File name: Pandora101s1_Izana_20240421_L2Fit_fwvt1c12d20230620p1-8.txt File generation date: 20240422T011918.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v12d20230620.txt Level 1 file used: Pandora101s1_Izana_20240421_L1_smca1c12d20230620p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20240421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 11 First and last pixel inside fitting window: 1642 1792 Nominal wavelengths inside fitting window [nm]: 492.0279 492.1490 492.2700 492.3910 492.5120 492.6329 492.7539 492.8748 492.9957 493.1166 493.2375 493.3584 493.4792 493.6001 493.7209 493.8417 493.9624 494.0832 494.2040 494.3247 494.4454 494.5661 494.6868 494.8074 494.9281 495.0487 495.1693 495.2899 495.4105 495.5311 495.6516 495.7721 495.8927 496.0132 496.1336 496.2541 496.3745 496.4950 496.6154 496.7358 496.8561 496.9765 497.0969 497.2172 497.3375 497.4578 497.5781 497.6983 497.8186 497.9388 498.0590 498.1792 498.2994 498.4195 498.5397 498.6598 498.7799 498.9000 499.0201 499.1401 499.2601 499.3802 499.5002 499.6202 499.7401 499.8601 499.9800 500.1000 500.2199 500.3397 500.4596 500.5795 500.6993 500.8191 500.9389 501.0587 501.1785 501.2982 501.4180 501.5377 501.6574 501.7771 501.8967 502.0164 502.1360 502.2556 502.3752 502.4948 502.6144 502.7339 502.8534 502.9730 503.0925 503.2119 503.3314 503.4508 503.5703 503.6897 503.8091 503.9285 504.0478 504.1672 504.2865 504.4058 504.5251 504.6444 504.7636 504.8829 505.0021 505.1213 505.2405 505.3596 505.4788 505.5979 505.7171 505.8362 505.9552 506.0743 506.1934 506.3124 506.4314 506.5504 506.6694 506.7884 506.9073 507.0262 507.1452 507.2641 507.3829 507.5018 507.6207 507.7395 507.8583 507.9771 508.0959 508.2146 508.3334 508.4521 508.5708 508.6895 508.8082 508.9268 509.0455 509.1641 509.2827 509.4013 509.5199 509.6384 509.7569 509.8755 509.9940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240421T063948.8Z 8877.277649 165 1 5.88 2 89.67 76.47 109.15 280.83 0.00 1 0.00 1 0 15 5.904e-03 5.849e-03 1.523e-04 1.519e-04 3.300293e+03 9.042298e+00 2.069385e+02 -6.000000e+00 3.259858e+02 276.44 -2.00 20.00 -2.00 505.39 0.00e+00 1.747343e-03 4.176147e-06 9.886541e-05 -6.000000e+00 1.641462e-04 276.44 -2.00 20.00 -2.00 501.05 0.00e+00 1.422119e+00 2.958211e-03 3.870597e-02 -6.000000e+00 1.185872e-01 228.15 -2.00 3.19 -2.00 502.55 0.00e+00 20.408 0.088 489.00 513.00 1 1.3341e+00 2.2597e-04 2.4449e-02 -6.0000e+00 9.0769e-03 -4.6868e-02 5.7542e-05 1.5239e-03 -6.0000e+00 2.3500e-03 5.0039e-02 -1.2272e-03 1.5735e-05 4.4756e-05 -6.0000e+00 6.2508e-04 2.0351e-02 -4.9478e-04 12 9 8 11 4 0 5.59 20.87 2.71 0.02035 0.01184 604 154 1 4 0 9.690 20.87 15.00 14.42 11.12 2.1 680.34 900000 -1472 -981 -429 112 430 817 1037 986 935 622 178 -73 -386 -503 -599 -439 -216 163 484 440 403 523 540 561 666 540 243 54 -282 -831 -1011 -759 -407 52 210 127 67 56 -126 -154 -17 155 338 568 679 674 555 264 -124 -405 -870 -1095 -1174 -899 -410 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471 540 389 262 240 111 -142 -415 -471 -457 -317 -199 -73 139 295 321 340 337 244 76 -90 -278 -579 -889 -932 SQ 20240421T063954.8Z 8877.277718 165 2 5.86 2 89.65 76.48 109.17 280.84 0.00 1 0.00 1 0 15 5.814e-03 5.761e-03 1.506e-04 1.502e-04 3.276944e+03 8.939812e+00 2.061089e+02 -6.000000e+00 3.209763e+02 276.44 -2.00 20.00 -2.00 505.39 0.00e+00 1.721536e-03 4.121399e-06 9.717885e-05 -6.000000e+00 1.616306e-04 276.44 -2.00 20.00 -2.00 501.04 0.00e+00 1.413317e+00 2.924610e-03 3.821564e-02 -6.000000e+00 1.167806e-01 228.15 -2.00 3.19 -2.00 502.54 0.00e+00 20.375 0.087 489.00 513.00 1 1.3166e+00 2.2338e-04 2.4389e-02 -6.0000e+00 8.9384e-03 -4.5964e-02 5.6853e-05 1.5178e-03 -6.0000e+00 2.3146e-03 5.1158e-02 -1.0128e-03 1.5549e-05 4.4733e-05 -6.0000e+00 6.1553e-04 2.1045e-02 -5.0852e-04 12 9 8 11 4 0 26.36 20.87 2.67 0.02105 0.01402 604 154 1 4 0 9.690 20.87 15.00 14.42 11.12 2.1 680.67 900000 -1436 -986 -450 112 454 862 1054 981 929 614 130 -98 -362 -490 -590 -443 -182 174 482 413 394 490 501 549 697 551 259 64 -278 -801 -972 -736 -408 19 177 137 112 50 -143 -137 10 141 317 579 646 657 552 246 -116 -421 -854 -1090 -1151 -904 -396 -43 202 385 570 692 726 741 711 638 526 287 -45 -264 -356 -448 -601 -611 -539 -316 -293 -496 -797 -860 -869 -915 -941 -835 -662 -536 -497 -539 -383 -322 -338 -142 44 254 456 496 488 266 -98 -437 -626 -933 -1094 -904 -586 -290 -260 -337 -326 -265 -247 -117 95 372 701 982 1169 1203 1175 1079 920 665 543 477 411 397 401 423 496 354 225 196 116 -131 -406 -435 -452 -282 -166 -70 135 310 300 291 302 211 77 -72 -223 -554 -812 -879 900000 -1277 -894 -409 105 425 822 997 937 886 582 125 -93 -342 -459 -553 -419 -170 167 472 399 383 478 491 541 691 547 257 63 -268 -773 -928 -708 -393 18 175 137 111 49 -140 -134 10 140 316 586 644 657 550 249 -115 -410 -835 -1047 -1102 -877 -384 -43 201 385 571 692 729 749 722 648 530 287 -44 -258 -353 -440 -590 -602 -526 -312 -291 -490 -778 -848 -852 -898 -928 -811 -649 -531 -497 -532 -379 -319 -336 -141 44 259 459 500 498 267 -96 -432 -609 -899 -1057 -889 -582 -291 -266 -346 -333 -268 -249 -119 98 381 727 1028 1231 1250 1230 1134 962 689 568 494 426 414 413 437 513 367 234 203 120 -134 -420 -448 -468 -290 -174 -73 143 334 320 312 327 230 84 -78 -238 -593 -861 -933 SQ 20240421T064000.7Z 8877.277786 165 3 5.89 2 89.63 76.49 109.19 280.85 0.00 1 0.00 1 0 15 5.783e-03 5.733e-03 1.486e-04 1.482e-04 3.209187e+03 8.799633e+00 2.020708e+02 -6.000000e+00 3.192857e+02 276.44 -2.00 20.00 -2.00 505.39 0.00e+00 1.727273e-03 4.071351e-06 9.766410e-05 -6.000000e+00 1.607787e-04 276.44 -2.00 20.00 -2.00 501.03 0.00e+00 1.420229e+00 2.888676e-03 3.764629e-02 -6.000000e+00 1.161639e-01 228.15 -2.00 3.19 -2.00 502.54 0.00e+00 20.341 0.087 489.00 513.00 1 1.2956e+00 2.2060e-04 2.4333e-02 -6.0000e+00 8.8912e-03 -4.5242e-02 5.6239e-05 1.5081e-03 -6.0000e+00 2.3023e-03 5.2401e-02 -9.9580e-04 1.5360e-05 4.4347e-05 -6.0000e+00 6.1229e-04 1.9108e-02 -4.9562e-04 12 9 8 11 4 0 12.54 20.87 2.64 0.01911 0.01220 604 154 1 4 0 9.690 20.87 15.00 14.42 11.12 2.1 680.67 900000 -1425 -986 -411 109 446 827 1072 998 949 612 157 -72 -392 -501 -598 -471 -160 196 459 416 412 487 476 538 679 566 246 41 -267 -824 -974 -707 -415 26 217 102 88 56 -132 -136 -12 159 353 555 609 673 544 245 -127 -403 -850 -1054 -1133 -930 -414 -66 175 367 534 653 711 745 726 635 525 288 -43 -280 -368 -460 -602 -612 -514 -334 -280 -491 -803 -863 -827 -909 -916 -803 -666 -513 -513 -531 -378 -359 -310 -162 75 232 442 512 489 241 -132 -407 -603 -934 -1069 -889 -565 -323 -247 -335 -342 -295 -253 -149 65 383 697 977 1166 1198 1199 1083 917 653 564 509 417 397 414 414 438 344 234 206 97 -161 -392 -447 -435 -279 -150 -72 128 298 306 303 298 208 55 -75 -215 -534 -811 -891 900000 -1283 -882 -378 101 422 780 1026 964 915 587 149 -68 -366 -475 -566 -439 -152 190 444 407 406 480 472 524 665 555 241 40 -260 -786 -919 -672 -404 25 217 101 88 56 -130 -134 -12 159 349 554 614 680 547 244 -125 -397 -820 -1024 -1096 -891 -406 -65 175 372 541 661 707 745 729 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