File name: Pandora101s1_Izana_20210730_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T113118.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v7d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210730_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210730T065641.3Z 7881.289367 213 1 49.07 2 84.70 71.90 26.08 210.72 0.00 1 0.00 1 0 25 7.319e-01 3.862e-02 2.984e-01 1.070e-02 9.616984e-01 5.920077e-03 9.976340e-03 -6.000000e+00 4.109342e-01 227.88 -2.00 3.19 -2.00 321.91 0.00e+00 -5.140080e-02 2.749149e-03 1.013439e-02 -6.000000e+00 1.810532e-02 282.01 -2.00 20.00 -2.00 321.39 0.00e+00 9.452 0.009 302.00 328.00 3 2.5867e+00 2.1174e-02 1.3546e-01 -6.0000e+00 1.0222e+00 1.0301e+00 2.9067e-02 1.7824e-01 -6.0000e+00 1.1083e+00 -1.6529e+00 2.4130e-02 3.0262e-02 -6.0000e+00 6.5971e-01 6.8639e-01 1.1357e-02 4.7493e-02 -6.0000e+00 2.8450e-01 1.3875e-05 -3.6570e-04 2.6839e-04 4.6803e-04 -6.0000e+00 1.8378e-02 -5.0669e-04 0.0000e+00 12 8 8 10 0 0 95.00 16.74 0.31 -0.00051 -0.00325 22 5 1 5 0 2230.139 21.48 15.00 16.74 59240 30106 64579 -5804 63794 9278 -37419 285644 169156 42780 15129 -23731 39135 197467 85728 13367 7974 116057 -27850 323298 30444 900000 69285 78184 115628 -96570 363833 57441 110371 -25005 31749 56612 241973 104147 66335 2732 59501 72363 125053 199553 121209 108813 73626 107067 54043 23757 66772 34800 6010 107845 28988 16888 48782 41780 54693 73018 76241 83084 44079 45879 52712 26707 -3438 24486 20586 34048 6397 14157 12609 7080 10533 32163 11862 21011 26221 9547 -1384 5041 -5196 -4163 3084 2539 3898 -2394 337 3556 6711 9138 -1189 -3369 1308 1441 732 7103 -5505 -2911 -2299 -5392 -7361 -6314 -7685 -6574 -8967 -5618 -2761 -5021 -2541 -3010 -2565 -1028 570 -126 3380 1064 204 1117 1526 44 -1946 641 916 2855 2630 2888 1949 2859 2119 2514 411 145 -383 -229 -1310 -368 220 952 741 1934 520 -819 -582 -1869 -2726 1135 746 1040 -158 717 162 -1214 2979 1764 1482 756 -1703 1495 2059 1914 601 372 1895 -1732 3371 1026 900000 1664 2245 3132 -22540 3794 2692 2394 -1597 1165 1771 2523 2389 2066 144 1944 2515 3472 3535 5455 5880 5336 5104 3735 1941 3362 2238 515 3769 2326 1728 4102 4144 5415 6747 7548 7918 5711 5130 4919 3091 -569 3483 3302 4784 1138 2461 2497 1708 2790 7427 3337 5142 5535 2066 -300 1008 -1225 -1140 923 892 1541 -1100 160 1744 3349 4574 -654 -1813 634 660 333 3186 -3147 -1877 -1692 -4618 -7187 -6360 -7522 -5809 -7271 -4290 -2209 -4375 -2266 -2856 -2648 -1198 747 -186 5029 1642 310 1629 2186 66 -3116 1034 1472 4308 3812 4079 2709 3876 2780 3336 626 257 -755 -492 -3000 -892 567 2559 2050 5335 1452 -2225 -1479 -4474 -6242 SS 20210730T070913.3Z 7881.298071 217 1 48.66 2 82.07 73.29 27.55 216.71 0.00 1 0.00 1 0 17 5.963e-01 1.036e-02 7.448e-02 1.887e-03 7.657190e-01 1.001631e-03 7.928243e-03 -6.000000e+00 3.347587e-01 227.88 -2.00 3.19 -2.00 321.13 0.00e+00 2.098054e-03 4.705897e-04 2.056511e-03 -6.000000e+00 1.465815e-02 282.01 -2.00 20.00 -2.00 320.61 0.00e+00 6.788 0.003 302.00 328.00 3 1.7434e+00 3.3336e-03 6.3825e-02 -6.0000e+00 8.3295e-01 1.1941e-01 4.6855e-03 3.8997e-02 -6.0000e+00 9.0303e-01 -1.8427e-01 4.9153e-03 2.1230e-02 -6.0000e+00 5.3752e-01 6.9512e-02 2.3493e-03 6.8666e-03 -6.0000e+00 2.3151e-01 2.4082e-04 -5.7125e-04 4.7102e-05 8.4240e-05 -6.0000e+00 1.4964e-02 -1.6388e-03 0.0000e+00 12 8 8 10 0 0 -2.64 16.75 0.18 -0.00164 -0.00593 156 37 1 5 0 311.902 21.48 15.00 16.75 -228517 -198825 -184750 -146189 -218509 -139419 -232518 -125374 -156688 -161496 -182801 -176954 -146439 -92100 -77095 -121385 -53439 -62314 -53522 -39402 -17295 -48694 -19992 -57614 -19280 -90957 -14770 -36693 -35678 -41063 -26070 -3604 -2209 4242 -15908 -10217 -19381 -5101 -992 14963 553 6790 6626 7794 4506 1743 5688 2958 7623 3311 8314 4759 10402 8566 8529 5506 6546 5968 4815 4515 4986 4397 4224 6387 4359 4551 1502 2589 1117 2419 1531 2306 665 733 634 -700 -2378 -3613 -2396 -1494 -937 -1728 -979 -2297 -669 -1006 129 287 329 871 571 243 -789 -1160 -1525 -360 -625 212 -187 63 -644 -939 -1281 -894 -648 -1501 -1024 -887 -474 368 325 347 720 175 152 -21 245 206 172 169 -50 408 599 575 546 280 145 661 96 433 40 134 -225 -98 -302 -153 -124 413 66 -174 -165 -287 -248 -2439 -1976 -1802 -995 -2815 -770 -3151 -738 -1471 -1783 -2658 -2670 -2075 -1017 -965 -2721 -787 -1135 -995 -682 -251 -968 -305 -1292 -362 -3439 -299 -912 -854 -1088 -715 -99 -66 136 -620 -357 -788 -212 -49 786 39 498 519 627 379 155 501 279 731 357 953 595 1377 1276 1379 968 1193 1108 879 796 877 842 931 1602 1241 1305 435 762 363 838 609 970 286 300 238 -237 -809 -1235 -821 -611 -458 -993 -586 -1492 -454 -733 98 227 262 672 415 165 -517 -770 -1131 -310 -591 231 -218 76 -749 -1051 -1270 -844 -652 -1634 -1162 -1073 -585 510 482 565 1206 290 241 -32 363 317 281 290 -85 669 932 869 795 419 209 949 147 768 76 259 -462 -215 -675 -364 -303 1019 156 -422 -375 -637 -517 SS 20210730T072439.8Z 7881.308794 222 1 48.52 2 78.80 74.97 29.66 223.28 0.00 1 0.00 1 0 25 2.208e-01 6.379e-03 1.462e-02 6.537e-04 5.874864e-01 3.330831e-04 6.175023e-03 -6.000000e+00 1.239630e-01 227.88 -2.00 3.19 -2.00 319.96 0.00e+00 1.157879e-03 1.101416e-04 5.236320e-04 -6.000000e+00 5.427714e-03 282.01 -2.00 20.00 -2.00 319.34 0.00e+00 4.978 0.001 302.00 328.00 3 1.3376e+00 9.6961e-04 4.6963e-02 -6.0000e+00 3.0845e-01 1.5667e-02 1.1904e-03 2.7976e-02 -6.0000e+00 3.3439e-01 -2.6483e-02 1.0859e-03 1.4261e-02 -6.0000e+00 1.9904e-01 2.6165e-03 5.6335e-04 4.4117e-03 -6.0000e+00 8.5733e-02 1.5985e-03 -4.1892e-04 1.6822e-05 4.3425e-05 -6.0000e+00 5.5409e-03 -2.0356e-03 0.0000e+00 10 0 0 10 0 0 -1.48 16.76 0.23 -0.00204 -0.00518 485 115 1 5 0 100.042 21.48 15.00 16.76 -92935 -77229 -67708 -67995 -70979 -76582 -75088 -68854 -61602 -58210 -61675 -60401 -48142 -36428 -26078 -22442 -14725 -13803 -10703 -9889 -5866 -8992 -8265 -6879 -7840 -12145 -7432 -8600 -11843 -12122 -8146 -3709 -1550 -1301 -4757 -6209 -5092 -2138 807 1845 1335 1253 1321 1274 1701 1155 1460 83 402 241 1221 1922 2652 2008 1923 1963 1895 1426 653 612 600 1375 1965 2827 1857 1116 193 -264 130 764 949 807 211 112 -56 -643 -1754 -2335 -1770 -1315 -1154 -1255 -1748 -1687 -1224 -659 -69 192 644 867 731 405 -267 -324 -320 -214 -85 716 369 184 -314 -730 -634 -224 -516 -1026 -856 -568 -190 317 618 567 522 299 89 5 90 125 95 -105 -245 -73 248 180 358 312 -70 583 324 287 148 -48 -175 -140 -320 -227 -45 181 270 -84 -127 -160 -228 -1209 -1049 -928 -949 -932 -1001 -1024 -1018 -990 -1009 -1160 -1194 -1022 -880 -718 -728 -505 -517 -388 -379 -227 -360 -335 -301 -383 -669 -406 -465 -633 -661 -488 -255 -123 -115 -429 -537 -462 -221 100 279 215 220 245 245 328 228 293 17 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