File name: Pandora101s1_Izana_20240126_L2Fit_fout2c22d20230904p1-8.txt File generation date: 20240911T142140.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt Level 1 file used: Pandora101s1_Izana_20240126_L1_smca1c22d20230904p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20240126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 fieldcal with sens applied First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1209 305.2618 305.4026 305.5434 305.6843 305.8251 305.9659 306.1066 306.2474 306.3882 306.5289 306.6697 306.8104 306.9511 307.0918 307.2325 307.3732 307.5139 307.6545 307.7952 307.9358 308.0764 308.2170 308.3576 308.4982 308.6388 308.7794 308.9199 309.0605 309.2010 309.3415 309.4820 309.6225 309.7630 309.9035 310.0440 310.1844 310.3249 310.4653 310.6057 310.7461 310.8865 311.0269 311.1673 311.3076 311.4480 311.5883 311.7287 311.8690 312.0093 312.1496 312.2898 312.4301 312.5704 312.7106 312.8509 312.9911 313.1313 313.2715 313.4117 313.5519 313.6920 313.8322 313.9723 314.1125 314.2526 314.3927 314.5328 314.6729 314.8129 314.9530 315.0931 315.2331 315.3731 315.5131 315.6531 315.7931 315.9331 316.0731 316.2130 316.3530 316.4929 316.6329 316.7728 316.9127 317.0526 317.1924 317.3323 317.4722 317.6120 317.7518 317.8916 318.0315 318.1712 318.3110 318.4508 318.5906 318.7303 318.8701 319.0098 319.1495 319.2892 319.4289 319.5686 319.7082 319.8479 319.9875 320.1272 320.2668 320.4064 320.5460 320.6856 320.8252 320.9647 321.1043 321.2438 321.3833 321.5229 321.6624 321.8019 321.9413 322.0808 322.2203 322.3597 322.4991 322.6386 322.7780 322.9174 323.0568 323.1961 323.3355 323.4749 323.6142 323.7535 323.8928 324.0321 324.1714 324.3107 324.4500 324.5893 324.7285 324.8677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240126T100646.9Z 8791.421376 9 1 8.98 2 66.05 129.76 106.98 305.56 0.00 1 0.00 1 0 17 9.640e-03 5.849e-03 5.590e-03 2.215e-03 2.809045e-01 1.098906e-03 3.115773e-03 -6.000000e+00 5.375439e-03 223.35 -2.00 3.19 -2.00 316.67 0.00e+00 4.903863e-04 1.327001e-04 6.422190e-05 -6.000000e+00 2.304185e-04 272.59 -2.00 20.00 -2.00 316.17 0.00e+00 2.447 0.000 302.00 328.00 3 5.8128e+00 2.8427e-03 2.2441e-02 -6.0000e+00 1.3280e-02 5.1167e-02 3.1839e-03 1.2837e-02 -6.0000e+00 1.4453e-02 -4.6615e-03 1.9013e-03 6.4275e-03 -6.0000e+00 8.5800e-03 -1.5456e-03 9.4316e-04 1.8981e-03 -6.0000e+00 3.7323e-03 1.7259e-04 -1.6938e-04 6.0031e-05 2.0354e-05 -6.0000e+00 2.4942e-04 3.5734e-03 0.0000e+00 12 1 1 12 1 1 97.54 21.17 0.24 0.00357 0.00230 11 16 1 5 0 747.520 21.17 15.00 14.58 14.41 0.0 915.13 -2381 -1744 -2691 -1719 -3992 -1085 -2239 -153 -1482 -1359 -2073 -1223 -2237 -54 -476 -111 731 876 -53 1525 516 1318 1201 1300 486 444 -350 -800 -758 467 289 1883 -161 -1322 -2626 -2215 -935 215 517 -68 -481 -563 -735 3 63 -687 -657 -341 86 380 695 635 1155 897 911 651 500 68 -40 547 731 1155 1945 835 -87 -76 -458 -87 304 163 418 682 561 97 348 -689 -1460 -1227 -1432 -1330 -1066 -1501 -1726 -1273 -720 -92 105 613 627 504 506 -285 -210 -354 -502 64 666 880 115 -5 -557 -700 -378 -605 -657 -528 -479 40 605 581 836 361 267 1 -225 -33 -117 -48 477 -160 21 120 94 574 241 -116 432 200 229 77 -66 -63 -164 -19 128 -166 408 102 107 -420 -280 -627 -352 -272 -418 -238 -507 -134 -308 -24 -252 -234 -354 -223 -475 -13 -120 -30 203 254 -16 472 161 405 384 444 176 165 -127 -269 -242 150 101 713 -62 -545 -1015 -870 -379 103 276 -42 -293 -356 -475 2 40 -441 -412 -223 55 251 458 449 858 698 680 498 387 52 -30 407 571 980 1676 762 -77 -65 -370 -71 275 157 404 673 542 94 308 -583 -1217 -1008 -1213 -1208 -1080 -1575 -1908 -1396 -845 -108 129 765 771 616 567 -307 -210 -359 -557 74 815 1124 152 -6 -686 -830 -437 -751 -837 -703 -634 55 840 863 1237 556 390 2 -307 -43 -156 -64 687 -231 30 177 134 778 327 -150 561 258 320 110 -98 -91 -243 -30 202 -273 680 166 172 -686 -438 -988 SS 20240126T101108.1Z 8791.424399 12 1 48.38 2 65.32 130.55 107.73 306.22 0.00 1 0.00 1 0 17 1.181e-02 7.491e-03 4.454e-03 1.693e-03 2.764608e-01 8.415254e-04 3.063968e-03 -6.000000e+00 6.584050e-03 223.35 -2.00 3.19 -2.00 316.75 0.00e+00 1.021072e-03 1.038256e-04 6.852821e-05 -6.000000e+00 2.822060e-04 272.59 -2.00 20.00 -2.00 316.25 0.00e+00 2.379 0.000 302.00 328.00 3 6.9658e+00 2.1801e-03 2.1924e-02 -6.0000e+00 1.6266e-02 8.8344e-02 2.4434e-03 1.2671e-02 -6.0000e+00 1.7701e-02 -3.9959e-03 1.4662e-03 6.3427e-03 -6.0000e+00 1.0508e-02 -3.0941e-03 7.3055e-04 1.9845e-03 -6.0000e+00 4.5721e-03 5.6501e-05 -7.7892e-05 4.6065e-05 2.0470e-05 -6.0000e+00 3.0544e-04 2.4166e-03 0.0000e+00 11 8 0 10 0 0 99.56 21.17 0.20 0.00242 0.00183 27 7 1 5 0 1791.650 21.17 14.99 14.58 13.88 0.0 912.09 -437 1339 -436 -2737 -3849 -2639 -2650 -961 -696 -2326 -3016 -3373 -953 -541 2123 -151 686 1762 794 1389 268 1525 -20 1358 -859 850 -779 -5 -1406 865 -1540 802 2 -1294 -4213 -2863 -1533 -1463 665 -282 295 -426 450 355 -291 -947 -524 -512 -268 331 643 893 1154 1210 796 890 530 282 -95 485 628 1791 1979 1382 367 -545 -1147 -464 592 506 691 478 711 8 -47 -1438 -2076 -2382 -1888 -1488 -1105 -1495 -1896 -863 -835 191 552 1023 803 695 279 -281 -998 -681 -756 -49 729 930 872 120 -680 -1267 -693 -857 -700 -482 -208 -37 777 726 999 1043 477 -251 -514 -608 -710 -30 -12 30 265 544 436 541 -55 -259 -274 65 139 122 -52 -195 -24 -278 136 -46 513 377 130 -240 -355 -791 -61 195 -64 -368 -470 -316 -349 -141 -111 -382 -490 -592 -182 -120 521 -39 184 487 230 413 81 447 -6 439 -298 297 -267 -2 -427 271 -521 290 1 -503 -1558 -1063 -615 -679 351 -165 183 -269 287 226 -187 -608 -336 -321 -165 209 421 623 823 901 608 693 417 219 -72 368 500 1495 1745 1250 331 -462 -944 -381 509 479 680 481 698 8 -42 -1198 -1637 -1856 -1607 -1361 -1096 -1583 -2065 -954 -969 234 689 1290 999 836 315 -304 -1032 -709 -817 -57 896 1225 1182 157 -860 -1507 -800 -1037 -892 -640 -282 -52 1105 1082 1515 1597 709 -353 -680 -790 -942 -41 -17 45 390 794 616 742 -74 -337 -342 84 190 171 -75 -289 -36 -425 216 -74 842 630 217 -394 -559 -1224 SS 20240126T101815.4Z 8791.429345 17 1 11.14 2 64.14 131.88 108.96 307.30 0.00 1 0.00 1 0 17 9.327e-03 5.509e-03 6.031e-04 2.826e-04 2.614936e-01 1.408424e-04 2.921271e-03 -6.000000e+00 5.201238e-03 223.35 -2.00 3.19 -2.00 316.28 0.00e+00 4.717593e-04 1.544516e-05 4.171965e-05 -6.000000e+00 2.229417e-04 272.59 -2.00 20.00 -2.00 315.78 0.00e+00 2.279 0.000 302.00 328.00 3 2.1879e+00 3.6287e-04 2.0914e-02 -6.0000e+00 1.2850e-02 3.0478e-02 4.0573e-04 1.1971e-02 -6.0000e+00 1.3984e-02 -6.2926e-03 2.3826e-04 5.9892e-03 -6.0000e+00 8.3017e-03 1.5565e-04 1.1526e-04 1.7699e-03 -6.0000e+00 3.6116e-03 7.6486e-03 -1.6078e-04 7.6607e-06 1.9654e-05 -6.0000e+00 2.4131e-04 2.8685e-03 0.0000e+00 12 1 1 12 1 1 99.24 21.17 0.28 0.00287 0.00166 655 740 1 5 0 16.450 21.17 15.00 14.59 13.41 0.0 907.72 -675 -1128 -2318 -3777 -3623 -2790 -989 -250 -679 -2210 -2308 -1415 -674 97 256 296 569 1106 1203 1291 649 1375 1157 990 525 333 -453 -641 -328 500 979 1538 275 -1766 -1969 -2047 -1211 -369 -76 -528 -400 -534 -518 -217 -74 -374 -243 -482 -392 586 765 999 937 856 782 905 433 460 299 777 918 1390 1416 704 -94 -245 -536 156 709 239 269 -55 297 -41 -88 -472 -824 -841 -755 -1165 -1211 -1761 -1807 -1251 -920 -344 -20 342 363 429 256 82 157 264 38 190 611 449 46 -229 -500 -395 79 -410 -712 -672 -526 -257 421 446 599 366 250 24 151 253 91 206 175 -93 -97 176 185 439 250 146 559 601 211 161 -166 -154 -86 -167 38 -80 255 67 -112 -266 -379 -515 -127 -207 -462 -684 -587 -446 -171 -49 -146 -486 -498 -297 -161 27 79 90 179 360 406 450 227 473 414 378 212 138 -182 -239 -115 177 373 636 124 -793 -819 -868 -535 -193 -45 -330 -266 -368 -364 -152 -52 -260 -165 -319 -255 387 540 709 701 669 625 738 359 374 238 619 767 1189 1313 651 -84 -210 -457 133 634 230 262 -55 305 -40 -83 -398 -675 -678 -665 -1108 -1220 -1847 -1992 -1374 -1084 -411 -25 432 452 504 289 88 165 279 41 219 746 577 61 -292 -614 -465 90 -507 -910 -859 -702 -358 591 641 896 543 365 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