File name: Pandora101s1_Izana_20210222_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T130445.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v7d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210222_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210222T092259.4Z 7723.390965 174 1 46.70 2 68.77 114.96 127.53 4.12 0.00 1 0.00 1 0 17 2.079e-02 8.459e-03 7.296e-03 2.217e-03 3.081157e-01 1.088999e-03 3.359167e-03 -6.000000e+00 1.148360e-02 224.34 -2.00 3.19 -2.00 317.20 0.00e+00 6.792923e-04 1.504307e-04 9.735312e-05 -6.000000e+00 4.914971e-04 272.89 -2.00 20.00 -2.00 316.67 0.00e+00 2.737 0.000 302.00 328.00 3 5.8298e+00 2.8488e-03 2.4960e-02 -6.0000e+00 2.8429e-02 5.5572e-02 3.2061e-03 1.4094e-02 -6.0000e+00 3.0972e-02 1.9411e-03 1.9661e-03 7.0361e-03 -6.0000e+00 1.8387e-02 -6.1080e-03 9.9414e-04 2.1132e-03 -6.0000e+00 7.8966e-03 1.3034e-04 4.1482e-04 5.9309e-05 2.0909e-05 -6.0000e+00 5.2143e-04 1.3841e-02 0.0000e+00 11 9 0 11 40 0 21.22 16.85 0.40 0.01384 0.01696 12 3 1 5 0 3891.211 21.58 15.00 16.85 -1988 -5346 -790 -3800 -4700 -6112 -7830 -56 -1890 -4189 -7392 -9437 -6924 -452 -2043 468 -3384 637 -2225 3101 957 2549 355 -350 1566 -1194 2768 -2107 -840 -3179 1899 410 4663 672 -1383 -4008 -2296 -515 1122 2091 -481 -549 20 967 1137 -107 418 -465 -906 -183 477 54 1082 849 1624 1315 300 1198 208 -125 425 783 1454 2334 1345 340 -845 -1518 -274 207 -223 941 -100 483 342 522 -2338 -2866 -3466 -1825 -1247 -1460 -1237 -1510 -930 -456 215 539 1310 1434 451 -142 -825 -835 -1292 -477 297 621 688 579 -299 -881 -1126 -779 -459 -324 -754 -299 -151 647 1136 1075 705 164 -775 -209 -548 -49 -8 175 326 94 410 298 716 329 -267 683 29 592 202 -111 -490 134 -81 69 102 324 429 97 -542 -515 -1076 -189 -591 -88 -419 -466 -574 -775 -6 -225 -544 -984 -1290 -1035 -74 -388 97 -766 144 -541 748 242 629 90 -94 437 -357 809 -614 -229 -861 520 124 1474 232 -461 -1310 -781 -195 492 1041 -264 -314 11 569 669 -63 246 -272 -525 -106 285 34 719 589 1149 948 222 882 152 -90 309 597 1178 1986 1176 286 -677 -1189 -219 182 -211 912 -98 461 314 444 -1879 -2215 -2740 -1560 -1159 -1458 -1301 -1631 -1042 -535 260 666 1617 1742 526 -157 -865 -849 -1358 -535 355 794 924 781 -390 -1093 -1329 -921 -572 -419 -1003 -409 -212 945 1725 1660 1078 241 -1095 -282 -730 -66 -12 258 488 140 599 425 990 444 -350 880 38 837 297 -167 -744 208 -130 115 172 550 734 164 -900 -835 -1711 SS 20210222T092947.1Z 7723.395684 178 1 48.19 2 67.42 116.02 127.40 5.97 0.00 1 0.00 1 0 17 1.899e-02 8.262e-03 6.027e-03 2.055e-03 2.931601e-01 1.009923e-03 3.206072e-03 -6.000000e+00 1.049314e-02 224.34 -2.00 3.19 -2.00 316.97 0.00e+00 4.370212e-04 1.314074e-04 9.642502e-05 -6.000000e+00 4.491109e-04 272.89 -2.00 20.00 -2.00 316.43 0.00e+00 2.584 0.000 302.00 328.00 3 5.8629e+00 2.6327e-03 2.3624e-02 -6.0000e+00 2.5977e-02 5.0346e-02 2.9589e-03 1.3395e-02 -6.0000e+00 2.8301e-02 3.3415e-03 1.7870e-03 6.6832e-03 -6.0000e+00 1.6801e-02 -6.4757e-03 8.9160e-04 1.9597e-03 -6.0000e+00 7.2154e-03 1.4485e-04 2.5948e-04 5.5001e-05 1.9971e-05 -6.0000e+00 4.7648e-04 1.4086e-02 0.0000e+00 11 9 0 11 32 0 7.34 16.86 0.08 0.01409 0.01604 13 3 1 5 0 3706.552 21.58 15.00 16.86 -2635 -1981 -4242 -1287 -6391 -3843 -7081 3106 -3255 -4265 -7628 -7227 -5517 36 -1185 -221 -379 249 -1744 2870 3462 1442 1037 -1429 468 -625 3084 -1660 -1279 -1977 1483 1395 3814 1413 -3135 -2766 -1663 -2151 290 1587 -108 314 -213 298 458 -581 477 -104 -879 -534 949 116 1576 1149 1496 699 980 442 473 38 706 971 1338 2171 1152 266 -1418 -1408 -842 -115 239 1268 112 318 538 250 -1809 -2994 -2281 -1844 -1489 -1370 -1770 -1888 -966 -391 564 518 1312 608 540 -62 -446 -619 -1090 -426 220 973 461 676 -417 -668 -1175 -267 -995 -884 -612 -216 296 438 1072 772 870 316 -645 -502 -388 34 -22 466 55 335 252 418 613 428 -364 640 -87 759 -60 138 -493 -14 75 -28 97 413 205 -118 -406 -456 -934 -295 -247 -561 -160 -743 -408 -803 361 -453 -636 -1166 -1102 -923 7 -250 -51 -93 63 -467 762 937 395 287 -425 144 -203 983 -529 -381 -577 440 451 1304 518 -1135 -957 -600 -881 136 840 -63 188 -131 185 283 -363 294 -63 -531 -321 586 76 1080 819 1096 522 743 337 354 28 529 761 1115 1896 1031 229 -1164 -1121 -688 -102 229 1246 112 309 500 217 -1473 -2348 -1811 -1593 -1395 -1379 -1879 -2056 -1090 -460 685 643 1632 746 634 -69 -469 -629 -1144 -476 262 1236 618 907 -543 -824 -1382 -315 -1242 -1146 -812 -294 414 636 1617 1187 1316 462 -901 -670 -511 46 -30 679 81 494 365 594 843 573 -472 816 -115 1061 -88 205 -739 -21 118 -46 160 691 347 -197 -664 -730 -1464 SS 20210222T093934.4Z 7723.402481 181 1 48.72 2 65.49 117.60 127.13 8.61 0.00 1 0.00 1 0 17 1.517e-02 8.048e-03 4.842e-03 1.898e-03 2.736589e-01 9.337993e-04 2.997116e-03 -6.000000e+00 8.379327e-03 224.34 -2.00 3.19 -2.00 316.65 0.00e+00 6.595853e-04 1.123945e-04 6.008408e-05 -6.000000e+00 3.586367e-04 272.89 -2.00 20.00 -2.00 316.13 0.00e+00 2.395 0.000 302.00 328.00 3 5.9008e+00 2.4239e-03 2.1944e-02 -6.0000e+00 2.0744e-02 4.8425e-02 2.7199e-03 1.2501e-02 -6.0000e+00 2.2600e-02 2.1791e-03 1.6159e-03 6.2269e-03 -6.0000e+00 1.3417e-02 -6.5221e-03 7.9174e-04 1.8630e-03 -6.0000e+00 5.7619e-03 1.6556e-04 3.4655e-04 5.0759e-05 1.9065e-05 -6.0000e+00 3.8049e-04 1.3987e-02 0.0000e+00 11 9 0 11 32 0 40.10 16.86 0.14 0.01399 0.01659 14 3 1 5 0 3479.801 21.58 14.99 16.86 908 -3022 72 -3513 -1933 -2758 -6189 1462 -1884 -2190 -5621 -6234 -3756 1396 -840 947 -816 767 -466 3827 1353 1120 93 -711 211 -1008 2334 -942 -51 -2268 1237 -96 3313 457 -2607 -2973 -1341 -1459 150 1522 -141 -34 -854 643 106 -59 -631 -448 -718 -276 133 381 1514 831 1064 1274 785 768 296 193 1612 814 1458 1906 1113 38 -1045 -1056 -367 161 -7 960 -377 727 350 263 -2029 -2832 -2651 -1494 -1844 -1106 -1727 -1688 -1118 -173 259 580 1154 773 638 -284 -326 -688 -1129 -661 268 1290 958 547 -334 -817 -1072 -436 -778 -572 -326 -458 -166 877 1062 766 846 245 -372 -319 -417 -252 -271 189 342 98 418 251 581 284 -310 545 151 332 140 -279 -183 -269 -114 122 -23 610 233 -50 -397 -321 -875 120 -460 11 -540 -259 -348 -835 206 -307 -380 -996 -1108 -723 292 -204 250 -229 218 -139 1142 422 347 29 -235 73 -365 833 -331 -17 -734 407 -34 1241 184 -1023 -1117 -522 -642 75 860 -87 -22 -560 421 70 -39 -415 -289 -457 -174 87 262 1079 617 810 982 617 604 230 149 1242 660 1252 1716 1023 34 -874 -861 -306 146 -7 957 -381 715 332 233 -1690 -2266 -2153 -1306 -1751 -1118 -1843 -1851 -1270 -204 316 723 1442 952 753 -318 -344 -702 -1187 -739 317 1630 1269 730 -433 -1002 -1258 -512 -966 -737 -431 -623 -230 1262 1586 1162 1266 355 -512 -421 -541 -334 -374 272 501 144 600 353 791 376 -397 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