File name: Pandora101s1_Izana_20210911_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T110814.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v8d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20210911_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20210911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210911T072738.9Z 7924.310867 54 1 48.27 2 82.40 89.05 138.86 80.31 0.00 1 0.00 1 0 25 4.534e-01 1.772e-02 2.063e-01 4.068e-03 7.409445e-01 2.151372e-03 7.838463e-03 -6.000000e+00 2.535378e-01 226.99 -2.00 3.19 -2.00 321.14 0.00e+00 -3.351656e-03 9.839903e-04 4.214233e-03 -6.000000e+00 1.110355e-02 281.13 -2.00 20.00 -2.00 320.61 0.00e+00 7.047 0.004 302.00 328.00 3 3.0429e+00 7.0990e-03 6.8216e-02 -6.0000e+00 6.2972e-01 1.9347e-01 9.8589e-03 4.9171e-02 -6.0000e+00 6.8339e-01 -3.3712e-01 9.9409e-03 2.0569e-02 -6.0000e+00 4.0685e-01 1.4318e-01 4.7540e-03 7.1391e-03 -6.0000e+00 1.7531e-01 5.7795e-05 -4.7907e-04 1.0393e-04 6.5198e-05 -6.0000e+00 1.1378e-02 2.2461e-03 0.0000e+00 12 8 8 10 0 0 72.99 16.90 0.22 0.00225 -0.00135 38 9 1 5 0 1270.246 21.58 14.98 16.90 33494 -219954 -91431 -144452 54550 -118146 -144946 -2440 -83036 -131538 -174523 -127109 -118722 33024 -86095 -76703 -84192 5988 -56202 81090 -28845 56186 -22456 -36813 -26301 -142781 78827 -22472 29537 -54404 24509 -15905 24178 -541 20656 -22543 27992 -7147 32597 32415 13726 19459 11879 24722 3608 2713 15517 7749 -283 22138 7376 8161 10627 13607 15495 13342 12192 12171 10399 4214 12633 5251 7118 6333 10125 4265 2214 1534 3388 2525 3172 5409 375 2963 2596 1959 -2131 -2306 -3491 -922 -2093 -298 -938 -2053 -2285 -958 630 882 391 -640 -259 272 565 -53 -2438 -1660 -1156 -987 -1014 -382 -1152 -2353 -2961 -1193 -1179 -1970 -1609 -917 -813 385 226 348 1233 106 -64 415 388 549 -202 397 582 912 1083 821 1027 386 860 862 742 121 399 30 -335 -380 -330 -144 47 919 294 42 -658 -550 -1211 133 -5025 -678 -1750 216 -963 -1631 -10 -708 -1976 -4191 -2089 -2195 184 -1848 -1799 -2432 82 -1479 625 -642 559 -486 -1014 -740 -12644 920 -659 503 -2067 520 -587 721 -23 704 -1100 907 -375 1438 1780 1024 1496 1020 1938 342 261 1358 741 -31 2094 885 1091 1544 2079 2518 2344 2277 2304 1938 798 2183 1048 1563 1614 2693 1201 621 444 1048 907 1265 2246 162 1207 987 666 -699 -749 -1235 -374 -1012 -162 -571 -1334 -1583 -691 473 677 303 -495 -187 185 371 -36 -1801 -1403 -1106 -1063 -1201 -466 -1351 -2577 -2972 -1136 -1188 -2119 -1807 -1078 -1015 531 342 560 2024 173 -100 625 584 848 -329 670 981 1487 1701 1255 1531 567 1215 1225 1146 210 754 60 -698 -823 -752 -341 114 2223 720 102 -1525 -1209 -2551 SS 20210911T074415.2Z 7924.322399 59 1 48.47 2 78.75 91.02 135.44 82.83 0.00 1 0.00 1 0 25 1.662e-01 6.086e-03 1.881e-02 9.263e-04 5.572618e-01 4.677608e-04 5.880974e-03 -6.000000e+00 9.295789e-02 226.99 -2.00 3.19 -2.00 319.84 0.00e+00 1.147787e-03 1.467584e-04 4.703537e-04 -6.000000e+00 4.070664e-03 281.13 -2.00 20.00 -2.00 319.23 0.00e+00 4.957 0.001 302.00 328.00 3 2.1056e+00 1.3470e-03 4.5807e-02 -6.0000e+00 2.3088e-01 1.5325e-02 1.6343e-03 2.6358e-02 -6.0000e+00 2.5055e-01 -2.5435e-02 1.4560e-03 1.3428e-02 -6.0000e+00 1.4916e-01 2.5794e-03 7.6212e-04 4.1647e-03 -6.0000e+00 6.4282e-02 7.8803e-04 -3.9475e-04 2.4091e-05 3.9849e-05 -6.0000e+00 4.1712e-03 1.5062e-03 0.0000e+00 10 0 0 10 0 0 60.40 16.90 0.21 0.00151 -0.00146 230 54 1 5 0 210.709 21.58 15.00 16.90 -58392 -56660 -51687 -44198 -60996 -60533 -65414 -48421 -48139 -42892 -51188 -42047 -38708 -20267 -20028 -17478 -13838 -8856 -10336 -5532 -3212 -6865 -5422 -7557 -4782 -15365 -2190 -7679 -5888 -9402 -3277 -1379 -953 911 -3794 -4852 -4977 -2357 -167 2227 -322 902 807 1401 428 1008 1065 707 103 432 1137 828 2143 1595 1883 1498 1668 1100 837 63 1102 1426 2262 2434 1749 1087 -299 -244 18 865 602 713 84 212 125 -521 -1394 -2017 -1665 -1262 -963 -1160 -1835 -1774 -1252 -638 109 227 782 748 592 295 0 -234 -444 -194 -9 698 439 331 -406 -668 -765 -328 -787 -944 -737 -657 -316 487 627 476 487 287 29 47 175 156 140 -163 -256 -206 356 199 369 249 48 660 325 277 163 13 -291 -157 -324 -204 -116 306 244 8 -195 -124 -313 -723 -834 -798 -639 -948 -880 -1058 -761 -878 -825 -1114 -885 -951 -525 -649 -609 -526 -351 -454 -246 -146 -325 -258 -401 -272 -1045 -135 -489 -351 -589 -219 -108 -87 91 -387 -473 -516 -279 -24 350 -60 179 170 302 94 224 240 163 24 107 305 250 701 526 662 551 637 427 318 23 410 569 1009 1225 888 544 -155 -126 9 507 400 470 56 146 80 -300 -733 -1029 -900 -794 -662 -916 -1517 -1554 -1158 -630 113 231 797 745 588 271 0 -211 -407 -203 -10 844 593 436 -539 -806 -878 -366 -951 -1157 -943 -889 -433 732 991 767 791 474 45 72 262 231 219 -259 -414 -340 562 306 569 369 69 920 500 457 281 22 -532 -300 -635 -425 -238 637 514 16 -399 -238 -599 SS 20210911T075114.8Z 7924.327254 63 1 48.50 2 77.21 91.86 134.00 83.83 0.00 1 0.00 1 0 17 9.982e-02 5.956e-03 8.863e-03 6.361e-04 5.001655e-01 3.197116e-04 5.334301e-03 -6.000000e+00 5.581808e-02 226.99 -2.00 3.19 -2.00 319.32 0.00e+00 9.865523e-04 8.414374e-05 3.449612e-04 -6.000000e+00 2.444415e-03 281.13 -2.00 20.00 -2.00 318.67 0.00e+00 4.402 0.001 302.00 328.00 3 1.8789e+00 8.9106e-04 4.0812e-02 -6.0000e+00 1.3864e-01 4.1737e-03 1.0472e-03 2.3561e-02 -6.0000e+00 1.5045e-01 -9.0210e-03 8.4870e-04 1.1859e-02 -6.0000e+00 8.9568e-02 -4.2286e-03 4.5232e-04 3.6121e-03 -6.0000e+00 3.8597e-02 1.5768e-03 -2.5976e-04 1.6774e-05 3.5428e-05 -6.0000e+00 2.5048e-03 1.8990e-03 0.0000e+00 11 1 0 11 8 0 56.45 16.91 0.22 0.00190 -0.00005 361 85 1 5 0 134.330 21.69 14.99 16.91 -36324 -33913 -32012 -29776 -39344 -35473 -40313 -26758 -30838 -19218 -31008 -23066 -23083 -11965 -11049 -7761 -6136 -4952 -2932 -2372 -588 -4412 -949 -3885 -873 -6907 -619 -4921 -4033 -5990 -778 -667 855 233 -3169 -4081 -3631 -839 -559 1321 -668 563 -337 745 363 724 98 359 -254 27 1229 1342 2140 1527 1729 967 1483 870 830 212 881 1285 2078 2471 1504 816 -258 -446 19 645 487 736 3 205 -82 -475 -1495 -1830 -1820 -1124 -1174 -1439 -1777 -1796 -1253 -548 35 155 728 708 642 340 -3 -297 -187 51 64 712 373 193 -299 -673 -783 -135 -706 -781 -797 -499 -271 383 566 492 494 296 32 26 138 143 106 -105 -186 -82 225 271 320 291 66 637 347 343 143 -20 -275 -130 -318 -127 -80 278 238 -106 -189 -193 -335 -674 -734 -743 -676 -888 -722 -908 -604 -842 -516 -967 -695 -826 -435 -491 -399 -347 -300 -188 -160 -41 -318 -67 -308 -74 -662 -58 -464 -358 -543 -75 -75 109 33 -453 -556 -522 -137 -103 291 -172 154 -98 221 109 219 30 111 -81 8 396 482 832 646 776 454 667 398 399 100 417 604 1087 1443 885 503 -151 -259 12 423 361 541 2 157 -59 -306 -941 -1107 -1157 -769 -879 -1230 -1584 -1692 -1246 -549 37 171 803 763 648 336 -3 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