File name: Pandora101s1_Izana_20231006_L2Fit_fwvt1c12d20230620p1-8.txt File generation date: 20231007T142838.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v12d20230620.txt Level 1 file used: Pandora101s1_Izana_20231006_L1_smca1c12d20230620p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20231006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 11 First and last pixel inside fitting window: 1642 1792 Nominal wavelengths inside fitting window [nm]: 492.0279 492.1490 492.2700 492.3910 492.5120 492.6329 492.7539 492.8748 492.9957 493.1166 493.2375 493.3584 493.4792 493.6001 493.7209 493.8417 493.9624 494.0832 494.2040 494.3247 494.4454 494.5661 494.6868 494.8074 494.9281 495.0487 495.1693 495.2899 495.4105 495.5311 495.6516 495.7721 495.8927 496.0132 496.1336 496.2541 496.3745 496.4950 496.6154 496.7358 496.8561 496.9765 497.0969 497.2172 497.3375 497.4578 497.5781 497.6983 497.8186 497.9388 498.0590 498.1792 498.2994 498.4195 498.5397 498.6598 498.7799 498.9000 499.0201 499.1401 499.2601 499.3802 499.5002 499.6202 499.7401 499.8601 499.9800 500.1000 500.2199 500.3397 500.4596 500.5795 500.6993 500.8191 500.9389 501.0587 501.1785 501.2982 501.4180 501.5377 501.6574 501.7771 501.8967 502.0164 502.1360 502.2556 502.3752 502.4948 502.6144 502.7339 502.8534 502.9730 503.0925 503.2119 503.3314 503.4508 503.5703 503.6897 503.8091 503.9285 504.0478 504.1672 504.2865 504.4058 504.5251 504.6444 504.7636 504.8829 505.0021 505.1213 505.2405 505.3596 505.4788 505.5979 505.7171 505.8362 505.9552 506.0743 506.1934 506.3124 506.4314 506.5504 506.6694 506.7884 506.9073 507.0262 507.1452 507.2641 507.3829 507.5018 507.6207 507.7395 507.8583 507.9771 508.0959 508.2146 508.3334 508.4521 508.5708 508.6895 508.8082 508.9268 509.0455 509.1641 509.2827 509.4013 509.5199 509.6384 509.7569 509.8755 509.9940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231006T070646.3Z 8679.296369 213 1 18.44 2 89.65 95.93 3.59 268.85 0.00 1 0.00 1 0 29 6.359e-03 6.283e-03 1.625e-04 1.621e-04 1.312762e+04 1.127948e+01 8.575839e+02 -6.000000e+00 3.549416e+02 279.35 -2.00 20.00 -2.00 505.41 0.00e+00 1.732461e-03 4.502080e-06 1.149940e-04 -6.000000e+00 1.781189e-04 279.35 -2.00 20.00 -2.00 500.99 0.00e+00 1.147373e+00 3.166324e-03 9.915445e-02 -6.000000e+00 1.271384e-01 226.02 -2.00 3.19 -2.00 502.51 0.00e+00 20.295 0.086 489.00 513.00 1 2.6302e+00 2.4209e-04 2.5521e-02 -6.0000e+00 9.7443e-03 -4.9828e-02 6.0699e-05 2.6918e-03 -6.0000e+00 2.5191e-03 1.3848e-02 -8.7899e-04 1.5632e-05 1.0677e-04 -6.0000e+00 6.7335e-04 1.8617e-02 -4.8035e-04 12 9 8 11 4 0 -14.25 21.06 2.65 0.01862 0.01252 539 137 1 4 0 34.210 21.06 15.00 14.57 18.16 0.0 954.57 900000 -1526 -959 -362 215 627 991 1205 1134 1009 644 184 -117 -469 -586 -692 -522 -232 209 533 436 382 446 466 549 707 570 272 -43 -448 -1037 -1114 -836 -419 79 275 151 81 15 -216 -162 -26 176 374 626 712 764 606 270 -107 -499 -942 -1232 -1262 -952 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540 611 498 403 295 129 104 44 -259 -512 -561 -553 -288 -94 66 261 396 358 385 372 377 256 142 -147 -624 -989 -1056 SQ 20231006T070703.6Z 8679.296570 213 2 15.81 2 89.59 95.96 3.65 268.90 0.00 1 0.00 1 0 22 6.154e-03 6.087e-03 1.639e-04 1.635e-04 1.292450e+04 1.133868e+01 8.468151e+02 -6.000000e+00 3.434661e+02 279.35 -2.00 20.00 -2.00 505.40 0.00e+00 1.709501e-03 4.541155e-06 1.130470e-04 -6.000000e+00 1.723553e-04 279.35 -2.00 20.00 -2.00 500.99 0.00e+00 1.144464e+00 3.189897e-03 9.732817e-02 -6.000000e+00 1.230183e-01 226.02 -2.00 3.19 -2.00 502.50 0.00e+00 20.195 0.085 489.00 513.00 1 2.5084e+00 2.4389e-04 2.5323e-02 -6.0000e+00 9.4287e-03 -4.7736e-02 6.1257e-05 2.6508e-03 -6.0000e+00 2.4373e-03 1.5824e-02 -7.9616e-04 1.5728e-05 1.0324e-04 -6.0000e+00 6.5155e-04 1.6152e-02 -4.6023e-04 12 9 9 12 5 1 -10.24 21.06 2.55 0.01615 0.01063 461 137 1 4 0 34.210 21.06 15.00 14.57 18.16 0.0 954.57 900000 -1437 -913 -355 258 578 1003 1150 1063 971 614 130 -130 -444 -557 -660 -522 -195 169 483 428 387 455 479 556 708 517 233 -19 -420 -984 -1041 -786 -409 94 223 114 28 -27 -183 -172 -36 177 402 595 694 708 552 248 -133 -491 -929 -1148 -1166 -888 -354 -3 261 408 596 728 796 799 723 643 512 248 -113 -371 -513 -572 -689 -673 -504 -319 -309 -610 -904 -916 -880 -872 -880 -793 -570 -450 -443 -555 -425 -332 -189 -17 220 387 627 704 638 404 -30 -464 -788 -1149 -1274 -1005 -620 -288 -218 -360 -380 -329 -299 -129 31 305 653 999 1271 1338 1280 1015 757 397 357 362 438 516 578 492 413 257 109 117 2 -271 -535 -521 -509 -230 -70 72 248 360 324 298 400 349 235 63 -187 -576 -884 -928 900000 -1300 -821 -328 240 551 951 1107 1033 943 593 124 -123 -417 -520 -615 -491 -187 162 471 423 384 453 468 547 700 513 231 -18 -412 -947 -992 -755 -402 93 221 114 28 -27 -183 -171 -36 175 402 601 707 724 563 250 -133 -490 -908 -1103 -1116 -862 -351 -3 265 409 597 730 802 809 736 654 517 249 -112 -372 -509 -564 -677 -665 -503 -315 -307 -603 -902 -901 -858 -849 -859 -779 -565 -442 -440 -556 -426 -332 -188 -17 220 392 626 711 629 396 -29 -443 -741 -1075 -1201 -950 -598 -289 -221 -364 -382 -336 -305 -130 32 314 676 1035 1322 1376 1334 1070 799 416 368 375 452 534 590 505 426 265 113 121 2 -276 -541 -526 -519 -238 -72 76 261 383 350 319 429 377 253 67 -202 -615 -937 -987 SQ 20231006T070930.3Z 8679.298268 217 1 11.43 2 89.06 96.25 4.18 269.29 0.00 1 0.00 1 0 22 4.768e-03 4.722e-03 1.622e-04 1.619e-04 1.136219e+04 1.107137e+01 7.543369e+02 -6.000000e+00 2.660928e+02 279.35 -2.00 20.00 -2.00 505.38 0.00e+00 1.488494e-03 4.484448e-06 9.894915e-05 -6.000000e+00 1.335471e-04 279.35 -2.00 20.00 -2.00 500.90 0.00e+00 1.175091e+00 3.171380e-03 8.484047e-02 -6.000000e+00 9.535134e-02 226.02 -2.00 3.19 -2.00 502.42 0.00e+00 19.105 0.072 489.00 513.00 1 2.2879e+00 2.4252e-04 2.3428e-02 -6.0000e+00 7.3076e-03 -3.4416e-02 6.1148e-05 2.3567e-03 -6.0000e+00 1.8901e-03 2.2248e-02 -4.2108e-04 1.5816e-05 9.2544e-05 -6.0000e+00 5.0496e-04 1.0686e-02 -4.5997e-04 12 9 8 11 4 0 0.85 21.06 1.92 0.01069 0.00777 523 133 1 4 0 21.850 21.06 15.01 14.58 18.27 0.0 955.21 900000 -1065 -671 -262 209 462 814 957 856 834 522 136 -66 -325 -401 -498 -338 -150 173 410 337 305 383 354 420 542 393 153 -39 -268 -727 -822 -600 -323 21 117 -14 -26 1 -162 -159 -48 97 244 440 501 537 421 157 -146 -349 -734 -903 -946 -724 -302 -38 157 270 465 550 610 614 596 496 393 183 -69 -278 -317 -408 -514 -521 -441 -273 -241 -468 -704 -721 -647 -657 -698 -606 -463 -399 -408 -482 -375 -223 -193 -27 182 264 490 464 504 313 -16 -349 -575 -843 -945 -752 -544 -290 -265 -334 -321 -196 -112 -84 -6 250 508 799 1035 1087 966 792 603 372 355 290 332 404 416 369 331 178 82 74 53 -200 -352 -365 -338 -202 -97 16 148 322 267 287 261 231 127 65 -82 -394 -629 -704 900000 -970 -607 -245 196 444 779 931 840 817 508 131 -63 -307 -385 -478 -326 -145 170 402 335 305 383 356 415 538 390 152 -39 -263 -699 -800 -575 -318 21 119 -14 -27 1 -162 -159 -48 98 249 443 508 547 427 157 -147 -345 -726 -877 -916 -710 -296 -38 158 274 471 558 620 628 613 509 401 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