File name: Pandora101s1_Izana_20200817_L2Fit_fout2c15d20200721p1-8.txt File generation date: 20240504T142544.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20200817_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20200817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0057 305.1465 305.2873 305.4282 305.5690 305.7098 305.8506 305.9914 306.1321 306.2729 306.4136 306.5544 306.6951 306.8358 306.9765 307.1172 307.2579 307.3986 307.5392 307.6799 307.8205 307.9611 308.1017 308.2423 308.3829 308.5235 308.6641 308.8046 308.9452 309.0857 309.2262 309.3667 309.5072 309.6477 309.7882 309.9286 310.0691 310.2095 310.3500 310.4904 310.6308 310.7712 310.9116 311.0519 311.1923 311.3326 311.4730 311.6133 311.7536 311.8939 312.0342 312.1745 312.3147 312.4550 312.5952 312.7355 312.8757 313.0159 313.1561 313.2963 313.4365 313.5766 313.7168 313.8569 313.9970 314.1371 314.2773 314.4173 314.5574 314.6975 314.8376 314.9776 315.1176 315.2577 315.3977 315.5377 315.6777 315.8176 315.9576 316.0976 316.2375 316.3774 316.5173 316.6573 316.7972 316.9370 317.0769 317.2168 317.3566 317.4965 317.6363 317.7761 317.9159 318.0557 318.1955 318.3352 318.4750 318.6147 318.7545 318.8942 319.0339 319.1736 319.3133 319.4529 319.5926 319.7323 319.8719 320.0115 320.1511 320.2907 320.4303 320.5699 320.7095 320.8490 320.9886 321.1281 321.2676 321.4072 321.5466 321.6861 321.8256 321.9651 322.1045 322.2440 322.3834 322.5228 322.6622 322.8016 322.9410 323.0803 323.2197 323.3591 323.4984 323.6377 323.7770 323.9163 324.0556 324.1949 324.3341 324.4734 324.6126 324.7519 324.8911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200817T070545.2Z 7534.295662 92 1 48.45 2 84.69 77.81 61.40 78.50 0.00 1 0.00 1 0 28 6.579e-01 1.629e-02 1.545e-01 3.579e-03 9.068891e-01 1.973653e-03 9.307571e-03 -6.000000e+00 3.690515e-01 227.57 -2.00 3.19 -2.00 321.93 0.00e+00 4.236711e-03 1.125050e-03 3.934196e-03 -6.000000e+00 1.616821e-02 281.97 -2.00 20.00 -2.00 321.47 0.00e+00 9.441 0.009 302.00 328.00 3 6.4558e-01 7.5858e-03 8.6170e-02 -6.0000e+00 9.1765e-01 5.4205e-01 1.1247e-02 5.0948e-02 -6.0000e+00 9.9493e-01 -7.7940e-01 1.1537e-02 2.8657e-02 -6.0000e+00 5.9238e-01 3.1676e-01 5.2486e-03 9.5773e-03 -6.0000e+00 2.5540e-01 9.2271e-05 -8.5544e-04 8.8846e-05 1.4402e-04 -6.0000e+00 1.6504e-02 1.9061e-03 0.0000e+00 12 8 8 10 0 0 -6.43 16.97 0.21 0.00191 -0.00452 154 36 1 5 0 314.606 21.58 15.01 16.97 -122959 -229625 -112208 -198169 -135988 -218094 -196949 -204994 -108094 -246878 -156946 -214781 -176928 -138069 -142193 -123490 -104455 -42565 -125159 -34349 -82908 32913 -82786 -50158 -68606 -30603 -63460 -65096 -84624 -82278 -18996 -44671 14153 -21485 2982 -34870 14356 -34859 30533 11951 31414 15552 18799 18060 16717 13315 16224 19544 10485 29507 9912 33291 20940 32360 25371 26694 14392 23018 13348 13136 15956 8659 9906 14571 19824 12582 14420 10556 14046 6271 10297 9852 8401 5970 6781 757 -1883 -3702 -3755 3127 133 3162 -1146 2034 -1846 1377 481 1345 244 421 -244 -704 -1202 -2106 -3409 -2796 -1988 -1839 -726 -373 -758 -2539 -2283 -2937 -1958 -2759 -2082 -1911 -1681 -154 -228 177 348 182 -728 434 -190 474 -244 731 408 1423 1019 1241 1444 920 518 953 729 316 750 401 259 -302 -345 -389 108 197 273 78 -213 -529 -1228 -601 -3643 -666 -2515 -902 -2699 -2000 -2472 -604 -5406 -1589 -3817 -2751 -1972 -2798 -2547 -2088 -565 -3773 -480 -1736 230 -1821 -858 -1533 -491 -1440 -1454 -2216 -2212 -332 -1294 277 -620 73 -1156 301 -1250 767 442 1108 637 787 785 737 617 752 918 579 1461 670 2050 1635 2485 2262 2465 1562 2301 1411 1321 1544 970 1267 2095 2803 1958 2190 1735 2443 1379 2474 2528 2192 1504 1533 160 -374 -754 -860 819 44 1191 -515 954 -881 679 253 727 134 225 -124 -336 -604 -1016 -1892 -1848 -1558 -1700 -708 -382 -749 -2472 -1936 -2362 -1656 -2529 -1992 -1822 -1771 -185 -319 257 530 279 -1089 659 -289 696 -382 1192 664 2170 1580 1867 2104 1311 713 1323 1088 562 1520 842 584 -734 -855 -1031 292 538 750 209 -531 -1288 -2808 SS 20200817T071757.3Z 7534.304135 96 1 48.53 2 82.06 79.20 58.85 79.62 0.00 1 0.00 1 0 25 5.182e-01 8.879e-03 2.945e-02 9.107e-04 7.129454e-01 4.780720e-04 7.454567e-03 -6.000000e+00 2.907248e-01 227.57 -2.00 3.19 -2.00 320.89 0.00e+00 2.169908e-03 2.095978e-04 1.840533e-03 -6.000000e+00 1.273536e-02 281.97 -2.00 20.00 -2.00 320.34 0.00e+00 6.782 0.003 302.00 328.00 3 4.7384e-01 1.5303e-03 6.2019e-02 -6.0000e+00 7.2289e-01 8.1680e-02 2.0824e-03 3.5736e-02 -6.0000e+00 7.8374e-01 -1.2792e-01 2.1430e-03 1.9309e-02 -6.0000e+00 4.6664e-01 4.5456e-02 1.0445e-03 6.3159e-03 -6.0000e+00 2.0121e-01 9.2185e-04 -2.6361e-04 2.2878e-05 7.2173e-05 -6.0000e+00 1.3000e-02 1.2314e-03 0.0000e+00 11 8 0 10 0 0 -0.90 16.97 0.19 0.00123 -0.00075 576 136 1 5 0 84.242 21.58 15.01 16.97 -176527 -181186 -143185 -165558 -166567 -179808 -187915 -158890 -157641 -137514 -147056 -128951 -125422 -79045 -72101 -64723 -56991 -38495 -44514 -25221 -38546 -39955 -36990 -34932 -25891 -30240 -21190 -31585 -24224 -34373 -16843 -16728 -4381 -8520 -6279 -11531 -10511 -7332 -889 4740 1989 6367 2422 5189 3501 3680 2851 4183 1352 4570 4013 4363 5450 4859 5721 4448 4906 3644 3661 2318 2960 3035 4023 4696 4544 3005 2332 997 959 1337 1231 1647 397 715 -190 -284 -2345 -2820 -2507 -1498 -1382 -1045 -1901 -1845 -1304 -626 83 -48 826 631 636 -43 -566 -1026 -896 -866 -292 332 388 88 -386 -933 -973 -702 -995 -1178 -1024 -642 -379 456 575 614 637 380 -15 37 14 125 152 23 -62 117 466 358 521 368 21 475 226 332 307 44 -210 -136 -474 -204 -86 308 262 -12 -141 -211 -392 -1521 -2044 -1246 -1853 -1731 -2012 -2420 -1764 -2016 -1612 -2011 -1603 -1894 -997 -1108 -1161 -1109 -701 -957 -479 -880 -926 -851 -869 -655 -865 -578 -943 -652 -1065 -519 -642 -179 -376 -269 -493 -472 -375 -53 331 167 561 237 513 357 384 309 464 163 570 559 635 876 865 1093 906 1041 795 778 482 615 680 1022 1370 1470 991 753 333 346 518 544 773 191 327 -81 -108 -894 -1064 -948 -670 -739 -648 -1242 -1289 -963 -492 68 -41 712 532 504 -32 -401 -731 -704 -793 -290 381 470 112 -469 -1096 -1014 -699 -1065 -1356 -1156 -769 -492 623 888 977 1042 611 -25 57 21 197 240 38 -103 187 753 563 788 539 30 663 353 566 554 87 -434 -283 -1062 -463 -201 727 625 -28 -325 -452 -795 SS 20200817T073327.3Z 7534.314899 101 1 48.58 2 78.70 80.94 55.60 81.05 0.00 1 0.00 1 0 25 1.589e-01 6.157e-03 6.677e-03 3.677e-04 5.449092e-01 1.861192e-04 5.766376e-03 -6.000000e+00 8.915771e-02 227.57 -2.00 3.19 -2.00 319.70 0.00e+00 1.268070e-03 5.599992e-05 4.848830e-04 -6.000000e+00 3.905367e-03 281.97 -2.00 20.00 -2.00 319.07 0.00e+00 4.938 0.001 302.00 328.00 3 3.6122e-01 5.3096e-04 4.5421e-02 -6.0000e+00 2.2169e-01 1.3815e-02 6.3907e-04 2.5818e-02 -6.0000e+00 2.4035e-01 -2.4680e-02 5.5349e-04 1.3104e-02 -6.0000e+00 1.4310e-01 2.5917e-03 2.9116e-04 4.1051e-03 -6.0000e+00 6.1709e-02 4.6246e-03 -1.7109e-04 9.5689e-06 3.9779e-05 -6.0000e+00 3.9865e-03 8.7592e-04 0.0000e+00 10 0 0 10 0 0 -10.35 16.98 0.21 0.00088 -0.00041 1356 320 1 5 0 35.773 21.58 15.01 16.98 -61472 -53699 -47435 -49490 -57452 -60177 -62021 -49076 -46283 -39266 -41168 -38825 -34144 -23115 -17129 -11711 -10912 -7684 -6726 -5208 -5545 -6730 -5615 -5443 -3808 -5437 -4399 -7013 -7202 -8122 -4218 -2715 -196 -650 -3455 -5165 -4874 -2610 -722 1097 570 788 572 910 852 1116 681 870 39 224 1095 1482 1977 1768 1762 1570 1464 1055 740 236 786 1401 2133 2545 2020 1037 184 -341 140 879 789 740 205 275 -73 -543 -1400 -2111 -1795 -1307 -1187 -1272 -1766 -1646 -1274 -675 -57 211 673 764 544 345 -165 -374 -300 -149 2 682 489 162 -269 -645 -729 -326 -641 -951 -761 -533 -332 399 603 528 566 359 50 -45 14 125 54 -97 -278 -95 274 246 432 335 -9 554 340 345 135 26 -189 -192 -347 -140 -96 260 273 -11 -186 -238 -312 -895 -878 -804 -868 -993 -999 -1103 -880 -939 -826 -920 -891 -895 -686 -599 -428 -448 -334 -316 -256 -287 -353 -296 -312 -236 -369 -306 -490 -481 -551 -310 -234 -19 -71 -383 -549 -546 -334 -112 188 113 169 130 213 201 267 166 215 10 60 313 473 637 619 659 613 596 436 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