File name: Pandora101s1_Izana_20201216_L2Fit_fout2c15d20200721p1-8.txt File generation date: 20240504T133027.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v6d20170928.txt Instrument calibration file used: Pandora101s1_CF_v15d20200721.txt Level 1 file used: Pandora101s1_Izana_20201216_L1_smca1c15d20200721p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20201216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 11 for vp 20200721 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0057 305.1465 305.2873 305.4282 305.5690 305.7098 305.8506 305.9914 306.1321 306.2729 306.4136 306.5544 306.6951 306.8358 306.9765 307.1172 307.2579 307.3986 307.5392 307.6799 307.8205 307.9611 308.1017 308.2423 308.3829 308.5235 308.6641 308.8046 308.9452 309.0857 309.2262 309.3667 309.5072 309.6477 309.7882 309.9286 310.0691 310.2095 310.3500 310.4904 310.6308 310.7712 310.9116 311.0519 311.1923 311.3326 311.4730 311.6133 311.7536 311.8939 312.0342 312.1745 312.3147 312.4550 312.5952 312.7355 312.8757 313.0159 313.1561 313.2963 313.4365 313.5766 313.7168 313.8569 313.9970 314.1371 314.2773 314.4173 314.5574 314.6975 314.8376 314.9776 315.1176 315.2577 315.3977 315.5377 315.6777 315.8176 315.9576 316.0976 316.2375 316.3774 316.5173 316.6573 316.7972 316.9370 317.0769 317.2168 317.3566 317.4965 317.6363 317.7761 317.9159 318.0557 318.1955 318.3352 318.4750 318.6147 318.7545 318.8942 319.0339 319.1736 319.3133 319.4529 319.5926 319.7323 319.8719 320.0115 320.1511 320.2907 320.4303 320.5699 320.7095 320.8490 320.9886 321.1281 321.2676 321.4072 321.5466 321.6861 321.8256 321.9651 322.1045 322.2440 322.3834 322.5228 322.6622 322.8016 322.9410 323.0803 323.2197 323.3591 323.4984 323.6377 323.7770 323.9163 324.0556 324.1949 324.3341 324.4734 324.6126 324.7519 324.8911 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201216T082156.9Z 7655.348575 43 1 47.83 2 84.89 120.00 106.11 110.24 0.00 1 0.00 1 0 25 6.452e-01 2.140e-02 2.882e-01 8.104e-03 9.301171e-01 4.553621e-03 9.386587e-03 -6.000000e+00 3.618754e-01 223.10 -2.00 3.19 -2.00 321.94 0.00e+00 2.752230e-03 2.364122e-03 3.503102e-03 -6.000000e+00 1.713504e-02 273.84 -2.00 20.00 -2.00 321.53 0.00e+00 9.735 0.009 302.00 328.00 3 1.9605e+00 1.6278e-02 8.7395e-02 -6.0000e+00 8.9217e-01 8.4145e-01 2.3393e-02 5.0239e-02 -6.0000e+00 9.7497e-01 -1.1180e+00 2.4484e-02 2.8977e-02 -6.0000e+00 5.7492e-01 4.5242e-01 1.1530e-02 1.0027e-02 -6.0000e+00 2.5101e-01 1.8923e-05 -7.1141e-04 2.0696e-04 1.4517e-04 -6.0000e+00 1.7014e-02 5.3011e-04 0.0000e+00 12 8 8 10 0 0 94.86 16.90 0.33 0.00053 -0.00482 32 8 1 5 0 1494.527 21.58 15.00 16.90 900000 -178591 900000 -100996 900000 900000 -155596 900000 -75464 -125844 -157534 -113177 -168797 900000 -114567 -46280 -108788 32420 -47004 900000 33211 140430 52324 -96715 257841 -94058 900000 -72829 48595 -93203 65743 -56139 328842 32329 72912 13454 33393 -1682 56687 236568 35563 104195 14702 73690 5900 4605 47631 42541 24623 74677 19611 22997 32369 25431 59083 10461 22810 30264 44582 8239 31833 3025 5755 8845 17464 12437 13364 15552 4668 9156 7413 19164 3205 11611 11126 13881 -13729 2790 -13280 6245 63 3189 3739 -451 155 1257 3054 64 3082 -2814 2727 -1973 -2 -912 -7991 -2472 -869 -1566 -2151 -155 -1115 -798 -5700 -2536 -3237 -2672 -5014 -930 -3312 -36 582 -277 394 -626 -885 -259 985 -217 139 -65 1003 1053 2345 1566 2295 1141 1367 2172 550 197 548 398 34 299 -497 84 -69 1056 -467 -172 -373 -553 -1557 900000 -4898 900000 -1352 900000 900000 -2658 900000 -688 -1973 -3383 -1672 -5278 900000 -3537 -913 -4419 374 -1246 900000 407 1108 490 -4007 2035 -4212 900000 -2557 503 -3885 708 -2453 2595 802 1197 361 745 -60 1372 1867 1432 2366 808 2333 353 279 1953 1879 1368 2776 1354 1750 2493 2268 4148 1198 2412 2955 3625 892 2690 354 753 1301 2657 2031 2144 2537 916 1974 1838 4465 862 2717 2376 2557 -2993 526 -3226 1527 20 1127 1483 -201 72 610 1528 34 1600 -1505 1294 -929 -1 -426 -4465 -1551 -635 -1345 -2090 -155 -1085 -708 -4668 -1908 -2570 -2239 -4517 -856 -3428 -41 761 -402 592 -955 -1325 -370 1391 -320 215 -105 1588 1588 3324 2176 3109 1521 1767 2827 813 342 1056 831 76 699 -1242 219 -185 2816 -1258 -449 -922 -1286 -3429 SS 20201216T083416.2Z 7655.357132 47 1 48.48 2 82.56 121.61 103.69 111.40 0.00 1 0.00 1 0 25 5.753e-01 1.170e-02 1.798e-01 3.131e-03 7.659269e-01 1.652286e-03 7.862218e-03 -6.000000e+00 3.173118e-01 223.10 -2.00 3.19 -2.00 321.18 0.00e+00 1.649539e-03 7.455593e-04 1.394471e-03 -6.000000e+00 1.370518e-02 273.84 -2.00 20.00 -2.00 320.75 0.00e+00 7.181 0.004 302.00 328.00 3 2.4884e+00 5.3203e-03 6.5295e-02 -6.0000e+00 7.8322e-01 1.4762e-01 7.6774e-03 3.8072e-02 -6.0000e+00 8.5344e-01 -2.0683e-01 8.5966e-03 2.1531e-02 -6.0000e+00 5.0715e-01 7.8705e-02 4.1382e-03 7.3147e-03 -6.0000e+00 2.2081e-01 8.9291e-05 -5.0549e-04 7.9410e-05 8.2599e-05 -6.0000e+00 1.4554e-02 -2.7850e-05 0.0000e+00 12 8 8 10 0 0 95.20 16.91 0.31 -0.00003 -0.00383 80 19 1 5 0 605.940 21.58 14.99 16.91 900000 -250841 -156788 -171675 -131409 -169131 -209086 -31696 -205474 -114658 -211035 -124917 -193539 132747 -132902 -41289 -81528 11019 -71334 24997 -18369 -12554 -16820 -65433 8694 -77386 90279 -64365 -7585 -79091 24670 -42743 37252 4286 16532 -4154 -7673 -1315 7658 21127 43 20248 -3476 23063 -5439 10732 4362 17592 -236 10849 8312 9977 10601 7180 10324 4741 5969 1935 9631 299 7123 1316 4981 2294 5310 3569 2548 2737 2388 3024 1131 4484 -227 2269 481 1750 -6256 -1490 -3684 487 -2422 -159 -1055 -2194 -1563 -1092 40 80 955 -601 1826 -816 -305 -772 -708 -783 -612 75 -95 561 -742 -948 -1662 -694 -1541 -1186 -1366 -480 -756 431 219 698 766 341 -22 122 285 -124 21 -276 -127 149 667 514 996 257 493 481 516 238 242 110 72 -135 -463 -38 -264 315 144 1 -255 -43 -607 900000 -3765 -1131 -1477 -693 -1220 -2379 -97 -3022 -764 -3924 -1075 -4189 405 -2766 -435 -1516 92 -1504 215 -255 -164 -233 -1634 116 -2641 661 -1983 -128 -2853 377 -1613 765 140 477 -139 -281 -53 351 1049 3 1200 -279 1473 -466 800 357 1316 -22 994 871 1180 1397 1081 1636 838 1092 345 1671 55 1214 256 991 546 1369 948 670 737 700 1028 447 1826 -98 906 179 572 -2016 -453 -1258 192 -1180 -82 -623 -1405 -1055 -784 30 63 744 -463 1291 -552 -196 -503 -512 -666 -570 81 -109 668 -856 -1052 -1634 -643 -1535 -1263 -1526 -567 -917 586 321 1118 1268 559 -34 182 417 -190 34 -469 -215 241 1022 765 1514 380 697 681 774 416 451 223 155 -291 -1077 -89 -640 769 355 2 -603 -95 -1256 SS 20201216T084401.3Z 7655.363903 50 1 48.51 2 80.74 122.94 101.79 112.35 0.00 1 0.00 1 0 25 3.515e-01 6.938e-03 2.916e-02 9.550e-04 6.561744e-01 4.859290e-04 6.852156e-03 -6.000000e+00 1.938329e-01 223.10 -2.00 3.19 -2.00 320.45 0.00e+00 1.988284e-03 1.794855e-04 5.240577e-04 -6.000000e+00 8.349507e-03 273.84 -2.00 20.00 -2.00 319.98 0.00e+00 5.926 0.002 302.00 328.00 3 1.4191e+00 1.4407e-03 5.4046e-02 -6.0000e+00 4.7843e-01 3.8150e-02 1.8713e-03 3.1042e-02 -6.0000e+00 5.2105e-01 -5.5332e-02 1.9335e-03 1.6765e-02 -6.0000e+00 3.0981e-01 1.5691e-02 9.8165e-04 5.9265e-03 -6.0000e+00 1.3393e-01 7.1547e-04 -4.8339e-04 2.4301e-05 5.7949e-05 -6.0000e+00 8.8063e-03 -3.1739e-04 0.0000e+00 11 8 0 10 0 0 86.70 16.91 0.25 -0.00032 -0.00395 324 76 1 5 0 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