File name: Pandora101s1_Izana_20220210_L2Fit_fout2c16d20210210p1-8.txt File generation date: 20240504T095811.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v10d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20220210_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20220210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0133 305.1541 305.2949 305.4357 305.5766 305.7173 305.8581 305.9989 306.1397 306.2804 306.4211 306.5619 306.7026 306.8433 306.9840 307.1247 307.2653 307.4060 307.5466 307.6873 307.8279 307.9685 308.1091 308.2497 308.3903 308.5309 308.6714 308.8120 308.9525 309.0930 309.2335 309.3740 309.5145 309.6550 309.7954 309.9359 310.0763 310.2168 310.3572 310.4976 310.6380 310.7784 310.9187 311.0591 311.1994 311.3398 311.4801 311.6204 311.7607 311.9010 312.0413 312.1816 312.3218 312.4621 312.6023 312.7425 312.8827 313.0229 313.1631 313.3033 313.4435 313.5836 313.7238 313.8639 314.0040 314.1441 314.2842 314.4243 314.5644 314.7044 314.8445 314.9845 315.1246 315.2646 315.4046 315.5446 315.6845 315.8245 315.9645 316.1044 316.2443 316.3843 316.5242 316.6641 316.8040 316.9438 317.0837 317.2236 317.3634 317.5032 317.6430 317.7829 317.9226 318.0624 318.2022 318.3420 318.4817 318.6214 318.7612 318.9009 319.0406 319.1803 319.3200 319.4596 319.5993 319.7389 319.8785 320.0182 320.1578 320.2974 320.4370 320.5765 320.7161 320.8556 320.9952 321.1347 321.2742 321.4137 321.5532 321.6927 321.8322 321.9716 322.1111 322.2505 322.3899 322.5293 322.6687 322.8081 322.9475 323.0868 323.2262 323.3655 323.5048 323.6442 323.7835 323.9228 324.0620 324.2013 324.3406 324.4798 324.6190 324.7582 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220210T083111.4Z 8076.354993 113 1 48.86 2 81.79 111.18 129.13 3.05 0.00 1 0.00 1 0 17 4.790e-01 1.461e-02 1.815e-01 3.986e-03 7.332492e-01 2.089882e-03 7.525764e-03 -6.000000e+00 2.645693e-01 223.73 -2.00 3.19 -2.00 321.18 0.00e+00 7.645567e-04 9.149274e-04 1.808289e-03 -6.000000e+00 1.135606e-02 272.58 -2.00 20.00 -2.00 320.75 0.00e+00 6.596 0.003 302.00 328.00 3 3.3762e+00 6.6287e-03 6.0954e-02 -6.0000e+00 6.5419e-01 1.3092e-01 9.3252e-03 3.7025e-02 -6.0000e+00 7.1291e-01 -2.7972e-01 1.0227e-02 2.0417e-02 -6.0000e+00 4.2313e-01 1.1501e-01 4.9725e-03 6.5615e-03 -6.0000e+00 1.8361e-01 6.0122e-05 -6.6297e-04 1.0324e-04 7.7611e-05 -6.0000e+00 1.2123e-02 -1.7976e-04 0.0000e+00 12 8 8 10 0 0 98.25 16.71 0.27 -0.00018 -0.00516 50 12 1 5 0 977.108 21.48 15.01 16.71 900000 -229832 -48215 -181281 -111985 -150156 -152152 -69106 30370 -160385 -167703 -175914 -94058 -57427 -78953 -94939 -71279 -10876 -39414 4284 -41539 7032 -14057 -21047 15105 -136118 73502 -32720 4975 -55166 20977 -6411 37208 7248 28226 -9289 17513 -8706 35283 25832 10561 19474 10821 24594 -6063 6883 13203 6048 2557 19503 10835 3470 6312 14244 7566 8304 9992 10023 8812 4394 8844 4066 5142 4899 5581 4047 2473 3392 1019 1224 3185 3967 1255 1138 3249 775 -3572 -1627 -3544 -951 -1394 -138 -1503 -2501 -2489 354 -198 555 658 224 473 54 -402 -562 -2010 -1291 -53 -952 -205 -438 -501 -1127 -1845 -1208 -1276 -1121 -1324 -198 -855 149 -316 591 494 -66 -114 405 401 833 -37 348 -669 975 954 543 892 408 439 756 517 453 609 99 -155 -270 -121 -382 292 277 37 -156 -209 -391 -756 900000 -4954 -206 -2690 -752 -1379 -1505 -376 118 -2550 -3022 -3729 -1097 -609 -1339 -2348 -1612 -150 -794 59 -939 97 -243 -431 240 -9699 800 -913 91 -1910 400 -199 894 266 828 -374 569 -431 1396 1387 769 1417 910 1860 -573 635 1171 546 253 1895 1169 460 906 2076 1274 1460 1806 1831 1578 790 1518 789 1129 1247 1562 1154 699 970 323 418 1209 1590 521 449 1151 271 -1189 -526 -1277 -369 -650 -74 -921 -1657 -1749 241 -143 413 493 164 325 37 -266 -376 -1513 -1049 -50 -1048 -237 -527 -575 -1254 -1829 -1142 -1292 -1216 -1508 -222 -1053 206 -467 946 815 -107 -177 594 579 1246 -60 585 -1137 1564 1458 809 1364 606 623 1074 776 789 1117 198 -326 -572 -274 -925 723 694 89 -385 -484 -843 -1632 SS 20220210T084540.6Z 8076.365054 118 1 48.50 2 78.84 113.10 128.83 7.14 0.00 1 0.00 1 0 17 2.340e-01 6.413e-03 2.613e-02 1.110e-03 5.826007e-01 5.584979e-04 6.135580e-03 -6.000000e+00 1.292569e-01 223.73 -2.00 3.19 -2.00 320.12 0.00e+00 1.652366e-03 1.844867e-04 3.691833e-04 -6.000000e+00 5.531298e-03 272.58 -2.00 20.00 -2.00 319.66 0.00e+00 4.997 0.001 302.00 328.00 3 2.4278e+00 1.6074e-03 4.6321e-02 -6.0000e+00 3.1961e-01 -1.6447e-02 1.9983e-03 2.7365e-02 -6.0000e+00 3.4810e-01 -3.2258e-02 1.9558e-03 1.4466e-02 -6.0000e+00 2.0672e-01 5.2396e-03 1.0171e-03 4.9530e-03 -6.0000e+00 8.9076e-02 5.6598e-04 -4.3721e-04 2.8958e-05 4.6853e-05 -6.0000e+00 5.8658e-03 -1.0914e-03 0.0000e+00 11 8 0 10 0 0 55.14 16.72 0.25 -0.00109 -0.00438 225 53 1 5 0 215.559 21.48 15.01 16.72 -108556 -65683 -77448 -61270 -76552 -90071 -80686 -73826 -50069 -65841 -56895 -75014 -43264 -41976 -21902 -31073 -12012 -16536 -8037 -9612 -4905 -6521 -11820 -7965 -8456 -20025 -6552 -5183 -12364 -9474 -9950 253 -2330 413 -5438 -4541 -3930 -2146 1095 2013 2419 199 1258 756 2150 295 2623 357 1327 468 1891 1591 2937 2353 1692 1977 1095 1372 123 1088 322 1775 1765 3044 1650 1352 221 -129 577 877 626 631 139 141 446 -906 -1143 -2503 -1608 -1542 -1074 -1293 -1526 -1933 -1314 -534 12 388 546 883 521 570 -550 -93 -633 -14 -235 678 381 370 -267 -623 -713 -434 -720 -1004 -716 -577 -110 324 502 330 508 254 41 73 117 160 3 -21 -435 -62 245 365 233 349 -27 718 399 326 47 17 -149 -139 -295 -246 -117 273 340 -131 -152 -145 -301 -1552 -747 -1099 -750 -995 -1258 -1083 -1063 -661 -1134 -936 -1576 -806 -991 -536 -1019 -372 -537 -289 -340 -173 -234 -456 -323 -380 -1088 -323 -247 -607 -461 -556 15 -170 33 -452 -354 -323 -203 124 277 382 32 212 133 376 54 475 67 258 96 417 396 796 698 541 659 383 484 43 365 109 642 666 1289 770 623 99 -57 273 479 361 387 87 84 265 -488 -559 -1202 -816 -918 -697 -966 -1188 -1605 -1150 -497 12 396 561 883 491 496 -453 -75 -557 -14 -255 837 497 497 -343 -772 -791 -467 -836 -1253 -877 -749 -153 470 766 542 843 410 65 110 173 245 4 -35 -724 -100 399 575 352 508 -38 1040 604 531 85 32 -283 -265 -601 -510 -250 590 741 -281 -323 -290 -572 SS 20220210T085250.2Z 8076.370025 122 1 48.55 2 77.39 114.08 128.60 9.14 0.00 1 0.00 1 0 25 1.346e-01 5.834e-03 1.305e-02 7.598e-04 5.269268e-01 3.766087e-04 5.597541e-03 -6.000000e+00 7.435197e-02 223.73 -2.00 3.19 -2.00 319.65 0.00e+00 1.359679e-03 1.075057e-04 2.613545e-04 -6.000000e+00 3.181579e-03 272.58 -2.00 20.00 -2.00 319.17 0.00e+00 4.464 0.001 302.00 328.00 3 2.1862e+00 1.0553e-03 4.1486e-02 -6.0000e+00 1.8385e-01 -2.0901e-02 1.2560e-03 2.4498e-02 -6.0000e+00 2.0023e-01 -1.8595e-02 1.1207e-03 1.2646e-02 -6.0000e+00 1.1891e-01 2.7257e-04 5.9778e-04 4.1491e-03 -6.0000e+00 5.1241e-02 1.1189e-03 -4.2166e-04 1.9901e-05 3.9200e-05 -6.0000e+00 3.3739e-03 -1.4824e-03 0.0000e+00 10 0 0 10 0 0 75.22 16.72 0.22 -0.00148 -0.00465 331 78 1 5 0 146.669 21.48 15.00 16.72 -49936 -41786 -43962 -41245 -57225 -47288 -51277 -40151 -38269 -31395 -35182 -36055 -26948 -19020 -12367 -12882 -7346 -5925 -3146 -4233 -2429 -6928 -4154 -5565 -2772 -10612 -3318 -6716 -7141 -6570 -3686 18 217 257 -3224 -3839 -4460 -1866 -175 1482 629 614 835 436 609 500 894 764 -131 419 1087 1078 1856 1617 2018 1443 1293 1067 474 638 699 1524 1806 2592 1673 811 -85 -473 -152 890 466 789 48 -25 -194 -374 -1392 -2020 -1830 -1189 -1111 -1232 -1749 -1737 -1276 -621 -87 135 641 866 704 549 -93 -248 -419 -46 -9 726 462 222 -317 -550 -525 -156 -567 -864 -745 -507 -345 327 617 389 461 221 58 -53 44 140 89 -99 -285 -65 186 227 351 309 -37 623 352 283 111 1 -173 -87 -280 -164 -63 284 235 -52 -185 -163 -364 -755 -703 -831 -764 -1128 -788 -935 -750 -814 -691 -834 -906 -739 -607 -461 -529 -322 -279 -157 -226 -133 -398 -235 -347 -185 -820 -247 -504 -513 -472 -289 2 22 30 -376 -425 -525 -250 -28 265 130 138 197 107 150 125 226 196 -35 115 320 355 665 581 769 575 536 448 196 256 282 655 871 1397 910 435 -47 -260 -82 547 325 545 34 -17 -131 -227 -771 -1081 -1031 -774 -791 -1003 -1488 -1565 -1213 -630 -87 141 674 888 721 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