File name: Pandora101s1_Izana_20250715_L2Fit_fout2c22d20230904p1-8.txt File generation date: 20250716T012755.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt Level 1 file used: Pandora101s1_Izana_20250715_L1_smca1c22d20230904p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20250715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 fieldcal with sens applied First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1209 305.2618 305.4026 305.5434 305.6843 305.8251 305.9659 306.1066 306.2474 306.3882 306.5289 306.6697 306.8104 306.9511 307.0918 307.2325 307.3732 307.5139 307.6545 307.7952 307.9358 308.0764 308.2170 308.3576 308.4982 308.6388 308.7794 308.9199 309.0605 309.2010 309.3415 309.4820 309.6225 309.7630 309.9035 310.0440 310.1844 310.3249 310.4653 310.6057 310.7461 310.8865 311.0269 311.1673 311.3076 311.4480 311.5883 311.7287 311.8690 312.0093 312.1496 312.2898 312.4301 312.5704 312.7106 312.8509 312.9911 313.1313 313.2715 313.4117 313.5519 313.6920 313.8322 313.9723 314.1125 314.2526 314.3927 314.5328 314.6729 314.8129 314.9530 315.0931 315.2331 315.3731 315.5131 315.6531 315.7931 315.9331 316.0731 316.2130 316.3530 316.4929 316.6329 316.7728 316.9127 317.0526 317.1924 317.3323 317.4722 317.6120 317.7518 317.8916 318.0315 318.1712 318.3110 318.4508 318.5906 318.7303 318.8701 319.0098 319.1495 319.2892 319.4289 319.5686 319.7082 319.8479 319.9875 320.1272 320.2668 320.4064 320.5460 320.6856 320.8252 320.9647 321.1043 321.2438 321.3833 321.5229 321.6624 321.8019 321.9413 322.0808 322.2203 322.3597 322.4991 322.6386 322.7780 322.9174 323.0568 323.1961 323.3355 323.4749 323.6142 323.7535 323.8928 324.0321 324.1714 324.3107 324.4500 324.5893 324.7285 324.8677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250715T064926.6Z 9327.284336 202 1 47.86 2 84.67 68.46 45.23 226.33 0.00 1 0.00 1 0 17 6.549e-01 1.464e-02 1.613e-01 3.261e-03 9.761070e-01 1.840393e-03 9.866697e-03 -6.000000e+00 3.720814e-01 228.11 -2.00 3.19 -2.00 322.04 0.00e+00 7.541500e-03 1.074699e-03 1.458458e-03 -6.000000e+00 1.627845e-02 281.95 -2.00 20.00 -2.00 321.61 0.00e+00 9.416 0.009 302.00 328.00 3 1.4929e+00 7.2527e-03 8.7081e-02 -6.0000e+00 9.2629e-01 7.2817e-01 1.0900e-02 5.2985e-02 -6.0000e+00 1.0030e+00 -9.4189e-01 1.1456e-02 2.9120e-02 -6.0000e+00 5.9651e-01 3.7776e-01 5.1945e-03 1.3583e-02 -6.0000e+00 2.5891e-01 3.4347e-05 -1.0246e-03 8.0582e-05 1.8040e-04 -6.0000e+00 1.6970e-02 2.5619e-03 0.0000e+00 12 8 8 10 0 0 3.96 20.96 0.45 0.00256 -0.00514 276 70 1 5 0 173.400 20.96 15.00 14.49 23.39 2.0 760.77 -228951 -137143 -244096 -125608 -267428 -166789 -243620 -170526 -172249 -76079 -193269 -167420 -126663 -128571 -105240 -98841 -24330 -92197 -46997 -86498 -28588 -86924 -62002 -81120 -121105 -76213 -77028 -60274 -61470 -55973 -42889 -1065 -30164 1016 -54548 -11049 -18414 18807 1620 22837 10587 27518 20877 21577 10348 3820 36379 1805 15326 9409 23803 9120 26252 13347 22970 16108 23649 11501 13801 6934 8530 8952 9436 18923 13102 16433 9018 12385 9835 13041 9476 11418 7667 7223 2234 -3033 -5320 -2969 1691 832 3033 955 1079 -1522 1817 680 2148 1813 1490 971 1 -1654 -2324 -2997 -2861 -1694 -805 -399 -1247 -846 -1898 -1158 -1961 -2189 -3321 -1652 -1949 -1746 -1141 -412 52 -172 22 -519 -172 -584 42 -323 683 610 1518 1347 1563 1289 547 777 703 670 160 700 186 314 -229 65 -24 -47 325 75 67 -176 -820 -1048 -3110 -832 -4374 -617 -4792 -1061 -3521 -1282 -1394 -266 -2123 -1790 -1369 -1747 -1460 -1697 -224 -1847 -628 -1733 -309 -1631 -946 -1599 -3696 -1502 -1494 -958 -1036 -1086 -955 -19 -844 21 -1821 -239 -480 407 50 668 384 892 750 775 421 171 1238 94 755 550 1385 693 1853 1163 1906 1480 2023 1068 1185 624 800 962 1194 2503 1929 2341 1436 2075 1779 2616 2109 2512 1655 1557 445 -575 -1028 -625 415 231 979 363 446 -683 837 333 1080 923 744 461 1 -727 -1053 -1540 -1764 -1245 -639 -366 -1241 -819 -1682 -965 -1510 -1749 -2885 -1484 -1725 -1706 -1282 -538 77 -272 36 -816 -259 -872 65 -527 1070 955 2413 2013 2249 1809 751 1028 933 1007 268 1349 401 730 -535 163 -64 -129 910 210 185 -450 -1933 -2458 SS 20250715T070002.2Z 9327.291692 205 1 47.83 2 82.50 69.62 46.89 229.09 0.00 1 0.00 1 0 17 6.566e-01 1.020e-02 3.102e-02 8.674e-04 7.987367e-01 4.697434e-04 8.377908e-03 -6.000000e+00 3.730722e-01 228.11 -2.00 3.19 -2.00 321.26 0.00e+00 3.830017e-03 2.291285e-04 3.100964e-03 -6.000000e+00 1.632161e-02 281.95 -2.00 20.00 -2.00 320.76 0.00e+00 7.121 0.004 302.00 328.00 3 1.1478e+00 1.5937e-03 6.7528e-02 -6.0000e+00 9.2876e-01 1.9775e-01 2.2992e-03 4.2442e-02 -6.0000e+00 1.0057e+00 -2.6077e-01 2.4444e-03 2.4332e-02 -6.0000e+00 5.9810e-01 1.0305e-01 1.1527e-03 8.5382e-03 -6.0000e+00 2.5961e-01 3.2313e-04 -4.4798e-04 2.1789e-05 1.0945e-04 -6.0000e+00 1.7014e-02 2.3335e-03 0.0000e+00 12 8 8 10 0 0 0.91 20.96 0.28 0.00233 -0.00103 1144 291 1 5 0 41.800 20.96 15.01 14.51 23.99 2.0 765.50 -219890 -198654 -213584 -203508 -228593 -206407 -224460 -185232 -201333 -180843 -194018 -149262 -146400 -114888 -98142 -85303 -63217 -64937 -47759 -65167 -48666 -61732 -46610 -48487 -53232 -44027 -48325 -55209 -51689 -39302 -27335 -14664 -14291 -12100 -18410 -16637 -11545 -2216 -28 5273 3532 6175 4652 7649 5065 3552 6286 4827 5839 6792 9321 7740 10276 7789 8952 6402 5849 3733 2644 2477 3611 4644 6004 6164 4954 4002 2593 3118 3835 3842 3390 2690 1673 1373 -590 -1534 -3375 -2342 -1363 -527 -616 -1234 -1624 -1739 -886 -294 76 334 625 316 -102 -961 -1377 -1312 -1235 -603 -91 58 -211 -521 -1042 -1141 -836 -1235 -1623 -1270 -793 -392 193 445 590 432 476 16 83 145 180 70 172 23 476 759 624 509 242 150 468 479 232 229 -59 -85 -165 -282 -189 -85 269 127 -14 -188 -197 -436 -2120 -1781 -2330 -1876 -2513 -1868 -2734 -1755 -2503 -1958 -2609 -1603 -2068 -1584 -1469 -1349 -914 -1071 -715 -1218 -774 -1128 -792 -931 -1157 -912 -1042 -1247 -1172 -931 -731 -423 -476 -403 -620 -567 -431 -93 -1 299 226 413 331 538 374 275 495 411 530 680 947 902 1290 1092 1312 1007 942 600 413 385 591 861 1280 1482 1245 999 670 863 1220 1403 1339 1088 655 496 -194 -460 -1010 -753 -518 -240 -303 -696 -995 -1130 -610 -213 58 254 465 223 -67 -608 -876 -916 -1011 -534 -94 68 -245 -635 -1159 -1118 -762 -1183 -1681 -1375 -909 -488 251 660 904 695 761 25 130 222 285 109 283 38 756 1223 973 767 354 211 649 737 389 437 -116 -176 -366 -632 -453 -210 671 320 -34 -437 -450 -933 SS 20250715T071804.4Z 9327.304217 210 1 48.17 2 78.75 71.54 49.86 233.44 0.00 1 0.00 1 0 17 2.163e-01 6.232e-03 5.585e-03 2.590e-04 5.902544e-01 1.339509e-04 6.234957e-03 -6.000000e+00 1.228752e-01 228.11 -2.00 3.19 -2.00 320.01 0.00e+00 1.621623e-03 4.433994e-05 7.589996e-04 -6.000000e+00 5.375528e-03 281.95 -2.00 20.00 -2.00 319.41 0.00e+00 4.959 0.001 302.00 328.00 3 7.8798e-01 3.8880e-04 4.7000e-02 -6.0000e+00 3.0590e-01 5.5625e-02 4.7856e-04 2.8214e-02 -6.0000e+00 3.3122e-01 -5.4842e-02 4.3678e-04 1.4613e-02 -6.0000e+00 1.9698e-01 1.5690e-02 2.2638e-04 4.7291e-03 -6.0000e+00 8.5510e-02 2.7469e-03 -2.0732e-04 6.8013e-06 4.7311e-05 -6.0000e+00 5.6031e-03 1.7574e-03 0.0000e+00 10 0 0 10 0 0 7.61 20.96 0.27 0.00176 0.00020 4044 1030 1 5 0 11.820 20.96 15.00 14.51 25.23 2.0 773.85 -72716 -75923 -67587 -80627 -78698 -85651 -74642 -67363 -60684 -60636 -58774 -48324 -38407 -24800 -20950 -12917 -13558 -9429 -10697 -7587 -11537 -9254 -9305 -7936 -8792 -7533 -8238 -11196 -10025 -8682 -3617 -1541 -732 -4352 -5100 -6413 -3242 -1609 734 722 1038 1195 1248 1684 1438 1313 764 1054 751 2114 2194 2682 2393 2306 1759 1772 783 472 273 619 1216 1974 2693 2037 1093 475 13 286 1156 909 832 358 424 -225 -561 -1229 -1915 -1787 -1344 -1183 -1192 -1608 -1817 -1292 -910 -107 197 554 640 667 426 8 -195 -63 -140 -9 500 431 69 -308 -685 -722 -250 -756 -1005 -924 -593 -213 375 484 610 434 345 158 132 236 115 141 -35 -266 -55 330 282 342 76 -12 437 574 174 93 -161 -186 -146 -287 -120 -133 268 132 -9 -136 -150 -183 -909 -1103 -934 -1179 -1045 -1255 -1108 -1082 -1022 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