File name: Pandora101s1_Izana_20250806_L2Fit_fwvt1c22d20230904p1-8.txt
File generation date: 20250807T012004.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c22p1-8
Local principal investigator: Alberto Redondas
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 101
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora101_OF_v3d20220624.txt
Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt
Level 1 file used: Pandora101s1_Izana_20250806_L1_smca1c22d20230904p1-8.txt
Full location name: Izana Atmospheric Research Center
Short location name: Izana
Country of location: Spain
Location latitude [deg]: 28.3090
Location longitude [deg]: -16.4994
Location altitude [m]: 2360
Local noon date: 20250806
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 12 fieldcal with sens applied
First and last pixel inside fitting window: 1643 1792
Nominal wavelengths inside fitting window [nm]: 492.0770 492.1980 492.3190 492.4400 492.5609 492.6818 492.8027 492.9236 493.0445 493.1653 493.2862 493.4070 493.5278 493.6486 493.7694 493.8901 494.0109 494.1316 494.2523 494.3730 494.4937 494.6143 494.7350 494.8556 494.9762 495.0968 495.2174 495.3379 495.4585 495.5790 495.6995 495.8200 495.9405 496.0609 496.1814 496.3018 496.4222 496.5426 496.6630 496.7833 496.9037 497.0240 497.1443 497.2646 497.3849 497.5051 497.6254 497.7456 497.8658 497.9860 498.1062 498.2263 498.3464 498.4666 498.5867 498.7068 498.8268 498.9469 499.0669 499.1870 499.3070 499.4270 499.5469 499.6669 499.7868 499.9068 500.0267 500.1466 500.2664 500.3863 500.5061 500.6260 500.7458 500.8655 500.9853 501.1051 501.2248 501.3445 501.4642 501.5839 501.7036 501.8233 501.9429 502.0625 502.1821 502.3017 502.4213 502.5408 502.6604 502.7799 502.8994 503.0189 503.1384 503.2578 503.3773 503.4967 503.6161 503.7355 503.8548 503.9742 504.0935 504.2128 504.3321 504.4514 504.5707 504.6900 504.8092 504.9284 505.0476 505.1668 505.2860 505.4051 505.5242 505.6434 505.7625 505.8815 506.0006 506.1197 506.2387 506.3577 506.4767 506.5957 506.7146 506.8336 506.9525 507.0714 507.1903 507.3092 507.4281 507.5469 507.6658 507.7846 507.9034 508.0221 508.1409 508.2596 508.3784 508.4971 508.6158 508.7345 508.8531 508.9718 509.0904 509.2090 509.3276 509.4462 509.5647 509.6833 509.8018 509.9203
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250806T065110.5Z 9349.285539 123 1 47.69 2 86.61 72.95 131.17 255.81 0.00 1 0.00 1 0 22 3.242e-03 3.213e-03 2.822e-04 2.819e-04 1.206197e+04 1.948366e+01 8.237608e+02 -6.000000e+00 1.793899e+02 282.03 -2.00 20.00 -2.00 505.32 0.00e+00 1.090008e-03 7.770505e-06 7.840585e-05 -6.000000e+00 9.071588e-05 282.03 -2.00 20.00 -2.00 500.59 0.00e+00 1.046769e+00 5.553055e-03 7.653696e-02 -6.000000e+00 6.430229e-02 227.77 -2.00 3.19 -2.00 502.16 0.00e+00 12.780 0.021 489.00 513.00 1 5.7559e+00 4.2498e-04 1.5663e-02 -6.0000e+00 4.9261e-03 2.0679e-03 1.0810e-04 2.0667e-03 -6.0000e+00 1.2817e-03 1.3859e-03 1.0276e-03 2.5810e-05 9.5754e-05 -6.0000e+00 3.2481e-04 -1.1925e-03 6.3413e-05 10 0 0 10 0 0 85.56 20.96 1.25 -0.00119 0.00594 120 31 1 4 0 397.390 20.96 15.00 14.55 27.03 2.0 784.74 -722 -479 25 206 234 514 667 591 613 346 11 -51 -129 -232 -315 -232 -116 141 361 195 77 249 121 238 385 266 89 97 -119 -604 -619 -470 -252 64 200 17 -78 -16 -147 -231 -113 44 110 281 310 325 297 104 -41 -212 -569 -621 -691 -539 -196 -19 120 134 286 270 280 381 365 308 309 135 -114 -235 -212 -373 -426 -337 -208 -21 -9 -221 -429 -441 -438 -442 -374 -319 -307 -177 -203 -209 -127 -135 -159 51 195 260 466 772 392 270 43 -252 -397 -649 -701 -609 -443 -89 -47 -86 -153 -212 -273 -119 -55 87 267 418 516 568 644 508 314 57 102 30 40 257 244 90 211 103 -15 125 57 -235 -212 -201 -256 36 157 89 248 330 177 270 205 243 204 65 -55 -348 -506 -455 -689 -467 24 202 235 526 673 601 621 348 12 -51 -128 -228 -309 -229 -117 141 370 202 80 259 126 243 394 273 91 100 -120 -611 -618 -473 -253 66 206 18 -80 -16 -152 -238 -117 45 112 291 323 340 308 107 -41 -213 -559 -614 -680 -537 -195 -20 122 137 292 275 286 391 376 317 315 136 -113 -236 -211 -368 -418 -331 -207 -21 -10 -221 -422 -427 -421 -422 -359 -308 -299 -175 -202 -210 -124 -135 -158 51 190 256 462 754 385 257 41 -234 -372 -602 -653 -567 -419 -88 -47 -86 -152 -209 -268 -117 -55 88 264 415 514 570 654 520 321 57 101 30 39 256 244 88 207 101 -14 122 57 -230 -206 -195 -250 36 154 89 252 332 180 277 211 251 210 66 -55 -353 -508 -458
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SQ 20250806T070217.2Z 9349.293255 126 2 18.47 2 84.27 74.22 133.43 256.59 0.00 1 0.00 1 0 22 2.660e-03 2.647e-03 1.579e-04 1.576e-04 8.022916e+03 1.041599e+01 5.566632e+02 -6.000000e+00 1.472139e+02 282.03 -2.00 20.00 -2.00 505.30 0.00e+00 8.442016e-04 4.336436e-06 5.873931e-05 -6.000000e+00 7.444807e-05 282.03 -2.00 20.00 -2.00 500.54 0.00e+00 7.558866e-01 3.111567e-03 5.378533e-02 -6.000000e+00 5.278164e-02 227.77 -2.00 3.19 -2.00 502.12 0.00e+00 8.892 0.007 489.00 513.00 1 4.0959e+00 2.3805e-04 1.0827e-02 -6.0000e+00 4.0434e-03 1.4796e-03 6.1015e-05 1.4222e-03 -6.0000e+00 1.0524e-03 1.1472e-02 1.1914e-03 1.4850e-05 6.7813e-05 -6.0000e+00 2.6655e-04 3.1199e-03 1.8770e-05 10 0 0 10 0 0 93.53 20.96 1.36 0.00312 0.01138 508 129 1 4 0 36.270 20.96 15.00 14.55 27.40 1.9 786.79 -607 -422 -137 161 228 425 555 508 553 324 54 -2 -129 -181 -285 -261 -110 119 365 184 131 244 154 171 285 228 83 122 -38 -435 -428 -328 -281 50 137 -81 -92 -73 -205 -181 -105 -37 66 208 252 260 180 67 -49 -147 -445 -499 -622 -493 -178 -8 72 129 210 235 291 322 302 284 207 119 -49 -159 -186 -235 -332 -299 -201 -42 35 -176 -388 -366 -304 -373 -364 -232 -211 -144 -154 -221 -151 -172 -195 -10 81 154 349 339 303 213 -35 -192 -264 -585 -562 -419 -281 -22 3 -136 -106 -159 -215 -89 -15 52 226 370 483 467 482 462 309 67 136 87 93 208 170 118 195 107 9 136 85 -187 -183 -183 -189 -48 118 92 208 264 194 200 214 141 107 77 -34 -240 -456 -434 -579 -410 -133 162 228 433 574 529 573 333 55 -2 -132 -182 -286 -264 -109 122 381 189 135 251 159 178 297 237 86 124 -38 -434 -420 -325 -286 51 143 -85 -96 -75 -208 -183 -106 -38 68 217 265 273 188 69 -49 -149 -439 -482 -616 -481 -178 -8 73 132 215 241 298 331 312 293 211 120 -48 -160 -185 -232 -325 -294 -200 -41 34 -177 -383 -356 -293 -358 -351 -225 -206 -142 -150 -217 -148 -168 -190 -10 80 154 351 338 296 209 -34 -179 -248 -545 -525 -401 -272 -22 3 -137 -106 -157 -212 -89 -15 51 225 370 485 472 491 473 315 67 134 87 92 207 166 116 191 104 9 132 84 -184 -177 -176 -183 -47 115 91 210 263 195 201 217 144 109 77 -34 -238 -449 -427
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