File name: Pandora101s1_Izana_20191220_L2Fit_fout2c18d20191026p1-8.txt File generation date: 20240504T165202.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v5d20170928.txt Instrument calibration file used: Pandora101s1_CF_v18d20191026.txt Level 1 file used: Pandora101s1_Izana_20191220_L1_smca1c18d20191026p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20191220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 baseline for VP20191026 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0349 305.1758 305.3166 305.4574 305.5982 305.7390 305.8798 306.0206 306.1614 306.3021 306.4428 306.5836 306.7243 306.8650 307.0057 307.1464 307.2870 307.4277 307.5683 307.7090 307.8496 307.9902 308.1308 308.2714 308.4120 308.5525 308.6931 308.8336 308.9742 309.1147 309.2552 309.3957 309.5362 309.6766 309.8171 309.9576 310.0980 310.2384 310.3788 310.5192 310.6596 310.8000 310.9404 311.0807 311.2211 311.3614 311.5018 311.6421 311.7824 311.9227 312.0629 312.2032 312.3435 312.4837 312.6239 312.7641 312.9044 313.0445 313.1847 313.3249 313.4651 313.6052 313.7454 313.8855 314.0256 314.1657 314.3058 314.4459 314.5859 314.7260 314.8660 315.0061 315.1461 315.2861 315.4261 315.5661 315.7061 315.8460 315.9860 316.1259 316.2659 316.4058 316.5457 316.6856 316.8255 316.9653 317.1052 317.2450 317.3849 317.5247 317.6645 317.8043 317.9441 318.0839 318.2236 318.3634 318.5031 318.6429 318.7826 318.9223 319.0620 319.2017 319.3413 319.4810 319.6206 319.7603 319.8999 320.0395 320.1791 320.3187 320.4583 320.5978 320.7374 320.8769 321.0165 321.1560 321.2955 321.4350 321.5745 321.7139 321.8534 321.9929 322.1323 322.2717 322.4111 322.5505 322.6899 322.8293 322.9687 323.1080 323.2474 323.3867 323.5260 323.6653 323.8046 323.9439 324.0832 324.2224 324.3617 324.5009 324.6401 324.7793 324.9185 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191220T121421.9Z 7293.509976 317 1 31.86 2 53.07 165.88 65.17 253.31 0.00 1 0.00 1 0 17 8.558e-03 6.068e-03 1.295e-04 8.093e-05 2.071885e-01 4.002058e-05 2.330575e-03 -6.000000e+00 4.705714e-03 223.10 -2.00 3.19 -2.00 315.29 0.00e+00 4.755972e-04 3.577968e-06 2.199720e-05 -6.000000e+00 2.030130e-04 273.71 -2.00 20.00 -2.00 314.82 0.00e+00 1.661 0.000 302.00 328.00 3 -1.4281e-01 1.0208e-04 1.5702e-02 -6.0000e+00 1.1615e-02 3.0689e-03 1.1381e-04 9.4661e-03 -6.0000e+00 1.2663e-02 4.4511e-03 6.5557e-05 4.7345e-03 -6.0000e+00 7.5282e-03 -3.9176e-03 3.0093e-05 1.3967e-03 -6.0000e+00 3.2436e-03 1.3713e-01 -3.6893e-04 2.1513e-06 1.6505e-05 -6.0000e+00 2.1465e-04 -6.3076e-03 0.0000e+00 10 0 0 10 0 0 7.54 17.18 0.30 -0.00631 -0.00908 5429 1282 1 5 0 5.830 21.69 15.00 17.18 -936 -911 -681 -2055 -3313 -2937 -1760 -292 400 -630 -1959 -2090 -1156 -454 186 119 32 282 722 1246 991 513 958 960 584 472 396 84 -180 238 949 1547 1721 404 -1591 -1710 -1548 -461 -100 176 -459 -501 -445 -544 136 -163 -211 -218 -556 -210 542 851 1238 999 841 888 865 551 532 465 712 1086 1331 1380 566 -43 -571 -736 -86 187 22 -9 -200 65 6 -162 -791 -1348 -1086 -1117 -1243 -1526 -1994 -1649 -1207 -635 -264 -11 395 453 235 79 -155 -51 -87 -10 136 860 520 269 -174 -502 -418 50 -318 -598 -532 -441 -192 391 597 514 521 292 40 24 83 265 296 181 -81 0 261 273 589 555 248 815 510 515 249 64 -175 -102 -246 -173 -152 70 34 -219 -362 -465 -653 -267 -266 -204 -594 -914 -738 -449 -82 117 -198 -610 -637 -381 -169 73 51 14 129 339 561 460 236 436 457 295 249 210 42 -89 111 454 737 882 221 -829 -832 -796 -271 -62 122 -353 -382 -348 -432 106 -128 -162 -171 -423 -156 414 658 1007 854 706 756 751 480 453 391 607 982 1242 1380 554 -41 -517 -630 -75 177 22 -10 -215 68 6 -151 -690 -1145 -925 -1008 -1207 -1569 -2115 -1812 -1402 -759 -321 -14 501 560 282 90 -167 -54 -90 -11 156 1040 657 342 -217 -598 -482 59 -389 -754 -697 -579 -262 542 841 741 727 394 51 29 104 328 391 250 -113 0 363 367 776 697 306 972 644 671 330 86 -240 -144 -353 -254 -230 104 52 -328 -543 -673 -951 SU 20191220T121941.9Z 7293.513679 321 1 31.76 2 52.80 167.37 66.27 254.05 0.00 1 0.00 1 0 17 8.574e-03 6.059e-03 1.286e-04 8.055e-05 2.060729e-01 3.977971e-05 2.319608e-03 -6.000000e+00 4.714205e-03 223.10 -2.00 3.19 -2.00 315.28 0.00e+00 4.682619e-04 3.545116e-06 2.179268e-05 -6.000000e+00 2.033788e-04 273.71 -2.00 20.00 -2.00 314.81 0.00e+00 1.650 0.000 302.00 328.00 3 -1.4133e-01 1.0147e-04 1.5612e-02 -6.0000e+00 1.1636e-02 3.9647e-03 1.1319e-04 9.4184e-03 -6.0000e+00 1.2686e-02 4.4999e-03 6.5138e-05 4.7105e-03 -6.0000e+00 7.5418e-03 -4.1841e-03 2.9883e-05 1.3889e-03 -6.0000e+00 3.2494e-03 1.3823e-01 -3.7321e-04 2.1387e-06 1.6368e-05 -6.0000e+00 2.1503e-04 -6.3614e-03 0.0000e+00 10 0 0 10 0 0 6.00 17.17 0.30 -0.00636 -0.00917 5449 1286 1 5 0 5.808 21.69 15.00 17.17 -905 -959 -599 -2164 -3223 -3097 -1615 -360 484 -723 -1972 -2095 -1121 -408 164 164 -8 335 691 1278 936 556 937 992 543 519 392 136 -164 197 958 1531 1770 373 -1588 -1771 -1491 -508 -72 129 -430 -545 -487 -528 125 -171 -225 -184 -570 -194 509 866 1210 1004 805 916 878 558 536 462 704 1082 1318 1369 568 -42 -545 -751 -68 166 46 -31 -205 55 26 -182 -788 -1338 -1084 -1110 -1264 -1504 -1993 -1630 -1211 -622 -271 -11 391 454 220 77 -157 -61 -89 -7 148 852 532 242 -161 -510 -399 41 -325 -593 -514 -448 -182 386 577 520 518 291 42 30 61 265 291 186 -87 8 260 273 591 554 259 800 527 514 247 55 -175 -111 -237 -194 -150 75 41 -228 -366 -458 -652 -241 -283 -181 -633 -898 -787 -416 -103 143 -229 -620 -645 -372 -153 65 71 -4 154 327 579 438 257 430 475 276 275 209 69 -76 93 460 733 912 205 -831 -867 -770 -281 -45 90 -332 -417 -383 -420 98 -135 -174 -145 -436 -145 390 671 987 860 677 781 764 487 458 389 601 980 1233 1372 556 -40 -494 -643 -60 157 46 -33 -220 58 26 -169 -688 -1138 -924 -1002 -1227 -1545 -2113 -1790 -1406 -742 -329 -14 495 561 265 88 -169 -65 -92 -8 170 1029 670 306 -200 -607 -460 47 -397 -745 -673 -588 -248 534 811 749 748 392 55 37 76 327 384 255 -120 11 361 366 777 695 318 952 664 668 326 75 -239 -156 -339 -284 -227 112 63 -341 -548 -661 -946 SU 20191220T122417.9Z 7293.516874 324 1 31.84 2 52.59 168.67 67.23 254.68 0.00 1 0.00 1 0 17 8.563e-03 6.078e-03 1.277e-04 8.062e-05 2.049818e-01 3.989766e-05 2.305967e-03 -6.000000e+00 4.708138e-03 223.10 -2.00 3.19 -2.00 315.24 0.00e+00 4.770093e-04 3.525084e-06 2.218554e-05 -6.000000e+00 2.031173e-04 273.71 -2.00 20.00 -2.00 314.77 0.00e+00 1.642 0.000 302.00 328.00 3 -1.3132e-01 1.0171e-04 1.5532e-02 -6.0000e+00 1.1621e-02 3.6106e-03 1.1343e-04 9.3642e-03 -6.0000e+00 1.2670e-02 4.4231e-03 6.5320e-05 4.6833e-03 -6.0000e+00 7.5321e-03 -4.1168e-03 2.9890e-05 1.3831e-03 -6.0000e+00 3.2452e-03 1.3797e-01 -3.6963e-04 2.1406e-06 1.6298e-05 -6.0000e+00 2.1476e-04 -6.3121e-03 0.0000e+00 10 0 0 10 0 0 10.17 17.17 0.29 -0.00631 -0.00909 5370 1268 1 5 0 5.896 21.69 15.00 17.17 -956 -804 -620 -2083 -3280 -2973 -1731 -252 411 -644 -2002 -2076 -1197 -387 215 188 43 269 730 1251 969 519 987 922 574 474 405 126 -133 249 952 1561 1778 410 -1595 -1706 -1551 -486 -101 147 -454 -509 -497 -547 128 -189 -212 -183 -543 -196 542 856 1224 960 827 894 883 547 540 455 690 1089 1321 1381 585 -44 -567 -730 -130 164 25 -8 -202 57 24 -171 -783 -1352 -1086 -1127 -1250 -1541 -1985 -1630 -1195 -627 -260 -18 403 460 252 62 -159 -57 -84 -11 158 854 513 246 -179 -516 -429 56 -326 -595 -532 -473 -173 395 584 515 522 300 54 34 75 258 297 183 -86 3 260 270 594 572 250 807 518 507 235 57 -169 -112 -237 -189 -149 72 38 -228 -358 -473 -638 -258 -240 -190 -616 -926 -765 -452 -73 123 -207 -638 -647 -403 -147 86 83 20 125 326 573 457 242 457 446 295 254 218 64 -62 118 462 753 923 227 -841 -841 -807 -271 -63 103 -353 -392 -394 -439 101 -149 -165 -145 -417 -147 418 668 1004 828 700 766 773 481 464 385 593 992 1243 1328 576 -42 -516 -629 -115 156 25 -9 -208 60 24 -159 -687 -1155 -930 -1022 -1219 -1590 -2113 -1797 -1335 -752 -317 -22 513 570 304 71 -172 -57 -87 -12 181 1035 648 312 -224 -617 -496 66 -400 -751 -672 -623 -237 547 824 743 729 405 69 42 93 319 393 252 -119 4 349 363 783 719 309 964 653 660 311 77 -232 -152 -340 -277 -225 108 58 -342 -538 -685 -928 SU 20191220T122937.0Z 7293.520567 328 1 31.91 2 52.38 170.18 68.34 255.39 0.00 1 0.00 1 0 17 8.522e-03 6.083e-03 1.270e-04 8.073e-05 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