7863 506.9052 507.0241 507.1430 507.2618 507.3807 507.4995 507.6183 507.7371 507.8559 507.9746 508.0934 508.2121 508.3308 508.4495 508.5682 508.6869 508.8055 508.9242 509.0428 509.1614 509.2800 509.3985 509.5171 509.6356 509.7541 509.8726 509.9911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191205T074854.0Z 7278.325625 435 1 32.00 2 89.74 115.73 158.93 354.53 0.00 1 0.00 1 0 204 6.925e-01 7.003e-01 3.975e-02 3.366e-02 6.826775e+04 3.875737e+03 2.070281e+04 -6.000000e+00 3.807642e+04 274.61 -2.00 20.00 -2.00 504.19 0.00e+00 1.580326e-01 9.196401e-04 3.277063e-03 -6.000000e+00 1.949637e-02 274.61 -2.00 20.00 -2.00 501.58 0.00e+00 3.038767e+01 9.242679e-01 2.658029e+00 -6.000000e+00 1.384040e+01 223.39 -2.00 3.19 -2.00 502.68 0.00e+00 20.549 0.090 489.00 513.00 1 5.6821e+00 6.8363e-02 1.8583e-01 -6.0000e+00 1.0573e+00 -6.5548e-01 1.8675e-02 3.7988e-02 -6.0000e+00 2.8417e-01 4.8967e-06 -5.5480e-01 8.4226e-04 2.3247e-02 -6.0000e+00 7.7111e-02 -9.1340e-02 1.2411e-02 12 12 12 10 0 0 53.05 16.99 3.53 -0.09134 -3.93969 8 2 1 4 0 4000.000 21.48 15.00 16.99 -58338 -50482 -47670 -40030 -41420 -25620 -16914 280 10929 14649 39644 30829 43046 47662 46638 20782 17598 3239 5295 4011 18480 20200 38443 32953 30834 33475 15619 5845 -2341 12423 -3934 -5327 -21885 -17516 -37554 -30983 -38708 -30275 -41038 -43045 -31699 -31953 -9054 2854 -6092 -13648 -3833 -11344 -36683 -21993 -631 -3442 6552 16218 384 -5661 4055 18684 18221 42809 49085 80226 83950 87363 90683 96572 97870 94686 106104 109970 126014 115825 130445 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123108 -467785 124570 120856 117671 115544 108363 106991 104117 99072 94606 90719 86456 84026 81139 76557 75808 70158 64850 60585 54177 44399 35628 38037 18469 7980 2645 3903 -12023 3531 13168 16975 8449 5968 -2933 -5559 -4435 -7553 -20832 -47427 -31981 -35413 -31565 -43176 -39663 -51912 -28815 -28796 -13685 6246 9929 20677 22320 36688 37130 46942 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 SO 20191205T075351.0Z 7278.329062 440 1 32.00 2 88.76 116.33 158.98 357.80 0.00 1 0.00 1 0 106 5.224e-01 6.382e-01 3.049e-02 2.733e-02 3.324556e+05 3.793709e+03 1.677235e+04 -6.000000e+00 2.878025e+04 274.61 -2.00 20.00 -2.00 504.38 0.00e+00 -4.529863e-02 8.601919e-04 2.562733e-03 -6.000000e+00 1.475734e-02 274.61 -2.00 20.00 -2.00 501.28 0.00e+00 -9.850425e+01 6.508252e-01 1.767397e+00 -6.000000e+00 1.055294e+01 223.39 -2.00 3.19 -2.00 502.50 0.00e+00 18.467 0.065 489.00 513.00 1 1.7955e+01 4.7771e-02 1.2532e-01 -6.0000e+00 8.0459e-01 1.7905e+00 1.5439e-02 2.2482e-02 -6.0000e+00 2.1912e-01 6.4067e-06 -1.5367e-01 5.3260e-04 1.6240e-02 -6.0000e+00 5.8449e-02 -5.9394e-01 1.5843e-02 12 13 12 11 256 0 -13.67 17.00 1.51 -0.59394 -1.65988 8 2 1 4 0 4000.000 21.58 15.00 17.00 37377 35001 39310 35670 33466 27865 28131 20464 14250 13737 16232 16203 19557 34603 27089 26198 27655 20216 14704 7588 6092 4676 7666 -6123 -2219 -3644 -8762 -7952 -1850 13776 9801 10311 1413 -5074 -14053 -11103 -14161 -6773 -18411 -13771 -12035 -14320 -11535 -6621 -21692 -26941 -19155 -17630 -32860 -9359 3231 7413 9638 15119 16776 -188 18610 11458 14808 14360 13272 24247 23853 24606 29558 32860 33871 43450 55706 64511 61202 54019 50953 54672 46611 56864 72096 68320 87388 95944 -107604 89660 81856 83588 77724 81150 74743 43700 21272 -7086 -39677 -29189 -30568 -27320 -21321 10504 46105 80336 119348 137983 142836 140990 144955 128852 113280 116808 96442 75221 69641 76219 78384 89036 88830 77827 61185 44330 36953 16963 16607 15555 28276 18067 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107.68 0.00 1 0.00 1 0 15 3.602e-02 4.498e-02 3.608e-03 3.592e-03 3.308322e+03 2.232685e+02 5.520270e+01 -6.000000e+00 1.962910e+03 274.58 -2.00 20.00 -2.00 505.21 0.00e+00 1.725745e-03 9.694467e-05 7.462365e-05 -6.000000e+00 9.916486e-04 274.58 -2.00 20.00 -2.00 500.28 0.00e+00 -9.935706e-01 7.207060e-02 7.732830e-02 -6.000000e+00 7.149688e-01 223.38 -2.00 3.19 -2.00 501.89 0.00e+00 2.445 0.000 489.00 513.00 1 9.8994e+00 5.5126e-03 6.6656e-03 -6.0000e+00 5.4654e-02 4.6730e-02 1.4302e-03 1.2295e-03 -6.0000e+00 1.4257e-02 7.8956e-05 -3.2288e-04 3.5668e-04 2.7611e-05 -6.0000e+00 3.6756e-03 -8.9235e-03 2.9781e-04 12 8 8 10 0 0 99.73 16.97 1.33 -0.00892 -0.01116 8 2 1 4 0 4000.000 21.69 15.00 16.97 506 668 966 1002 1265 1450 1420 1403 488 180 520 -151 169 905 -1207 -174 -622 -8 -197 20 -438 -225 49 258 111 -365 189 -1267 -706 -1299 -324 -1265 135 -927 -297 -1219 -1248 -119 -764 -587 -182 316 -282 1292 61 715 185 1119 -285 645 -90 438 163 1024 1124 288 1752 253 1202 663 1190 1334 2102 937 2013 841 1329 803 1508 294 1170 1092 1299 1482 1078 2247 1166 1333 284 1155 -41447 1540 634 2487 1150 1282 1769 925 699 782 449 1526 1352 433 780 268 -758 -1893 -327 -559 -1056 -642 318 631 169 1937 466 756 372 1719 1045 669 323 1369 1293 1467 1861 1289 1222 973 1794 926 2026 465 -124 741 870 303 1832 -311 -344 259 386 -36 967 1630 2 496 612 205 -977 -122 -252 623 -583 398 -1971 -543 -1148 -1481 900000 496 658 970 1029 1320 1536 1516 1508 526 193 548 -159 175 920 -1239 -178 -643 -9 -209 21 -469 -241 52 275 119 -391 202 -1349 -735 -1330 -325 -1279 137 -971 -314 -1306 -1327 -124 -796 -609 -188 327 -294 1350 64 753 195 1161 -294 651 -90 426 157 989 1103 291 1778 261 1230 681 1217 1368 2148 963 2038 850 1325 794 1473 287 1130 1053 1264 1452 1063 2185 1128 1271 271 1094 -52598 1461 609 2370 1117 1248 1717 906 682 765 442 1509 1349 435 777 263 -737 -1823 -306 -518 -980 -600 301 613 167 1894 456 730 358 1648 1014 659 321 1358 1291 1463 1856 1294 1217 961 1740 892 1928 449 -120 713 839 292 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