File name: Pandora101s1_Izana_20220221_L2Fit_fwvt1c16d20210210p1-8.txt File generation date: 20240504T094659.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c16p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v10d20170928.txt Instrument calibration file used: Pandora101s1_CF_v16d20210210.txt Level 1 file used: Pandora101s1_Izana_20220221_L1_smca1c16d20210210p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20220221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for VP 20210210 First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0542 492.1752 492.2961 492.4171 492.5380 492.6589 492.7798 492.9006 493.0215 493.1423 493.2631 493.3839 493.5047 493.6255 493.7462 493.8670 493.9877 494.1084 494.2291 494.3497 494.4704 494.5910 494.7116 494.8322 494.9528 495.0734 495.1939 495.3145 495.4350 495.5555 495.6760 495.7965 495.9169 496.0373 496.1578 496.2782 496.3986 496.5189 496.6393 496.7596 496.8800 497.0003 497.1205 497.2408 497.3611 497.4813 497.6015 497.7217 497.8419 497.9621 498.0823 498.2024 498.3225 498.4426 498.5627 498.6828 498.8029 498.9229 499.0429 499.1629 499.2829 499.4029 499.5229 499.6428 499.7627 499.8827 500.0025 500.1224 500.2423 500.3621 500.4820 500.6018 500.7216 500.8413 500.9611 501.0808 501.2006 501.3203 501.4400 501.5597 501.6793 501.7990 501.9186 502.0382 502.1578 502.2774 502.3969 502.5165 502.6360 502.7555 502.8750 502.9945 503.1140 503.2334 503.3528 503.4723 503.5916 503.7110 503.8304 503.9497 504.0691 504.1884 504.3077 504.4270 504.5462 504.6655 504.7847 504.9039 505.0231 505.1423 505.2615 505.3806 505.4997 505.6188 505.7379 505.8570 505.9761 506.0951 506.2142 506.3332 506.4522 506.5712 506.6901 506.8091 506.9280 507.0469 507.1658 507.2847 507.4036 507.5224 507.6412 507.7601 507.8788 507.9976 508.1164 508.2351 508.3539 508.4726 508.5913 508.7100 508.8286 508.9473 509.0659 509.1845 509.3031 509.4217 509.5403 509.6588 509.7773 509.8959 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220221T101752.4Z 8087.429078 2 1 48.53 2 58.59 124.83 86.93 256.79 0.00 1 0.00 1 0 15 2.507e-03 2.492e-03 3.659e-04 3.650e-04 7.451387e+02 2.024947e+01 4.747933e+01 -6.000000e+00 1.359261e+02 272.85 -2.00 20.00 -2.00 505.24 0.00e+00 4.667821e-04 9.753859e-06 2.728289e-05 -6.000000e+00 6.873392e-05 272.85 -2.00 20.00 -2.00 500.39 0.00e+00 8.066223e-02 7.216869e-03 6.323452e-03 -6.000000e+00 4.991563e-02 224.27 -2.00 3.19 -2.00 501.98 0.00e+00 1.912 0.000 489.00 513.00 1 6.0378e+00 5.5024e-04 2.2290e-03 -6.0000e+00 3.8123e-03 9.6709e-03 1.4417e-04 1.7483e-04 -6.0000e+00 9.9641e-04 3.7627e-03 1.1247e-03 3.6557e-05 1.3178e-05 -6.0000e+00 2.5585e-04 -4.1464e-04 2.5193e-05 10 0 0 10 0 0 99.99 16.52 1.50 -0.00041 0.00739 432 102 1 4 0 112.328 21.27 14.99 16.52 -407 -296 -190 140 174 284 534 409 499 337 123 116 26 -72 -136 -151 -80 44 258 163 129 233 179 101 270 238 35 72 -21 -278 -505 -338 -315 -97 112 -52 -94 -49 -83 -182 -120 -49 80 152 247 187 242 54 7 -137 -417 -549 -564 -603 -242 -83 -45 44 75 129 160 269 291 287 247 155 8 -176 -149 -150 -263 -224 -223 -182 2 -110 -321 -343 -220 -315 -331 -288 -259 -280 -121 -188 -131 -78 -222 -50 -65 45 165 712 129 90 -76 -130 -153 -442 -504 -458 -342 -194 -76 -192 -170 -174 -151 -82 71 47 228 324 410 385 384 344 362 218 186 169 115 282 118 84 251 222 113 187 144 -57 -144 -217 -136 -156 124 45 154 248 290 220 285 231 110 21 -47 -304 -452 -438 -390 -288 -190 144 176 293 559 432 525 351 127 117 26 -75 -140 -156 -80 45 270 173 137 248 190 108 289 254 37 76 -22 -277 -495 -331 -316 -101 119 -55 -100 -52 -86 -187 -124 -51 84 160 262 199 255 56 7 -137 -406 -548 -557 -600 -235 -83 -46 46 77 133 165 277 301 296 253 157 8 -173 -145 -144 -251 -214 -215 -178 2 -108 -309 -326 -207 -295 -312 -273 -248 -271 -118 -185 -129 -77 -220 -49 -65 46 169 728 132 91 -75 -126 -145 -411 -467 -431 -331 -194 -77 -188 -171 -173 -149 -81 71 46 225 322 410 386 387 346 361 214 180 161 114 282 113 81 240 212 108 178 143 -56 -138 -206 -129 -149 121 43 149 242 284 216 281 230 110 20 -45 -288 -439 -423 SQ 20220221T102218.5Z 8087.432158 5 1 49.16 2 57.79 125.70 87.86 257.29 0.00 1 0.00 1 0 15 3.691e-03 3.783e-03 1.056e-03 1.054e-03 7.647653e+02 5.859845e+01 1.472420e+01 -6.000000e+00 2.001423e+02 272.85 -2.00 20.00 -2.00 505.24 0.00e+00 4.144006e-04 2.832172e-05 2.891359e-05 -6.000000e+00 1.012072e-04 272.85 -2.00 20.00 -2.00 500.39 0.00e+00 8.444169e-02 2.092353e-02 1.360513e-02 -6.000000e+00 7.350237e-02 224.27 -2.00 3.19 -2.00 501.99 0.00e+00 1.870 0.000 489.00 513.00 1 8.1977e+00 1.5995e-03 2.3757e-03 -6.0000e+00 5.6136e-03 1.2351e-02 4.1736e-04 2.5737e-04 -6.0000e+00 1.4674e-03 4.3610e-04 1.1485e-03 1.0496e-04 1.0502e-05 -6.0000e+00 3.7672e-04 -2.6418e-04 1.8605e-05 11 8 0 10 0 0 99.98 16.54 1.51 -0.00026 0.00770 31 7 1 4 0 1585.764 21.38 15.00 16.54 -129 -391 -192 72 112 304 604 592 417 459 131 72 -101 181 -337 -151 -156 205 90 101 23 286 148 118 291 256 -38 -3 250 -419 -273 -478 -265 -336 279 -29 -195 82 -166 -296 -146 58 24 113 76 429 307 260 -363 -21 -330 -474 -563 -135 -19 -259 -106 -167 125 128 227 126 254 176 471 -91 -127 -226 -289 -232 -146 -215 -177 -199 -218 257 -235 -121 -203 -71 -340 -267 -290 7 -145 -44 62 145 53 62 2 250 374 -3146 -498 342 273 -231 292 -117 -353 -129 -305 -42 -149 420 -56 -390 -199 159 -4 14 31 222 296 512 616 395 424 279 260 229 161 168 230 324 63 138 265 138 62 232 43 -222 -144 263 -64 19 94 363 79 293 225 181 -91 -9 -423 -207 -488 -300 -127 -392 -189 73 117 322 651 614 433 492 139 75 -104 183 -341 -153 -160 215 93 106 25 299 155 124 306 270 -40 -3 263 -431 -275 -484 -273 -343 290 -30 -204 84 -169 -300 -148 58 25 117 79 447 319 266 -366 -22 -330 -463 -544 -131 -19 -267 -106 -169 126 129 229 128 258 178 472 -91 -125 -228 -289 -229 -143 -211 -176 -200 -211 257 -232 -118 -196 -68 -329 -260 -285 7 -139 -43 60 140 51 61 2 248 375 -3281 -502 337 264 -219 281 -111 -335 -123 -289 -41 -149 417 -55 -380 -192 153 -4 14 31 226 304 525 634 407 432 281 257 224 157 164 226 318 62 136 258 134 60 221 40 -206 -133 246 -61 18 92 361 79 295 217 176 -88 -9 -420 -200 -464 -283 SQ 20220221T102807.1Z 8087.436193 9 1 48.60 2 56.76 126.88 89.08 257.95 0.00 1 0.00 1 0 8 4.271e-03 4.329e-03 9.376e-04 9.352e-04 5.546996e+02 5.127250e+01 1.978404e+01 -6.000000e+00 2.315770e+02 272.86 -2.00 20.00 -2.00 505.24 0.00e+00 4.321207e-04 2.505714e-05 3.086426e-05 -6.000000e+00 1.171081e-04 272.86 -2.00 20.00 -2.00 500.38 0.00e+00 4.915473e-02 1.852723e-02 1.592147e-02 -6.000000e+00 8.506352e-02 224.28 -2.00 3.19 -2.00 501.98 0.00e+00 1.819 0.000 489.00 513.00 1 7.9883e+00 1.4154e-03 2.4093e-03 -6.0000e+00 6.4963e-03 1.2255e-02 3.7039e-04 2.6330e-04 -6.0000e+00 1.6986e-03 5.4219e-04 1.5083e-04 9.3410e-05 1.1902e-05 -6.0000e+00 4.3588e-04 9.2476e-06 -4.2558e-07 11 8 0 10 0 0 99.85 16.55 1.55 0.00001 0.00106 31 7 1 4 0 1567.745 21.38 15.00 16.55 -247 -586 -122 188 291 419 582 406 378 503 414 7 13 -104 -287 -100 -248 80 63 348 -13 376 148 278 289 166 -72 -140 128 -424 -209 -733 -189 -317 248 -7 -150 153 -141 -315 -167 -100 -113 243 156 383 249 306 -231 34 -398 -266 -712 -357 -465 -128 119 -234 186 161 53 36 371 307 576 -193 21 28 29 -80 -140 -348 -259 -130 -86 -4 -264 -103 -304 -29 101 -517 -744 106 -273 -74 -52 82 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