File name: Pandora101s1_Izana_20220104_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T101205.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v10d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20220104_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20220104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220104T090627.3Z 8039.379482 67 1 50.16 2 77.92 124.30 98.50 112.35 0.00 1 0.00 1 0 17 1.763e-01 1.072e-02 5.840e-02 3.713e-03 5.203896e-01 1.845601e-03 5.574526e-03 -6.000000e+00 9.715829e-02 223.09 -2.00 3.19 -2.00 319.62 0.00e+00 5.564796e-04 5.192952e-04 7.958320e-04 -6.000000e+00 4.176520e-03 273.09 -2.00 20.00 -2.00 319.13 0.00e+00 4.645 0.001 302.00 328.00 3 5.0837e+00 5.1533e-03 4.2427e-02 -6.0000e+00 2.3986e-01 8.2370e-02 6.1316e-03 2.4331e-02 -6.0000e+00 2.6135e-01 -6.3076e-02 5.3115e-03 1.2556e-02 -6.0000e+00 1.5532e-01 1.9491e-02 2.8217e-03 3.8269e-03 -6.0000e+00 6.7041e-02 5.2020e-05 -3.0769e-04 9.8166e-05 3.9385e-05 -6.0000e+00 4.4197e-03 -5.4009e-04 0.0000e+00 12 9 8 11 32 0 -12.16 16.90 0.16 -0.00054 -0.00285 13 3 1 5 0 3858.323 21.69 15.00 16.90 -35730 -97071 -66032 -36393 -37066 -2510 -72419 -6064 -16305 -54373 -63787 -79958 -47946 17620 -15746 -3779 -19105 -1576 -12978 19356 5394 -4077 -8211 -7213 -12953 2796 10109 -13868 -7731 -20223 3398 -5159 14292 3149 -1772 -2969 4295 -5037 3988 8669 -1750 2579 776 4034 -4750 655 4260 923 -1363 4920 1173 -12 1643 4935 3861 2521 2352 3931 716 -1346 2770 1936 -292 3468 1948 791 -107 -496 -302 -1468 2 2758 42 -237 257 -415 -3025 -3469 -3331 -1409 -986 -1406 -512 -1924 -1756 49 -52 -135 942 441 802 473 -441 9 -2350 -283 193 401 -314 764 -230 -642 -1935 -731 -404 -988 -1242 -501 217 876 877 860 1401 304 -659 -182 -696 957 -286 108 -845 873 582 392 635 39 76 799 72 229 219 -277 -494 -127 -10 -153 -250 443 497 -56 -314 90 -994 -572 -3254 -1797 -756 -702 -32 -1876 -96 -329 -1703 -2254 -3429 -1789 440 -655 -166 -1075 -81 -803 935 308 -254 -539 -506 -1045 208 726 -1213 -608 -1782 267 -512 1347 364 -209 -337 478 -706 622 1564 -391 596 191 985 -1262 168 1068 240 -368 1297 343 -4 571 1784 1486 1016 984 1633 299 -559 1116 835 -141 1793 1082 435 -57 -260 -166 -918 1 1926 30 -165 169 -251 -1708 -1903 -1913 -901 -713 -1130 -443 -1756 -1674 49 -54 -144 1005 464 801 446 -397 8 -2223 -290 218 496 -420 1034 -302 -791 -2230 -819 -477 -1234 -1599 -669 301 1293 1384 1416 2313 493 -1025 -270 -1022 1426 -447 175 -1397 1401 914 604 946 57 107 1108 107 367 373 -491 -894 -237 -20 -309 -514 917 1035 -115 -626 172 -1858 SS 20220104T091215.1Z 8039.383508 70 1 47.43 2 76.87 125.15 97.37 112.94 0.00 1 0.00 1 0 17 1.197e-01 8.267e-03 5.602e-02 3.148e-03 4.930557e-01 1.558696e-03 5.273929e-03 -6.000000e+00 6.597473e-02 223.09 -2.00 3.19 -2.00 319.37 0.00e+00 9.002610e-04 4.097937e-04 3.691353e-04 -6.000000e+00 2.835733e-03 273.09 -2.00 20.00 -2.00 318.87 0.00e+00 4.298 0.001 302.00 328.00 3 5.0438e+00 4.3034e-03 3.9492e-02 -6.0000e+00 1.6288e-01 4.5392e-02 5.0658e-03 2.2780e-02 -6.0000e+00 1.7746e-01 -1.1146e-02 4.2926e-03 1.1755e-02 -6.0000e+00 1.0547e-01 -5.3150e-03 2.3026e-03 3.7097e-03 -6.0000e+00 4.5528e-02 7.1956e-05 -2.3020e-04 8.3507e-05 3.6028e-05 -6.0000e+00 3.0006e-03 -1.3278e-03 0.0000e+00 11 9 0 11 8 0 70.07 16.90 0.10 -0.00133 -0.00306 15 4 1 5 0 3162.160 21.69 15.00 16.90 48165 -59829 -31265 3319 -2603 995 -51682 3617 -15900 -21223 -54363 -39659 -47714 23742 -13698 1283 -9025 887 -16421 6721 -759 5365 10847 192 -3518 -8377 12207 -10620 -14 -18261 7132 -757 9715 133 -1586 -860 -4067 -2219 3961 7301 -2599 3153 -608 3619 -6152 -3112 2706 374 -1439 4155 767 -1036 2327 1971 1630 606 1076 1564 1616 -986 2787 1217 966 2643 1351 1302 -1571 -577 -1539 394 -464 833 -793 653 443 445 -2391 -2213 -2718 -946 -529 -1390 -854 -1347 -688 -673 409 588 972 257 688 437 -67 -234 -704 -565 48 857 474 474 -206 -470 -1724 -792 -1042 -514 -993 -206 -91 627 976 891 734 297 -595 -186 50 32 -206 -183 -527 162 490 463 432 156 -110 449 -113 60 205 -102 -425 -205 -58 -78 -80 565 286 41 -52 50 -894 414 -1638 -712 55 -42 14 -1281 61 -369 -569 -2042 -1353 -2053 648 -640 62 -531 51 -1199 417 -52 351 684 14 -298 -793 985 -1035 -1 -1816 617 -82 1085 18 -211 -108 -555 -343 698 1494 -657 808 -168 993 -1852 -921 770 109 -435 1228 249 -374 883 800 702 271 494 721 732 -446 1227 576 503 1490 813 767 -903 -324 -910 257 -336 624 -607 479 309 285 -1441 -1281 -1644 -635 -400 -1166 -769 -1269 -673 -694 437 646 1071 279 711 427 -63 -213 -676 -592 55 1070 636 648 -273 -583 -2010 -904 -1253 -647 -1294 -277 -128 929 1538 1459 1207 477 -919 -274 72 48 -318 -295 -859 259 767 707 642 227 -154 623 -166 94 342 -177 -754 -374 -110 -153 -160 1138 582 83 -102 95 -1642 SS 20220104T091917.9Z 8039.388402 74 1 48.59 2 75.61 126.21 95.99 113.67 0.00 1 0.00 1 0 17 8.944e-02 7.838e-03 3.107e-02 2.529e-03 4.547847e-01 1.246764e-03 4.902601e-03 -6.000000e+00 4.928107e-02 223.09 -2.00 3.19 -2.00 319.03 0.00e+00 -3.705711e-05 2.946727e-04 4.183894e-04 -6.000000e+00 2.118347e-03 273.09 -2.00 20.00 -2.00 318.52 0.00e+00 3.945 0.001 302.00 328.00 3 5.0029e+00 3.3990e-03 3.6317e-02 -6.0000e+00 1.2166e-01 1.2725e-02 3.9400e-03 2.1032e-02 -6.0000e+00 1.3256e-01 6.0945e-03 3.1217e-03 1.0671e-02 -6.0000e+00 7.8781e-02 -1.0206e-02 1.6843e-03 3.1628e-03 -6.0000e+00 3.4006e-02 1.0306e-04 -2.4024e-04 6.7496e-05 3.1057e-05 -6.0000e+00 2.2416e-03 -8.3559e-04 0.0000e+00 11 8 0 10 0 0 83.56 16.91 0.48 -0.00084 -0.00264 19 4 1 5 0 2557.398 21.69 15.00 16.91 20479 -47757 -29368 -17447 5639 -45292 -7880 -20790 1978 -19516 -39901 -30907 -14073 4792 -10792 -3978 -13153 -4012 -9121 10725 1161 8477 -7956 -2371 -1723 9333 3849 -6487 -5575 -11757 5427 -739 7711 658 761 -8098 1917 -5378 3028 2242 1000 333 287 688 -2966 115 2137 737 -1149 2413 -791 391 1627 2338 832 1663 570 2353 -122 -574 1812 839 1779 1968 1599 283 88 -1445 287 -212 311 541 -347 -466 1253 -432 -1706 -2193 -2997 -397 -1406 -526 -1405 -1581 -1512 50 -297 490 955 608 494 335 -559 -564 -1258 -591 550 668 493 320 241 -822 -1177 -791 -87 -1007 -610 -529 -141 726 1102 777 929 563 -552 -208 -140 33 -85 127 -449 345 317 11 313 259 -124 509 203 53 -46 -205 -128 -539 -329 -128 48 367 479 196 -279 -33 -619 306 -1622 -898 -481 112 -1369 -176 -599 53 -707 -1806 -1321 -597 206 -647 -263 -1034 -312 -794 815 101 686 -762 -232 -184 956 429 -776 -621 -1378 593 -98 1062 106 119 -1312 297 -1025 646 575 292 103 93 228 -1013 39 711 249 -400 829 -295 158 701 1059 402 819 294 1203 -62 -290 899 442 1018 1222 1043 182 54 -880 179 -148 239 432 -281 -367 932 -300 -1098 -1368 -1945 -280 -1118 -457 -1317 -1543 -1542 53 -328 555 1086 682 530 340 -540 -529 -1244 -632 635 839 665 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