File name: Pandora101s1_Izana_20200721_L2Fit_fout2c15d20200721p1-8.txt File generation date: 20240504T144136.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20200721_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0057 305.1465 305.2873 305.4282 305.5690 305.7098 305.8506 305.9914 306.1321 306.2729 306.4136 306.5544 306.6951 306.8358 306.9765 307.1172 307.2579 307.3986 307.5392 307.6799 307.8205 307.9611 308.1017 308.2423 308.3829 308.5235 308.6641 308.8046 308.9452 309.0857 309.2262 309.3667 309.5072 309.6477 309.7882 309.9286 310.0691 310.2095 310.3500 310.4904 310.6308 310.7712 310.9116 311.0519 311.1923 311.3326 311.4730 311.6133 311.7536 311.8939 312.0342 312.1745 312.3147 312.4550 312.5952 312.7355 312.8757 313.0159 313.1561 313.2963 313.4365 313.5766 313.7168 313.8569 313.9970 314.1371 314.2773 314.4173 314.5574 314.6975 314.8376 314.9776 315.1176 315.2577 315.3977 315.5377 315.6777 315.8176 315.9576 316.0976 316.2375 316.3774 316.5173 316.6573 316.7972 316.9370 317.0769 317.2168 317.3566 317.4965 317.6363 317.7761 317.9159 318.0557 318.1955 318.3352 318.4750 318.6147 318.7545 318.8942 319.0339 319.1736 319.3133 319.4529 319.5926 319.7323 319.8719 320.0115 320.1511 320.2907 320.4303 320.5699 320.7095 320.8490 320.9886 321.1281 321.2676 321.4072 321.5466 321.6861 321.8256 321.9651 322.1045 322.2440 322.3834 322.5228 322.6622 322.8016 322.9410 323.0803 323.2197 323.3591 323.4984 323.6377 323.7770 323.9163 324.0556 324.1949 324.3341 324.4734 324.6126 324.7519 324.8911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200721T063852.0Z 7507.276990 35 1 49.92 2 87.46 68.18 94.14 63.05 0.00 1 0.00 1 0 25 9.609e-01 8.588e-02 4.171e-01 4.681e-02 1.072663e+00 2.906127e-02 1.092725e-02 -6.000000e+00 5.715764e-01 228.00 -2.00 3.19 -2.00 322.04 0.00e+00 -2.739895e-02 9.958131e-03 5.142063e-03 -6.000000e+00 3.090051e-02 281.99 -2.00 20.00 -2.00 321.42 0.00e+00 14.803 0.033 302.00 328.00 3 -5.3655e-02 9.1875e-02 1.3430e-01 -6.0000e+00 1.4167e+00 2.5907e+00 1.1134e-01 9.4569e-02 -6.0000e+00 1.5447e+00 -2.4314e+00 7.5458e-02 2.8341e-02 -6.0000e+00 8.9931e-01 7.6281e-01 4.0247e-02 2.0772e-02 -6.0000e+00 3.9537e-01 1.9698e-06 1.9006e-03 1.2278e-03 2.4389e-04 -6.0000e+00 2.6773e-02 2.2072e-03 0.0000e+00 12 8 8 10 0 0 -19.96 16.93 1.60 0.00221 0.01649 15 4 1 5 0 3327.590 21.58 14.98 16.93 900000 57073 900000 900000 900000 900000 900000 900000 900000 28327 -28556 11587 38471 900000 52670 900000 40431 114960 -14639 900000 900000 900000 329447 274722 249387 80663 900000 16077 106809 -90368 900000 -7758 900000 114319 144069 -52829 900000 -39062 345601 900000 197721 240820 374800 254726 25807 -41685 900000 -35634 -14175 900000 -54332 -21206 39245 115962 218209 90158 35725 900000 49405 42984 55733 10485 -63288 3390 24211 48276 -8738 51417 -4142 8266 8798 418031 -1034 9973 77352 24775 -40514 -65941 -19834 -15995 17703 37397 12652 -107 8371 25757 30204 51257 67481 8037 16581 11646 -6641 67631 -33013 802 13609 1485 11061 16750 631 7583 -27034 -898 15523 -10104 -11072 -14932 1497 6632 12864 -672 14364 -3270 -11448 4403 3890 5972 -11404 5100 -4831 13524 2998 1154 -3956 -6610 1839 735 2944 1800 1870 -1959 -143 -590 1396 -5689 1243 2484 361 1069 -1476 2944 -1192 900000 6130 900000 900000 900000 900000 900000 900000 900000 2926 -5191 1388 3655 900000 4787 900000 4343 5699 -2540 900000 900000 900000 14971 12484 11333 5665 900000 1660 4854 -19040 900000 -865 900000 5195 6547 -8294 900000 -6132 15705 900000 8985 10944 17032 11576 2772 -7922 900000 -5741 -1874 900000 -12345 -3855 4637 6851 9916 7785 5520 900000 5837 4688 4812 1429 -18041 616 3851 5923 -1866 6309 -979 1991 2319 18997 -301 2357 8085 3715 -10494 -22175 -4687 -4361 4103 8327 4082 -42 3157 8545 9883 13743 15026 3068 5350 3705 -2505 12908 -19953 412 7236 1039 7220 11722 446 4859 -19321 -518 8112 -7255 -8403 -11535 1101 5452 11692 -788 15370 -4229 -15701 4984 4420 6933 -16631 6531 -6646 14471 3369 1292 -4559 -7646 1892 799 3709 2767 3322 -4030 -314 -1424 3611 -16921 3539 7071 1050 2963 -3860 6713 -2654 SS 20200721T065147.2Z 7507.285963 40 1 48.46 2 84.81 69.65 91.70 64.59 0.00 1 0.00 1 0 17 6.909e-01 1.565e-02 1.612e-01 3.470e-03 9.687843e-01 1.949709e-03 9.765168e-03 -6.000000e+00 3.882233e-01 228.00 -2.00 3.19 -2.00 322.03 0.00e+00 3.889635e-03 1.133526e-03 1.851588e-03 -6.000000e+00 1.721382e-02 281.99 -2.00 20.00 -2.00 321.59 0.00e+00 9.598 0.009 302.00 328.00 3 3.5613e-01 7.6351e-03 8.7778e-02 -6.0000e+00 9.6637e-01 6.2443e-01 1.1725e-02 5.1343e-02 -6.0000e+00 1.0473e+00 -9.1332e-01 1.2311e-02 2.9087e-02 -6.0000e+00 6.2382e-01 3.7285e-01 5.5345e-03 1.0813e-02 -6.0000e+00 2.6957e-01 1.0267e-04 -8.9802e-04 8.4638e-05 1.4070e-04 -6.0000e+00 1.7498e-02 5.7245e-04 0.0000e+00 12 9 8 11 8 0 -1.01 16.95 0.25 0.00057 -0.00618 194 46 1 5 0 249.796 21.58 15.00 16.95 -218441 -227440 -220512 900000 -246988 -143901 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1481 527 932 -63 81 476 364 567 933 1022 1053 2396 1723 2539 1638 2331 1528 1593 890 1158 910 739 1847 2212 2552 1644 2270 1518 2626 1982 3650 1670 1628 768 59 -754 -1064 -614 -749 495 24 1125 -109 870 267 1900 579 1565 256 940 -670 -873 -806 -2059 -1247 -1458 -929 -1433 -406 -1632 -1265 -2448 -932 -2613 -1917 -2320 -2021 -1759 -1224 -195 16 617 304 -683 -501 263 -629 644 368 1239 1250 2221 1620 1806 1488 1133 1194 392 1326 568 1645 -129 713 -1499 104 -284 893 410 -448 -919 -992 -2280 SS 20200721T070344.3Z 7507.294263 44 1 48.61 2 82.33 70.96 89.41 65.96 0.00 1 0.00 1 0 17 6.352e-01 1.031e-02 3.236e-02 9.485e-04 7.715473e-01 5.055848e-04 8.057360e-03 -6.000000e+00 3.569656e-01 228.00 -2.00 3.19 -2.00 321.14 0.00e+00 2.633388e-03 2.373485e-04 2.468280e-03 -6.000000e+00 1.561113e-02 281.99 -2.00 20.00 -2.00 320.62 0.00e+00 6.988 0.003 302.00 328.00 3 2.9621e-01 1.6713e-03 6.5422e-02 -6.0000e+00 8.8848e-01 1.2668e-01 2.3496e-03 3.9747e-02 -6.0000e+00 9.6291e-01 -2.0033e-01 2.4705e-03 2.1661e-02 -6.0000e+00 5.7314e-01 7.7435e-02 1.1807e-03 7.0462e-03 -6.0000e+00 2.4696e-01 8.8342e-04 -3.5572e-04 2.3665e-05 9.1557e-05 -6.0000e+00 1.5936e-02 -8.0196e-06 0.0000e+00 12 8 8 10 0 0 -11.67 16.96 0.19 -0.00001 -0.00268 627 148 1 5 0 77.399 21.58 15.01 16.96 -234406 -186010 -216238 -175876 -217177 -207715 -213781 -193507 -180962 -181231 -169077 -165820 -141630 -117528 -92351 -99361 -51711 -72515 -44287 -55019 -37502 -57320 -51685 -46305 -33223 -38180 -33132 -37147 -45813 -36524 -33472 -18838 -13590 -2684 -12796 -10206 -14489 -6772 -4673 4757 3248 5826 7064 6960 7193 4188 6482 3622 5310 4486 7484 5951 8966 6985 8026 6648 5675 5376 3888 4020 2635 4199 4285 6245 5483 5195 2236 2955 1718 2814 2512 2850 1404 888 1174 -692 -1547 -2994 -1883 -1907 -972 -1402 -1399 -1736 -1355 -721 68 169 530 767 292 -134 -1025 -1237 -1561 -839 -807 324 72 36 -671 -856 -1228 -921 -1200 -1385 -1144 -923 -388 206 672 531 646 378 125 -49 -66 177 112 35 54 287 588 649 535 599 -128 631 181 429 303 299 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