File name: Pandora101s1_Izana_20231226_L2Fit_fwvt1c12d20230620p1-8.txt File generation date: 20240117T092531.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v12d20230620.txt Level 1 file used: Pandora101s1_Izana_20231226_L1_smca1c12d20230620p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20231226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 11 First and last pixel inside fitting window: 1642 1792 Nominal wavelengths inside fitting window [nm]: 492.0279 492.1490 492.2700 492.3910 492.5120 492.6329 492.7539 492.8748 492.9957 493.1166 493.2375 493.3584 493.4792 493.6001 493.7209 493.8417 493.9624 494.0832 494.2040 494.3247 494.4454 494.5661 494.6868 494.8074 494.9281 495.0487 495.1693 495.2899 495.4105 495.5311 495.6516 495.7721 495.8927 496.0132 496.1336 496.2541 496.3745 496.4950 496.6154 496.7358 496.8561 496.9765 497.0969 497.2172 497.3375 497.4578 497.5781 497.6983 497.8186 497.9388 498.0590 498.1792 498.2994 498.4195 498.5397 498.6598 498.7799 498.9000 499.0201 499.1401 499.2601 499.3802 499.5002 499.6202 499.7401 499.8601 499.9800 500.1000 500.2199 500.3397 500.4596 500.5795 500.6993 500.8191 500.9389 501.0587 501.1785 501.2982 501.4180 501.5377 501.6574 501.7771 501.8967 502.0164 502.1360 502.2556 502.3752 502.4948 502.6144 502.7339 502.8534 502.9730 503.0925 503.2119 503.3314 503.4508 503.5703 503.6897 503.8091 503.9285 504.0478 504.1672 504.2865 504.4058 504.5251 504.6444 504.7636 504.8829 505.0021 505.1213 505.2405 505.3596 505.4788 505.5979 505.7171 505.8362 505.9552 506.0743 506.1934 506.3124 506.4314 506.5504 506.6694 506.7884 506.9073 507.0262 507.1452 507.2641 507.3829 507.5018 507.6207 507.7395 507.8583 507.9771 508.0959 508.2146 508.3334 508.4521 508.5708 508.6895 508.8082 508.9268 509.0455 509.1641 509.2827 509.4013 509.5199 509.6384 509.7569 509.8755 509.9940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231226T080149.2Z 8760.334597 248 1 7.36 2 89.68 116.97 95.57 305.23 0.00 1 0.00 1 0 22 5.413e-03 5.357e-03 1.182e-04 1.179e-04 2.074760e+03 6.701912e+00 1.257408e+02 -6.000000e+00 2.950863e+02 273.47 -2.00 20.00 -2.00 505.38 0.00e+00 1.445723e-03 3.210626e-06 8.106208e-05 -6.000000e+00 1.494894e-04 273.47 -2.00 20.00 -2.00 501.05 0.00e+00 1.052793e+00 2.279544e-03 2.809340e-02 -6.000000e+00 1.082230e-01 223.10 -2.00 3.19 -2.00 502.55 0.00e+00 20.481 0.089 489.00 513.00 1 9.0295e-01 1.7397e-04 2.4369e-02 -6.0000e+00 8.2799e-03 -3.8961e-02 4.4435e-05 1.4157e-03 -6.0000e+00 2.1431e-03 7.9531e-02 -9.6077e-04 1.2284e-05 3.4778e-05 -6.0000e+00 5.7288e-04 1.7848e-02 -4.8224e-04 12 9 8 11 4 0 -0.83 21.06 2.27 0.01785 0.01118 988 252 1 4 0 5.920 21.06 15.00 14.55 8.68 0.4 874.99 900000 -1352 -935 -413 108 461 831 1027 927 901 585 175 -72 -336 -462 -537 -425 -165 166 429 394 387 489 486 496 631 506 208 24 -280 -784 -916 -696 -354 64 179 64 37 44 -169 -161 -29 112 307 513 616 611 505 227 -113 -374 -785 -1026 -1076 -866 -405 -74 154 334 484 615 695 721 635 600 504 317 -33 -223 -319 -435 -573 -578 -486 -278 -238 -491 -764 -817 -755 -813 -881 -787 -645 -504 -448 -494 -374 -350 -315 -169 51 246 437 433 430 218 -136 -377 -562 -860 -1004 -820 -537 -291 -285 -308 -263 -228 -186 -82 127 349 650 891 1067 1070 1073 1004 851 625 523 442 396 363 385 408 429 336 190 172 90 -151 -350 -414 -416 -261 -142 -71 134 290 300 336 274 166 32 -81 -208 -487 -734 -810 900000 -1217 -836 -380 100 437 784 984 896 869 560 166 -68 -314 -427 -496 -396 -156 158 415 386 381 483 471 483 618 496 204 23 -272 -747 -863 -661 -344 62 179 63 37 43 -167 -159 -28 112 303 513 620 617 508 226 -110 -367 -756 -972 -1039 -828 -397 -73 154 338 490 622 690 720 638 602 503 312 -32 -221 -313 -424 -557 -564 -480 -277 -234 -481 -755 -798 -733 -791 -862 -776 -628 -496 -445 -495 -377 -353 -318 -168 51 250 449 446 440 219 -135 -375 -549 -832 -974 -810 -535 -293 -292 -316 -267 -230 -188 -83 130 358 675 933 1127 1115 1124 1054 889 660 545 458 410 378 403 429 443 347 197 179 93 -157 -360 -424 -429 -267 -148 -76 142 311 324 358 295 180 34 -88 -225 -517 -771 -853 SQ 20231226T080156.0Z 8760.334676 248 2 5.93 2 89.66 116.98 95.59 305.25 0.00 1 0.00 1 0 22 5.364e-03 5.312e-03 1.167e-04 1.163e-04 2.098845e+03 6.608433e+00 1.268447e+02 -6.000000e+00 2.923909e+02 273.47 -2.00 20.00 -2.00 505.38 0.00e+00 1.432466e-03 3.166379e-06 8.050724e-05 -6.000000e+00 1.481246e-04 273.47 -2.00 20.00 -2.00 501.06 0.00e+00 1.054671e+00 2.248768e-03 2.841065e-02 -6.000000e+00 1.072365e-01 223.10 -2.00 3.19 -2.00 502.56 0.00e+00 20.447 0.088 489.00 513.00 1 8.8281e-01 1.7162e-04 2.4317e-02 -6.0000e+00 8.2044e-03 -3.8280e-02 4.3837e-05 1.4160e-03 -6.0000e+00 2.1236e-03 8.1441e-02 -9.8767e-04 1.2131e-05 3.4735e-05 -6.0000e+00 5.6766e-04 1.9705e-02 -4.9505e-04 12 9 8 11 4 0 -3.90 21.06 2.24 0.01970 0.01285 988 252 1 4 0 5.920 21.06 15.00 14.55 8.68 0.4 874.99 900000 -1351 -900 -400 130 425 802 998 940 899 569 157 -64 -323 -445 -547 -423 -196 141 428 388 386 496 490 519 648 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-382 -551 -814 -970 -809 -528 -274 -254 -320 -300 -253 -208 -98 114 363 663 893 1093 1146 1142 1069 896 659 531 444 374 400 392 426 491 359 223 179 111 -102 -376 -400 -404 -253 -170 -103 125 267 328 362 337 213 41 -92 -222 -556 -832 -857 SQ 20231226T080202.4Z 8760.334750 248 3 6.80 2 89.64 117.00 95.61 305.26 0.00 1 0.00 1 0 22 5.272e-03 5.220e-03 1.154e-04 1.151e-04 2.088188e+03 6.563001e+00 1.272937e+02 -6.000000e+00 2.874126e+02 273.47 -2.00 20.00 -2.00 505.38 0.00e+00 1.426938e-03 3.135199e-06 8.022452e-05 -6.000000e+00 1.456043e-04 273.47 -2.00 20.00 -2.00 501.04 0.00e+00 1.056567e+00 2.229089e-03 2.801493e-02 -6.000000e+00 1.054143e-01 223.10 -2.00 3.19 -2.00 502.55 0.00e+00 20.414 0.088 489.00 513.00 1 8.6473e-01 1.7014e-04 2.4263e-02 -6.0000e+00 8.0649e-03 -3.7627e-02 4.3436e-05 1.4108e-03 -6.0000e+00 2.0876e-03 8.3215e-02 -8.5260e-04 1.2001e-05 3.4589e-05 -6.0000e+00 5.5802e-04 1.4730e-02 -4.6695e-04 12 9 8 11 4 0 -3.47 21.06 2.22 0.01473 0.00882 988 252 1 4 0 5.920 21.06 15.00 14.55 8.68 0.4 874.99 900000 -1315 -893 -395 123 438 782 980 911 881 571 156 -47 -287 -413 -496 -399 -184 162 406 384 397 465 448 517 611 478 215 41 -256 -748 -895 -672 -412 28 159 89 68 39 -120 -144 -28 151 327 508 579 578 491 184 -139 -406 -761 -989 -1049 -839 -417 -59 153 300 512 636 669 670 652 552 462 259 -36 -263 -334 -393 -557 -566 -491 -269 -223 -451 -747 -752 -744 -819 -860 -750 -597 -478 -439 -490 -330 -338 -311 -147 55 250 404 416 423 178 -138 -384 -544 -848 -980 -832 -500 -275 -276 -334 -287 -231 -199 -92 111 338 619 837 1014 1103 1046 992 839 607 516 466 382 379 374 364 434 311 178 205 128 -128 -353 -419 -412 -263 -131 -59 127 313 309 318 282 174 3 -74 -198 -485 -758 -811 900000 -1178 -795 -362 113 414 736 936 878 848 546 148 -44 -273 -390 -468 -370 -174 156 392 375 390 458 444 502 597 468 210 41 -248 -709 -860 -636 -400 28 158 89 68 39 -118 -142 -28 150 321 506 582 582 492 183 -136 -398 -731 -954 -1009 -799 -408 -57 153 302 516 642 678 668 653 552 460 261 -36 -259 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