File name: Pandora101s1_Izana_20231106_L2Fit_fout2c12d20230620p1-8.txt File generation date: 20231107T005411.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v12d20230620.txt Level 1 file used: Pandora101s1_Izana_20231106_L1_smca1c12d20230620p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20231106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 11 First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1333 305.2742 305.4151 305.5559 305.6968 305.8376 305.9784 306.1192 306.2600 306.4008 306.5416 306.6823 306.8231 306.9638 307.1045 307.2452 307.3859 307.5266 307.6673 307.8080 307.9486 308.0893 308.2299 308.3706 308.5112 308.6518 308.7924 308.9329 309.0735 309.2141 309.3546 309.4951 309.6357 309.7762 309.9167 310.0572 310.1976 310.3381 310.4786 310.6190 310.7594 310.8998 311.0403 311.1807 311.3210 311.4614 311.6018 311.7421 311.8825 312.0228 312.1631 312.3034 312.4437 312.5840 312.7243 312.8645 313.0048 313.1450 313.2852 313.4254 313.5656 313.7058 313.8460 313.9862 314.1263 314.2665 314.4066 314.5467 314.6869 314.8270 314.9670 315.1071 315.2472 315.3872 315.5273 315.6673 315.8073 315.9473 316.0873 316.2273 316.3673 316.5073 316.6472 316.7871 316.9271 317.0670 317.2069 317.3468 317.4867 317.6265 317.7664 317.9062 318.0461 318.1859 318.3257 318.4655 318.6053 318.7451 318.8848 319.0246 319.1643 319.3041 319.4438 319.5835 319.7232 319.8629 320.0025 320.1422 320.2819 320.4215 320.5611 320.7007 320.8403 320.9799 321.1195 321.2591 321.3986 321.5382 321.6777 321.8172 321.9568 322.0962 322.2357 322.3752 322.5147 322.6541 322.7936 322.9330 323.0724 323.2118 323.3512 323.4906 323.6300 323.7693 323.9087 324.0480 324.1873 324.3266 324.4659 324.6052 324.7445 324.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231106T090725.6Z 8710.380158 288 1 25.62 2 69.60 122.23 19.26 238.97 0.00 1 0.00 1 0 17 2.039e-02 7.649e-03 1.582e-02 3.495e-03 3.449780e-01 1.753716e-03 3.768548e-03 -6.000000e+00 1.157099e-02 224.44 -2.00 3.19 -2.00 317.74 0.00e+00 1.354141e-03 2.880712e-04 8.713905e-05 -6.000000e+00 5.037933e-04 276.72 -2.00 20.00 -2.00 317.17 0.00e+00 2.842 0.000 302.00 328.00 3 6.9206e+00 4.6284e-03 2.6749e-02 -6.0000e+00 2.8604e-02 1.0401e-01 5.2200e-03 1.5968e-02 -6.0000e+00 3.1058e-02 -2.0560e-03 3.3752e-03 7.9848e-03 -6.0000e+00 1.8469e-02 -6.1888e-03 1.7678e-03 2.6413e-03 -6.0000e+00 8.0226e-03 3.6851e-05 4.3159e-04 9.7159e-05 2.5937e-05 -6.0000e+00 5.4695e-04 -2.1647e-02 0.0000e+00 12 9 1 12 13 1 99.93 20.96 0.12 -0.02165 -0.01840 8 4 1 5 0 2846.130 20.96 15.00 14.35 11.62 0.1 896.52 -7637 2347 -3350 4873 -10561 -5728 -1303 -7984 -4078 -4516 -3495 -1938 -1785 -1560 3017 -1361 -196 2354 -817 2784 -1631 3986 -715 2383 -2569 2218 -2278 -1221 -624 2684 1112 1094 -2610 -4528 -3817 -1074 -1253 -1351 1729 301 29 107 -802 -213 -313 -175 -97 -423 23 -25 806 632 1544 1173 1034 1374 376 -318 -458 519 1070 1876 1662 1012 -609 -113 -906 0 744 404 708 -6 1230 -105 -358 -806 -1601 -1874 -985 -2433 -1190 -1312 -2161 -1075 -872 550 412 1246 677 979 -24 -212 -668 -432 -1126 680 989 826 709 314 -581 -1366 -328 -904 -913 -725 -642 -163 731 907 1052 830 374 97 -455 -1226 -615 -281 -488 -5 385 373 188 683 309 -128 268 238 -538 117 52 104 -125 396 -73 -55 521 314 43 -429 -216 -776 -560 168 -255 313 -720 -379 -90 -656 -352 -403 -311 -185 -200 -202 430 -223 -33 413 -155 527 -324 747 -146 503 -588 509 -520 -266 -130 560 261 278 -747 -1312 -1032 -294 -378 -477 693 137 14 53 -414 -110 -162 -90 -49 -218 12 -13 449 372 957 749 680 923 258 -216 -304 342 735 1369 1304 827 -493 -87 -670 0 600 353 650 -6 1142 -94 -303 -624 -1176 -1376 -773 -2129 -1134 -1321 -2277 -1179 -1004 652 503 1531 823 1143 -27 -221 -669 -439 -1238 793 1240 1102 965 419 -744 -1632 -383 -1105 -1182 -963 -877 -228 1068 1379 1652 1303 571 142 -639 -1665 -846 -400 -732 -8 586 560 278 975 429 -172 353 321 -770 173 80 162 -198 647 -125 -95 911 557 77 -743 -368 -1268 SS 20231106T093118.1Z 8710.396737 301 1 22.63 2 65.26 126.29 23.93 247.46 0.00 1 0.00 1 0 17 9.973e-03 5.759e-03 4.056e-03 1.369e-03 2.886189e-01 6.875132e-04 3.188614e-03 -6.000000e+00 5.659956e-03 224.44 -2.00 3.19 -2.00 316.98 0.00e+00 5.616488e-04 9.153311e-05 6.298916e-05 -6.000000e+00 2.463895e-04 276.72 -2.00 20.00 -2.00 316.40 0.00e+00 2.375 0.000 302.00 328.00 3 5.6240e+00 1.7938e-03 2.2357e-02 -6.0000e+00 1.3992e-02 3.5090e-02 2.0116e-03 1.3297e-02 -6.0000e+00 1.5191e-02 1.8848e-03 1.2148e-03 6.6439e-03 -6.0000e+00 9.0334e-03 -4.5038e-03 6.0882e-04 1.9924e-03 -6.0000e+00 3.9249e-03 2.1567e-04 7.2425e-04 3.8161e-05 2.1178e-05 -6.0000e+00 2.6746e-04 -2.3252e-02 0.0000e+00 12 1 1 12 5 1 99.97 20.96 0.22 -0.02325 -0.01781 45 25 1 5 0 491.770 20.96 15.01 14.40 11.94 0.1 899.36 -1455 -2439 -2246 -2730 -2782 -3722 -347 -1603 -829 -2314 -2377 -1943 -55 -823 591 -284 501 1201 906 85 -303 1842 459 1411 454 168 -1219 -167 -49 1482 495 891 -518 -2353 -1846 -2465 -1560 -1156 -74 -1048 -467 -531 -576 384 15 -730 -251 -289 -186 815 812 939 835 907 897 1063 557 375 217 631 1136 1630 1473 628 -22 -78 -19 376 915 -101 382 -102 292 -203 -203 -682 -831 -777 -715 -1200 -1258 -1875 -1952 -974 -793 -203 -113 401 269 390 402 174 607 406 -17 501 769 286 -225 -99 -650 -449 329 -651 -1087 -953 -546 -145 574 550 551 372 175 -82 210 204 -134 163 -120 -268 -79 230 45 428 263 62 666 674 395 213 -118 85 57 -79 58 -219 407 -62 -126 -207 -450 -510 -171 -309 -282 -314 -290 -388 -38 -204 -114 -331 -339 -295 -9 -166 134 -70 128 318 250 22 -81 521 125 406 139 53 -378 -52 -15 441 148 292 -185 -843 -617 -841 -594 -524 -37 -596 -284 -312 -346 229 9 -437 -158 -178 -114 506 501 621 585 664 673 815 433 288 163 475 892 1294 1273 574 -20 -63 -15 290 778 -91 370 -102 284 -188 -183 -553 -663 -611 -573 -1100 -1212 -1985 -2055 -1069 -932 -239 -140 501 330 454 454 190 614 415 -19 584 941 385 -298 -133 -809 -541 383 -815 -1393 -1279 -723 -200 835 814 851 572 256 -116 289 269 -180 220 -174 -389 -115 342 64 585 363 80 832 874 557 305 -177 129 84 -123 92 -360 680 -105 -213 -340 -744 -810 SS 20231106T093733.5Z 8710.401082 305 1 47.99 2 64.16 127.43 25.20 249.24 0.00 1 0.00 1 0 17 1.120e-02 6.336e-03 4.501e-03 1.594e-03 2.812819e-01 8.022098e-04 3.101764e-03 -6.000000e+00 6.354605e-03 224.44 -2.00 3.19 -2.00 316.91 0.00e+00 6.371811e-04 1.050121e-04 6.858938e-05 -6.000000e+00 2.766341e-04 276.72 -2.00 20.00 -2.00 316.33 0.00e+00 2.281 0.000 302.00 328.00 3 6.6852e+00 2.0876e-03 2.1581e-02 -6.0000e+00 1.5709e-02 6.8221e-02 2.3392e-03 1.2934e-02 -6.0000e+00 1.7055e-02 -5.9789e-04 1.4100e-03 6.4553e-03 -6.0000e+00 1.0142e-02 -3.7706e-03 7.0434e-04 1.9421e-03 -6.0000e+00 4.4065e-03 7.9617e-05 6.4028e-04 4.4536e-05 2.0931e-05 -6.0000e+00 3.0030e-04 -2.3075e-02 0.0000e+00 11 1 0 11 4 0 99.92 20.96 0.16 -0.02308 -0.01826 38 10 1 5 0 1262.770 20.96 14.99 14.41 11.98 0.1 899.34 -1368 -1349 -1997 -1232 -5223 -2126 -2995 -373 -3045 -1686 -3769 191 -2083 432 -71 1222 181 1113 1456 1347 -252 1079 1377 68 178 -766 -52 -696 49 301 1580 1381 -64 -2750 -2645 -2479 -1341 -632 -656 -158 -552 -12 -421 519 -230 -226 -723 -648 -261 434 455 826 1248 1057 1105 1156 226 -214 669 533 1328 1500 2018 644 -214 -42 -813 221 554 168 543 251 641 246 -341 -479 -1766 -1323 -1426 -1760 -1640 -1735 -1689 -861 -515 -295 184 487 482 598 538 -130 -226 -380 -49 137 908 303 281 -141 -343 -603 -25 -663 -1216 -606 -507 103 619 1063 726 601 330 -22 -91 -340 -264 -143 16 -249 63 124 172 302 177 -248 605 387 362 152 -217 -196 20 -21 138 153 313 240 -284 -116 -457 -604 -172 -181 -268 -149 -595 -240 -360 -50 -453 -253 -573 30 -382 87 -16 298 46 295 386 369 -71 306 403 21 57 -254 -17 -216 14 89 499 463 -23 -1016 -915 -866 -521 -282 -339 -90 -327 -8 -264 323 -144 -141 -443 -399 -158 268 292 565 874 774 829 861 171 -161 500 400 1009 1236 1749 577 -192 -35 -646 175 472 157 530 251 626 235 -307 -396 -1391 -1021 -1168 -1602 -1625 -1830 -1831 -950 -594 -354 230 617 601 722 610 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