File name: Pandora101s1_Izana_20240703_L2Fit_fout2c22d20230904p1-8.txt File generation date: 20240704T011659.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt Level 1 file used: Pandora101s1_Izana_20240703_L1_smca1c22d20230904p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20240703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 fieldcal with sens applied First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1209 305.2618 305.4026 305.5434 305.6843 305.8251 305.9659 306.1066 306.2474 306.3882 306.5289 306.6697 306.8104 306.9511 307.0918 307.2325 307.3732 307.5139 307.6545 307.7952 307.9358 308.0764 308.2170 308.3576 308.4982 308.6388 308.7794 308.9199 309.0605 309.2010 309.3415 309.4820 309.6225 309.7630 309.9035 310.0440 310.1844 310.3249 310.4653 310.6057 310.7461 310.8865 311.0269 311.1673 311.3076 311.4480 311.5883 311.7287 311.8690 312.0093 312.1496 312.2898 312.4301 312.5704 312.7106 312.8509 312.9911 313.1313 313.2715 313.4117 313.5519 313.6920 313.8322 313.9723 314.1125 314.2526 314.3927 314.5328 314.6729 314.8129 314.9530 315.0931 315.2331 315.3731 315.5131 315.6531 315.7931 315.9331 316.0731 316.2130 316.3530 316.4929 316.6329 316.7728 316.9127 317.0526 317.1924 317.3323 317.4722 317.6120 317.7518 317.8916 318.0315 318.1712 318.3110 318.4508 318.5906 318.7303 318.8701 319.0098 319.1495 319.2892 319.4289 319.5686 319.7082 319.8479 319.9875 320.1272 320.2668 320.4064 320.5460 320.6856 320.8252 320.9647 321.1043 321.2438 321.3833 321.5229 321.6624 321.8019 321.9413 322.0808 322.2203 322.3597 322.4991 322.6386 322.7780 322.9174 323.0568 323.1961 323.3355 323.4749 323.6142 323.7535 323.8928 324.0321 324.1714 324.3107 324.4500 324.5893 324.7285 324.8677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240703T064429.4Z 8950.280896 125 1 47.59 2 84.65 66.82 53.38 77.75 0.00 1 0.00 1 0 25 3.544e-01 2.592e-02 1.937e-01 7.620e-03 9.695696e-01 4.268631e-03 9.815354e-03 -6.000000e+00 2.015762e-01 228.40 -2.00 3.19 -2.00 321.87 0.00e+00 -9.031018e-03 2.137391e-03 4.444515e-03 -6.000000e+00 8.792978e-03 281.50 -2.00 20.00 -2.00 321.40 0.00e+00 9.386 0.008 302.00 328.00 3 3.0383e+00 1.5261e-02 9.1300e-02 -6.0000e+00 5.0225e-01 1.1439e+00 2.0479e-02 6.7664e-02 -6.0000e+00 5.4377e-01 -1.4509e+00 1.8060e-02 2.7050e-02 -6.0000e+00 3.2323e-01 5.8222e-01 8.5868e-03 1.1800e-02 -6.0000e+00 1.4015e-01 7.0464e-06 -1.3435e-03 1.8340e-04 1.0471e-04 -6.0000e+00 9.1841e-03 2.6060e-03 0.0000e+00 12 8 8 10 0 0 39.41 20.96 0.19 0.00261 -0.00749 44 11 1 5 0 1081.570 20.96 15.00 14.50 27.27 1.4 789.59 -91950 14719 -29262 130130 -134403 -67191 -60405 -63747 -23028 -43088 -29764 -82147 -1572 -70605 44128 -32022 92950 -3979 49117 -15850 -8098 -6783 2105 31154 -128100 51609 -27766 6285 -24280 103010 -6629 27971 5206 41841 -29347 45001 7828 24664 58833 53681 54350 56843 67224 64725 42459 -940 27404 12866 62328 17085 28250 32467 37338 43679 43387 47796 37312 33738 22948 27755 -1569 27325 12525 21094 10301 27167 10369 10627 15248 14584 12407 14011 11123 8732 12435 -4653 3788 -4110 2677 -6271 -422 -1381 52 -1068 2141 705 1431 2752 -258 2182 -1836 -677 -5211 -1523 -5294 -2815 -3744 -2392 -3703 -1730 -3963 -3657 -1502 -2640 -5195 -1799 -1436 -2761 -1662 -1172 975 -37 1585 -933 1209 -660 -133 -68 510 707 1841 2890 1518 2702 943 1946 576 499 970 403 180 191 -461 432 341 -72 807 187 -13 -877 -1439 -1495 -3097 187 -544 967 -4793 -1284 -1186 -1455 -379 -892 -553 -2921 -30 -3008 749 -1292 1135 -133 964 -580 -258 -205 63 777 -15672 1123 -1238 177 -876 1236 -267 935 243 1332 -1729 1337 349 1126 2342 2621 2855 2986 3139 2954 2321 -78 1716 970 3043 1442 2414 2964 3547 4219 4444 4895 4277 3814 2655 2872 -221 3219 1974 3437 1930 4239 1970 2182 3447 3532 3282 3671 2832 2197 2633 -1042 764 -977 710 -2063 -155 -589 24 -524 1079 378 789 1504 -141 1096 -896 -315 -2591 -817 -3503 -2164 -3204 -2328 -3913 -1751 -3721 -3185 -1178 -2170 -4421 -1555 -1320 -2830 -1941 -1592 1383 -57 2429 -1435 1749 -955 -197 -106 832 1150 2811 4358 2240 3830 1321 2601 778 760 1646 795 375 427 -1115 1118 897 -196 2200 513 -34 -2322 -3494 -3340 SS 20240703T065518.1Z 8950.288404 128 1 47.84 2 82.45 68.00 51.12 78.58 0.00 1 0.00 1 0 17 6.456e-01 1.116e-02 5.841e-02 1.635e-03 8.064871e-01 8.859848e-04 8.406610e-03 -6.000000e+00 3.672142e-01 228.40 -2.00 3.19 -2.00 321.27 0.00e+00 3.613841e-03 4.291703e-04 2.779380e-03 -6.000000e+00 1.601784e-02 281.50 -2.00 20.00 -2.00 320.76 0.00e+00 7.087 0.004 302.00 328.00 3 2.4267e+00 2.9927e-03 6.7333e-02 -6.0000e+00 9.1496e-01 2.2568e-01 4.2974e-03 4.2194e-02 -6.0000e+00 9.9058e-01 -2.9487e-01 4.5545e-03 2.3952e-02 -6.0000e+00 5.8882e-01 1.1880e-01 2.1520e-03 8.3419e-03 -6.0000e+00 2.5532e-01 9.0705e-05 -6.0950e-04 4.1029e-05 1.0429e-04 -6.0000e+00 1.6729e-02 2.0797e-03 0.0000e+00 12 8 8 10 0 0 37.58 20.96 0.27 0.00208 -0.00250 295 75 1 5 0 162.140 20.96 15.00 14.50 27.38 1.4 790.74 -195320 -192670 -201265 -201892 -238035 -212051 -226603 -176820 -200463 -155788 -212258 -132440 -148371 -91749 -111069 -50027 -77119 -54191 -60343 -58408 -66644 -62758 -47170 -58686 -66503 -51725 -41255 -61368 -39395 -42462 -19097 -25364 -12951 -14456 -18524 -20282 -14038 -4127 395 6845 3382 10188 2270 9246 1543 4634 2895 7696 3751 7563 7194 8847 11048 8791 8710 7232 8801 3307 5390 2128 5711 5066 8600 6441 5255 4285 3517 3808 4320 4245 3360 3268 1578 1509 -987 -509 -3189 -1781 -1998 -507 -1262 -1234 -1979 -1451 -923 -546 209 393 641 191 349 -1415 -1266 -2024 -1177 -696 121 386 -473 -672 -1041 -988 -833 -1419 -2040 -1335 -995 -369 61 335 513 611 444 89 63 65 81 -116 208 -14 523 805 833 558 589 92 676 494 395 181 -34 -46 -82 -331 -195 3 248 146 -109 -44 -429 -503 -1588 -1751 -2085 -1963 -3074 -2163 -2998 -1635 -2620 -1391 -3620 -1267 -2247 -1053 -1983 -582 -1340 -838 -1068 -1061 -1317 -1201 -835 -1291 -1707 -1196 -855 -1516 -810 -1063 -481 -833 -436 -505 -638 -731 -546 -179 20 388 221 664 168 647 119 358 238 642 350 756 752 1026 1385 1228 1287 1135 1384 536 823 332 915 934 1785 1544 1317 1067 902 1048 1368 1545 1328 1315 619 544 -325 -151 -950 -568 -761 -231 -623 -695 -1215 -939 -634 -396 157 298 476 135 228 -898 -803 -1421 -960 -617 124 453 -552 -822 -1161 -968 -759 -1360 -2117 -1444 -1141 -458 79 497 787 981 711 137 99 100 129 -182 343 -23 833 1296 1294 840 857 128 934 758 661 344 -67 -97 -182 -743 -467 8 620 367 -270 -103 -982 -1074 SS 20240703T071321.6Z 8950.300945 133 1 47.86 2 78.74 69.91 47.31 79.97 0.00 1 0.00 1 0 17 2.251e-01 6.208e-03 8.566e-03 3.731e-04 5.983975e-01 1.941442e-04 6.314687e-03 -6.000000e+00 1.280400e-01 228.40 -2.00 3.19 -2.00 320.05 0.00e+00 1.506315e-03 6.497234e-05 7.274270e-04 -6.000000e+00 5.584963e-03 281.50 -2.00 20.00 -2.00 319.46 0.00e+00 4.955 0.001 302.00 328.00 3 1.5305e+00 5.6679e-04 4.7278e-02 -6.0000e+00 3.1903e-01 4.2676e-02 6.9939e-04 2.8715e-02 -6.0000e+00 3.4538e-01 -4.5646e-02 6.4547e-04 1.4852e-02 -6.0000e+00 2.0530e-01 1.3016e-02 3.3346e-04 4.7754e-03 -6.0000e+00 8.9031e-02 1.3045e-03 -2.3741e-04 9.8420e-06 5.0101e-05 -6.0000e+00 5.8323e-03 1.5101e-03 0.0000e+00 10 0 0 10 0 0 55.57 20.96 0.25 0.00151 -0.00027 1836 468 1 5 0 26.050 20.96 15.00 14.51 27.93 1.4 794.97 -81229 -74980 -73624 -80505 -82935 -86629 -77488 -70890 -59696 -64676 -58148 -52057 -38460 -32511 -20657 -18074 -12811 -11971 -9886 -9204 -10662 -9274 -10009 -7455 -10750 -8130 -10862 -11075 -12228 -8654 -5334 -1084 -1539 -4300 -6523 -6541 -3771 -1298 731 901 1293 1020 1760 1408 1797 963 1310 961 911 1839 2282 2390 2354 2203 1669 1696 690 611 55 668 963 2196 2453 2145 1069 526 -31 323 1151 783 914 394 349 -220 -446 -1350 -1857 -1903 -1275 -1245 -1109 -1591 -1859 -1322 -769 -86 177 607 692 757 419 54 -261 -100 -203 -37 512 476 93 -332 -656 -769 -307 -744 -1000 -930 -574 -238 446 453 583 408 392 95 192 232 72 62 -80 -242 -80 332 253 352 77 63 423 583 150 116 -158 -150 -184 -283 -125 -126 287 138 8 -137 -154 -230 -996 -974 -978 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