File name: Pandora101s1_Izana_20240323_L2Fit_fout2c12d20230620p1-8.txt File generation date: 20240327T085854.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v12d20230620.txt Level 1 file used: Pandora101s1_Izana_20240323_L1_smca1c12d20230620p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20240323 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 11 First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1333 305.2742 305.4151 305.5559 305.6968 305.8376 305.9784 306.1192 306.2600 306.4008 306.5416 306.6823 306.8231 306.9638 307.1045 307.2452 307.3859 307.5266 307.6673 307.8080 307.9486 308.0893 308.2299 308.3706 308.5112 308.6518 308.7924 308.9329 309.0735 309.2141 309.3546 309.4951 309.6357 309.7762 309.9167 310.0572 310.1976 310.3381 310.4786 310.6190 310.7594 310.8998 311.0403 311.1807 311.3210 311.4614 311.6018 311.7421 311.8825 312.0228 312.1631 312.3034 312.4437 312.5840 312.7243 312.8645 313.0048 313.1450 313.2852 313.4254 313.5656 313.7058 313.8460 313.9862 314.1263 314.2665 314.4066 314.5467 314.6869 314.8270 314.9670 315.1071 315.2472 315.3872 315.5273 315.6673 315.8073 315.9473 316.0873 316.2273 316.3673 316.5073 316.6472 316.7871 316.9271 317.0670 317.2069 317.3468 317.4867 317.6265 317.7664 317.9062 318.0461 318.1859 318.3257 318.4655 318.6053 318.7451 318.8848 319.0246 319.1643 319.3041 319.4438 319.5835 319.7232 319.8629 320.0025 320.1422 320.2819 320.4215 320.5611 320.7007 320.8403 320.9799 321.1195 321.2591 321.3986 321.5382 321.6777 321.8172 321.9568 322.0962 322.2357 322.3752 322.5147 322.6541 322.7936 322.9330 323.0724 323.2118 323.3512 323.4906 323.6300 323.7693 323.9087 324.0480 324.1873 324.3266 324.4659 324.6052 324.7445 324.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240323T071900.4Z 8848.304866 214 1 48.50 2 87.97 89.67 103.55 288.75 0.00 1 0.00 1 0 33 1.274e-01 5.178e-02 2.683e-02 1.075e-02 9.757862e-01 5.817229e-03 1.064507e-02 -6.000000e+00 7.276630e-02 226.28 -2.00 3.19 -2.00 318.71 0.00e+00 -1.418377e-02 8.044338e-04 3.442477e-03 -6.000000e+00 3.116945e-03 274.35 -2.00 20.00 -2.00 317.96 0.00e+00 16.281 0.045 302.00 328.00 3 -3.0731e+00 1.5302e-02 1.3582e-01 -6.0000e+00 1.8078e-01 3.0456e+00 1.7586e-02 5.8741e-02 -6.0000e+00 1.9613e-01 -2.0231e+00 9.8737e-03 2.1664e-02 -6.0000e+00 1.1631e-01 5.7366e-01 4.7535e-03 1.4932e-02 -6.0000e+00 5.0205e-02 1.1455e-05 4.1135e-03 2.4458e-04 1.6438e-04 -6.0000e+00 3.4186e-03 -1.9837e-02 0.0000e+00 12 9 8 11 20 0 -18.34 21.06 1.73 -0.01984 0.01107 26 7 1 5 0 1865.050 21.06 15.00 14.58 3.72 0.6 830.64 31744 18343 11128 -17797 -27947 -32150 -24918 -17757 -11680 -8294 -10109 2030 4162 19291 19733 27409 25055 27327 11067 16875 -4802 -839 -1779 10878 14947 7141 -8104 -29453 -29326 -29612 -9292 -8408 -2765 -14483 -19684 -22853 -9309 -2965 10053 27836 19986 24257 12213 4144 -5029 -2385 -11825 -10235 -13459 -2229 3620 11962 10442 13223 14597 17240 16313 1612 -1264 -14427 -11832 -13224 -3023 -2999 -3611 -5745 -905 3836 8310 12501 10831 8051 -804 -4949 -22767 -26744 -33821 -22008 -15678 -2679 -1530 7007 5790 9415 5631 7576 6090 3153 -1758 -7428 -7575 -12957 -9968 -6508 513 2670 8053 5847 6610 -323 -3584 -9010 -7639 -4661 -4530 -4466 -1305 3810 4576 8458 7755 5855 1954 -47 -3982 -2309 -2825 -231 333 1361 1686 2851 2211 480 29 -3540 1047 -242 2341 -237 -828 -3214 -2861 -3164 -2363 -1072 344 1732 961 1846 614 3503 7679 4773 2682 -4585 -6736 -7945 -6245 -4512 -2897 -1970 -2454 471 1054 5090 5621 7468 6969 7263 3268 4340 -1386 -223 -510 3005 4072 1986 -2277 -8670 -7962 -8604 -2514 -2491 -801 -4346 -5550 -6531 -2572 -912 3199 8220 6588 7464 3956 1323 -1619 -704 -3729 -3198 -4500 -716 1200 3920 3681 4749 5326 6208 6308 659 -472 -5639 -4526 -5585 -1283 -1361 -1627 -2558 -391 1705 3980 6262 5664 4185 -416 -2318 -10855 -11771 -15665 -9870 -7755 -1370 -890 4164 3689 6009 3865 5224 4289 2227 -1231 -5052 -4763 -8255 -6351 -4501 386 2294 7544 6243 7211 -356 -3601 -8290 -6492 -3996 -4092 -4188 -1258 3837 5255 10742 10987 8829 3055 -72 -6079 -3412 -4319 -359 531 2099 2426 3795 2854 609 36 -4329 1250 -335 3736 -442 -1709 -7284 -6953 -7556 -5946 -2722 866 4280 2528 4436 1360 7023 SS 20240323T074342.1Z 8848.322015 224 1 1.97 2 82.54 92.60 108.53 292.02 0.00 1 0.00 1 0 17 7.055e-01 1.904e-02 2.774e-01 5.783e-03 1.072437e+00 3.278082e-03 1.100932e-02 -6.000000e+00 4.054155e-01 226.28 -2.00 3.19 -2.00 321.82 0.00e+00 1.266752e-02 1.673543e-03 3.451963e-03 -6.000000e+00 1.783637e-02 274.35 -2.00 20.00 -2.00 321.44 0.00e+00 7.162 0.004 302.00 328.00 3 1.1402e+00 1.1420e-02 7.5871e-02 -6.0000e+00 1.0090e+00 7.7584e-01 1.7688e-02 5.4965e-02 -6.0000e+00 1.0953e+00 -1.0125e+00 1.9783e-02 3.5800e-02 -6.0000e+00 6.4727e-01 4.1628e-01 9.1085e-03 2.0484e-02 -6.0000e+00 2.8130e-01 2.0879e-04 -6.6946e-05 1.3252e-04 2.6951e-04 -6.0000e+00 1.9455e-02 -2.4767e-02 0.0000e+00 12 9 9 12 5 1 -20.52 21.06 0.29 -0.02477 -0.02527 30 192 1 5 0 63.430 21.06 15.00 14.60 4.38 0.5 832.94 -242428 900000 -265156 900000 -289204 -31149 -266563 900000 -242189 -140543 -262627 -164665 -194842 -154278 -89764 -121736 39301 -104113 -34480 -80395 51265 -137496 48699 -96798 43658 -75649 -27327 -99752 -53470 -2251 -17977 41704 -19043 83072 -37113 55115 -32277 38098 -5678 61685 3051 35834 10882 34908 14629 11136 35061 30222 40040 15734 51446 16175 35470 19176 39643 15167 32119 12459 21443 2881 14855 15985 15402 21139 21239 22217 9739 21590 9294 14067 8879 15549 6276 8076 -905 1556 -5151 -4481 -220 -593 5076 711 702 -1242 1001 -1846 1709 -711 1732 338 1372 -2557 -3402 -3596 -4893 -2115 -2262 -51 -1274 12 -2376 -69 -2362 -2199 -4151 -1459 -1718 -1379 -500 -523 -17 -410 415 -1055 630 -316 677 95 957 -462 1182 1879 2020 1276 768 760 953 967 169 1094 196 478 -299 223 -379 113 56 208 -468 -235 -467 -1243 -3478 900000 -5570 900000 -6223 -176 -4370 900000 -3350 -792 -4978 -1518 -3494 -2608 -1058 -2432 221 -2240 -427 -1442 289 -4015 274 -1984 246 -1407 -308 -2305 -844 -27 -334 541 -526 843 -1171 683 -1055 730 -202 1286 126 1131 460 1180 618 508 1344 1328 1760 993 2609 1202 2399 1650 2904 1453 2583 1168 1736 275 1332 1638 1894 2848 3058 3221 1671 3595 2014 3308 2347 3855 1604 1816 -195 295 -1048 -1021 -59 -199 1924 298 321 -611 507 -1007 931 -399 925 173 649 -1218 -1686 -2028 -3382 -1730 -2047 -53 -1437 13 -2396 -59 -2003 -1889 -3577 -1286 -1625 -1441 -604 -693 -26 -623 639 -1620 983 -491 1073 149 1545 -748 1890 2771 2849 1762 1034 988 1245 1435 284 2136 406 1072 -686 549 -997 304 153 559 -1227 -570 -1088 -2660 SS 20240323T080122.3Z 8848.334286 229 1 47.84 2 78.65 94.73 112.03 294.53 0.00 1 0.00 1 0 17 5.126e-01 8.454e-03 9.125e-03 2.874e-04 7.771196e-01 1.520335e-04 7.963529e-03 -6.000000e+00 2.929698e-01 226.28 -2.00 3.19 -2.00 320.62 0.00e+00 4.331648e-03 5.956602e-05 1.107254e-03 -6.000000e+00 1.253995e-02 274.35 -2.00 20.00 -2.00 320.18 0.00e+00 4.921 0.001 302.00 328.00 3 6.3253e-01 4.5574e-04 5.2460e-02 -6.0000e+00 7.2786e-01 1.5171e-01 6.1254e-04 3.7209e-02 -6.0000e+00 7.8943e-01 -1.5475e-01 6.5891e-04 2.2163e-02 -6.0000e+00 4.6813e-01 5.4722e-02 3.2854e-04 1.0122e-02 -6.0000e+00 2.0227e-01 2.5778e-03 5.2254e-04 7.0865e-06 9.2258e-05 -6.0000e+00 1.3747e-02 -2.6349e-02 0.0000e+00 11 9 0 11 4 0 93.81 21.06 0.26 -0.02635 -0.02242 3703 943 1 5 0 12.910 21.06 15.00 14.60 5.04 0.5 839.19 -175552 -169982 -165356 -172757 -179245 -178224 -172790 -155491 -153383 -146896 -141176 -122692 -103306 -76353 -65349 -48939 -45875 -36422 -36112 -33111 -35398 -34359 -33896 -31784 -30771 -29504 -29622 -33859 -30026 -22694 -13567 -7671 -5185 -7575 -8979 -10386 -6644 -3560 -572 583 1147 1796 1825 2748 3006 2609 2897 2994 3404 4681 4747 5341 5340 4568 4120 3335 1944 1253 1210 1572 2625 3347 3998 2868 2411 2336 1602 1731 1847 1204 1113 441 320 -359 -861 -1263 -2047 -1681 -1285 -1125 -1029 -1713 -1944 -1354 -1088 -391 -50 238 447 605 474 32 -157 -189 -450 -148 435 93 -266 -315 -504 -93 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