File name: Pandora101s1_Izana_20210622_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T115328.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v7d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210622_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210622T064002.6Z 7843.277807 142 1 48.53 2 84.83 66.12 125.26 266.76 0.00 1 0.00 1 0 17 4.524e-01 2.322e-02 1.758e-01 3.988e-03 1.007927e+00 2.242254e-03 9.883667e-03 -6.000000e+00 2.546990e-01 228.73 -2.00 3.19 -2.00 322.14 0.00e+00 -8.820304e-03 1.267273e-03 2.714464e-03 -6.000000e+00 1.107360e-02 281.02 -2.00 20.00 -2.00 321.70 0.00e+00 9.639 0.009 302.00 328.00 3 4.5277e-01 8.7560e-03 9.1393e-02 -6.0000e+00 6.3523e-01 9.0847e-01 1.2815e-02 6.2053e-02 -6.0000e+00 6.8840e-01 -1.3572e+00 1.2410e-02 2.9837e-02 -6.0000e+00 4.0924e-01 5.5711e-01 5.6499e-03 1.1413e-02 -6.0000e+00 1.7575e-01 8.7094e-05 -1.1124e-03 9.7886e-05 1.2137e-04 -6.0000e+00 1.1355e-02 -5.6618e-04 0.0000e+00 12 8 8 10 0 0 -2.18 16.63 0.27 -0.00057 -0.00893 168 40 1 5 0 288.841 21.38 15.00 16.63 145684 -149169 31044 -116743 -93752 -124513 -145998 -50227 -106912 -76021 -121296 -94532 -125379 -19140 -57590 -28069 -70197 25659 -58747 68120 -29083 8023 15558 -19613 22797 -157181 51312 -43535 -20207 -76988 23994 -26531 64352 -6559 24452 -4760 28070 22768 53410 69832 46751 80592 40373 68936 15050 46142 14798 38154 8323 48193 19470 34518 42004 45498 50175 49986 43041 39863 45013 15586 32406 12091 30154 17272 29338 20933 24036 15511 17585 16724 15589 24252 14509 15051 11599 11901 -7164 143 -4687 6193 -365 4105 1457 1935 1223 3630 3677 2427 3857 427 3141 -2339 -461 -2851 -2482 -3627 -2130 -2922 -3154 -3349 -2993 -3021 -4176 -2539 -3308 -2493 -3629 -1927 -3010 -1312 -1490 83 -277 377 -84 170 -17 118 34 399 925 1782 2136 1419 2550 1382 1789 981 1132 244 624 329 -221 -73 -116 201 162 815 292 -176 -717 -841 -1836 567 -3429 133 -1858 -995 -1585 -2375 -391 -1512 -946 -2230 -1544 -3015 -216 -1059 -502 -1936 319 -1620 583 -645 115 206 -412 355 -14340 639 -1287 -424 -2815 373 -846 976 -225 590 -141 611 602 1288 1766 1728 2288 1759 2226 796 1741 760 1588 450 2081 1143 2002 2525 2912 3335 3535 3424 3284 3327 1422 2383 1142 2708 2064 3496 2768 3077 2276 2798 3146 3362 5085 3345 3225 2301 2054 -1360 26 -990 1434 -101 1287 539 771 521 1606 1708 1180 1849 205 1377 -1019 -193 -1282 -1279 -2276 -1575 -2378 -2961 -3322 -2845 -2576 -3135 -1910 -2666 -1976 -3059 -1721 -3030 -1520 -2032 117 -417 571 -124 243 -24 174 53 653 1484 2667 3000 1955 3642 1947 2419 1363 1695 442 1212 712 -520 -186 -299 553 455 2300 830 -484 -1827 -2083 -4252 SS 20210622T065159.2Z 7843.286101 146 1 48.51 2 82.42 67.42 127.77 267.99 0.00 1 0.00 1 0 17 6.980e-01 1.032e-02 4.148e-02 1.102e-03 8.047391e-01 5.872159e-04 8.278288e-03 -6.000000e+00 3.930091e-01 228.73 -2.00 3.19 -2.00 321.25 0.00e+00 2.930974e-03 2.833264e-04 2.237413e-03 -6.000000e+00 1.708685e-02 281.02 -2.00 20.00 -2.00 320.74 0.00e+00 7.059 0.004 302.00 328.00 3 4.1626e-01 1.9855e-03 6.6777e-02 -6.0000e+00 9.8018e-01 1.4049e-01 2.8683e-03 4.1289e-02 -6.0000e+00 1.0622e+00 -2.1457e-01 3.0791e-03 2.3133e-02 -6.0000e+00 6.3148e-01 8.2596e-02 1.4551e-03 7.9454e-03 -6.0000e+00 2.7119e-01 7.1769e-04 -5.3680e-04 2.7171e-05 9.5838e-05 -6.0000e+00 1.7521e-02 -6.2336e-04 0.0000e+00 12 8 8 10 0 0 -10.27 16.64 0.22 -0.00062 -0.00466 526 124 1 5 0 92.214 21.38 15.00 16.64 -249429 -226246 -212421 -209573 -230040 -221124 -237237 -210032 -192900 -202611 -176364 -179245 -152613 -136281 -106782 -104333 -78723 -70677 -64278 -64925 -49768 -61713 -53607 -44599 -45788 -86271 -38348 -46885 -49529 -44583 -35519 -18144 -17311 -6261 -15664 -18537 -16520 -10410 -2869 6293 6070 5434 4708 5026 7282 3739 6787 4238 6489 5567 7311 6067 9188 7735 8983 7263 6536 6270 4279 3857 2984 4741 5205 6890 5730 5474 3189 2486 1964 3335 2740 2961 1846 1642 1074 -556 -1975 -3570 -2466 -1494 -656 -1306 -1466 -1878 -1275 -761 -249 296 582 729 365 -11 -1308 -1506 -1445 -776 -737 137 -18 70 -370 -1011 -1115 -950 -1179 -1408 -1032 -718 -395 220 615 487 475 332 76 -232 64 173 149 58 77 407 645 547 591 470 2 618 179 428 123 80 -135 -202 -257 -253 -23 331 256 -49 -190 -362 -385 -2332 -2115 -1963 -1937 -2398 -1996 -2677 -2077 -1866 -2417 -1725 -2003 -1689 -1743 -1354 -1648 -1142 -1079 -1029 -1123 -776 -1081 -887 -748 -866 -2643 -758 -998 -1059 -963 -855 -468 -540 -201 -547 -634 -588 -411 -131 296 334 332 310 343 493 270 492 331 531 498 722 700 1154 1091 1360 1182 1122 1093 738 644 504 853 987 1501 1412 1370 805 653 567 1114 1047 1203 763 646 388 -181 -597 -1096 -831 -604 -293 -686 -873 -1205 -864 -549 -176 216 425 518 263 -8 -857 -1005 -1080 -631 -707 143 -21 86 -436 -1076 -1119 -910 -1207 -1445 -1106 -820 -492 291 928 763 769 531 124 -361 98 276 237 97 129 646 1029 848 883 681 2 861 284 745 228 163 -289 -440 -602 -599 -57 812 633 -117 -450 -794 -837 SS 20210622T070928.8Z 7843.298249 151 1 48.50 2 78.84 69.26 131.46 269.86 0.00 1 0.00 1 0 17 2.411e-01 6.491e-03 9.012e-03 3.924e-04 6.015427e-01 2.015469e-04 6.305721e-03 -6.000000e+00 1.357849e-01 228.73 -2.00 3.19 -2.00 320.01 0.00e+00 1.170139e-03 6.702880e-05 5.721427e-04 -6.000000e+00 5.902697e-03 281.02 -2.00 20.00 -2.00 319.42 0.00e+00 4.994 0.001 302.00 328.00 3 2.9124e-01 5.8608e-04 4.7559e-02 -6.0000e+00 3.3865e-01 1.9819e-02 7.2077e-04 2.8755e-02 -6.0000e+00 3.6698e-01 -3.4765e-02 6.6647e-04 1.4672e-02 -6.0000e+00 2.1817e-01 7.3180e-03 3.4496e-04 4.5594e-03 -6.0000e+00 9.3707e-02 4.4206e-03 -3.0081e-04 1.0115e-05 4.4498e-05 -6.0000e+00 6.0521e-03 -1.6602e-03 0.0000e+00 11 8 0 10 0 0 -12.89 16.65 0.22 -0.00166 -0.00392 1374 324 1 5 0 35.295 21.38 15.00 16.65 -92022 -80939 -72751 -76031 -85937 -87624 -90966 -79636 -67841 -64103 -62041 -61680 -48068 -36421 -26730 -20733 -16411 -14744 -12507 -11044 -10707 -12900 -11015 -9647 -8060 -12523 -7923 -9167 -11378 -10928 -6914 -3755 -775 -924 -4685 -6547 -5940 -3590 -393 1155 1313 1262 1669 1594 2134 1496 1125 878 464 485 1563 2032 2270 2135 1929 1941 1660 1117 845 344 875 1411 2308 2834 2153 1174 237 -397 140 965 896 946 385 223 -39 -738 -1627 -2366 -1877 -1430 -1179 -1221 -1744 -1632 -1256 -603 -55 277 690 832 588 460 -260 -468 -303 -251 5 644 389 215 -305 -707 -709 -330 -695 -963 -746 -508 -272 353 520 536 522 331 37 15 18 121 100 -83 -262 -46 273 245 402 316 -31 616 329 290 161 2 -177 -180 -286 -191 -88 230 233 -61 -119 -185 -292 -1078 -1038 -955 -1047 -1194 -1167 -1330 -1201 -1062 -1079 -1073 -1135 -942 -815 -688 -616 -534 -521 -475 -441 -407 -502 -473 -407 -371 -650 -409 -468 -570 -556 -388 -246 -58 -78 -402 -543 -520 -360 -47 169 203 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