File name: Pandora101s1_Izana_20250807_L2Fit_fwvt1c22d20230904p1-8.txt File generation date: 20250808T011746.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c22p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt Level 1 file used: Pandora101s1_Izana_20250807_L1_smca1c22d20230904p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20250807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 fieldcal with sens applied First and last pixel inside fitting window: 1643 1792 Nominal wavelengths inside fitting window [nm]: 492.0770 492.1980 492.3190 492.4400 492.5609 492.6818 492.8027 492.9236 493.0445 493.1653 493.2862 493.4070 493.5278 493.6486 493.7694 493.8901 494.0109 494.1316 494.2523 494.3730 494.4937 494.6143 494.7350 494.8556 494.9762 495.0968 495.2174 495.3379 495.4585 495.5790 495.6995 495.8200 495.9405 496.0609 496.1814 496.3018 496.4222 496.5426 496.6630 496.7833 496.9037 497.0240 497.1443 497.2646 497.3849 497.5051 497.6254 497.7456 497.8658 497.9860 498.1062 498.2263 498.3464 498.4666 498.5867 498.7068 498.8268 498.9469 499.0669 499.1870 499.3070 499.4270 499.5469 499.6669 499.7868 499.9068 500.0267 500.1466 500.2664 500.3863 500.5061 500.6260 500.7458 500.8655 500.9853 501.1051 501.2248 501.3445 501.4642 501.5839 501.7036 501.8233 501.9429 502.0625 502.1821 502.3017 502.4213 502.5408 502.6604 502.7799 502.8994 503.0189 503.1384 503.2578 503.3773 503.4967 503.6161 503.7355 503.8548 503.9742 504.0935 504.2128 504.3321 504.4514 504.5707 504.6900 504.8092 504.9284 505.0476 505.1668 505.2860 505.4051 505.5242 505.6434 505.7625 505.8815 506.0006 506.1197 506.2387 506.3577 506.4767 506.5957 506.7146 506.8336 506.9525 507.0714 507.1903 507.3092 507.4281 507.5469 507.6658 507.7846 507.9034 508.0221 508.1409 508.2596 508.3784 508.4971 508.6158 508.7345 508.8531 508.9718 509.0904 509.2090 509.3276 509.4462 509.5647 509.6833 509.8018 509.9203 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250807T064047.2Z 9350.278324 140 1 19.27 2 88.90 72.01 117.46 252.88 0.00 1 0.00 1 0 22 4.585e-03 4.521e-03 8.139e-04 8.127e-04 1.360438e+04 5.679259e+01 9.242755e+02 -6.000000e+00 2.537186e+02 282.03 -2.00 20.00 -2.00 505.36 0.00e+00 1.498073e-03 2.245235e-05 9.899823e-05 -6.000000e+00 1.283115e-04 282.03 -2.00 20.00 -2.00 500.73 0.00e+00 1.322903e+00 1.588223e-02 8.637193e-02 -6.000000e+00 9.097498e-02 227.76 -2.00 3.19 -2.00 502.28 0.00e+00 18.662 0.067 489.00 513.00 1 6.2181e+00 1.2149e-03 2.2945e-02 -6.0000e+00 6.9691e-03 -7.1705e-03 3.0799e-04 2.4677e-03 -6.0000e+00 1.8141e-03 4.4883e-04 1.6324e-03 7.3674e-05 1.1003e-04 -6.0000e+00 4.5939e-04 1.0130e-02 -3.2547e-05 12 9 1 12 1 1 0.70 20.96 1.45 0.01013 0.02145 16 11 1 4 0 1133.030 20.96 15.00 14.55 25.62 2.0 776.31 -1085 -785 151 131 519 760 831 791 656 455 138 -52 -231 -278 -549 -355 -189 211 486 316 82 353 299 416 480 217 206 69 -295 -1031 -764 -664 -401 151 328 173 -114 -1 -188 -189 -61 10 148 406 420 389 506 187 45 -309 -674 -906 -970 -697 -279 -33 237 328 438 444 272 453 419 524 246 151 11 -309 -190 -412 -681 -551 -228 -131 -118 -302 -564 -695 -558 -578 -360 -431 -338 -189 -257 -402 -217 -194 -165 -41 174 351 747 956 473 431 135 -230 -713 -1110 -942 -942 -505 -59 56 -3 -310 -330 -338 -338 -11 174 420 556 810 870 941 583 396 202 103 84 -69 215 339 347 322 276 91 -46 85 -230 -543 -347 -296 -75 175 143 336 357 133 184 438 486 275 212 -183 -522 -665 -645 -999 -738 145 126 513 743 826 792 655 451 135 -50 -228 -272 -538 -350 -184 211 494 315 83 354 302 421 488 221 209 69 -299 -1021 -746 -654 -406 152 339 180 -118 -1 -191 -191 -62 10 153 411 430 399 515 194 46 -308 -657 -893 -951 -692 -276 -34 238 331 443 449 276 461 429 535 249 151 12 -311 -189 -406 -670 -544 -227 -132 -120 -304 -559 -678 -539 -557 -347 -418 -331 -188 -257 -395 -213 -195 -166 -41 171 347 740 935 467 411 129 -215 -656 -1013 -863 -889 -482 -57 56 -3 -313 -330 -337 -340 -11 174 422 559 817 885 969 608 413 208 104 83 -69 213 338 348 324 278 92 -46 85 -226 -547 -348 -292 -76 178 145 345 371 141 190 454 506 286 225 -192 -539 -680 -662 SQ 20250807T064334.6Z 9350.280262 144 1 27.00 2 88.32 72.33 118.02 253.12 0.00 1 0.00 1 0 22 4.045e-03 4.005e-03 2.809e-04 2.805e-04 1.197005e+04 1.932918e+01 8.142747e+02 -6.000000e+00 2.238208e+02 282.03 -2.00 20.00 -2.00 505.36 0.00e+00 1.363447e-03 7.757606e-06 9.036572e-05 -6.000000e+00 1.131842e-04 282.03 -2.00 20.00 -2.00 500.72 0.00e+00 1.203215e+00 5.506200e-03 7.844871e-02 -6.000000e+00 8.022598e-02 227.76 -2.00 3.19 -2.00 502.27 0.00e+00 17.115 0.052 489.00 513.00 1 4.6886e+00 4.2142e-04 2.0697e-02 -6.0000e+00 6.1460e-03 -5.5218e-03 1.0682e-04 2.2164e-03 -6.0000e+00 1.5991e-03 2.4834e-03 1.0909e-03 2.5806e-05 9.8255e-05 -6.0000e+00 4.0526e-04 9.7871e-04 5.0636e-05 12 9 1 12 1 1 21.96 20.96 1.38 0.00098 0.00855 124 56 1 4 0 215.950 20.96 15.00 14.55 25.72 2.0 776.45 -881 -611 -189 203 319 636 816 763 703 445 135 -47 -269 -302 -412 -289 -175 140 420 282 172 271 246 301 412 285 215 72 -130 -696 -712 -567 -298 109 266 97 -81 -53 -263 -259 -96 6 153 307 422 452 320 163 -94 -293 -609 -836 -874 -698 -229 -48 214 231 382 341 454 458 479 418 297 130 -128 -302 -255 -331 -547 -409 -322 -130 -41 -279 -541 -553 -525 -558 -554 -442 -348 -254 -187 -314 -199 -196 -144 20 93 382 613 630 509 353 4 -354 -555 -841 -879 -706 -452 -43 -38 -156 -217 -288 -325 -191 -66 162 371 555 724 700 772 699 454 202 60 65 98 264 345 169 304 154 73 169 109 -246 -324 -253 -333 -47 93 194 274 331 286 258 297 241 203 146 -110 -469 -706 -612 -811 -574 -183 197 317 629 819 772 709 445 134 -45 -260 -297 -405 -278 -171 141 419 285 175 275 251 309 424 294 221 73 -128 -691 -698 -561 -295 111 270 99 -82 -54 -269 -263 -98 6 155 315 436 468 330 165 -94 -294 -595 -825 -858 -676 -228 -47 217 236 389 348 464 471 494 430 303 131 -128 -297 -254 -328 -539 -404 -322 -128 -41 -274 -537 -541 -508 -539 -537 -431 -343 -253 -183 -310 -197 -194 -141 20 92 382 615 626 494 341 4 -334 -515 -773 -813 -670 -436 -43 -37 -156 -215 -283 -326 -188 -66 163 377 565 740 704 785 718 465 204 61 65 98 265 348 171 308 157 74 171 110 -245 -319 -248 -330 -47 93 197 283 340 296 270 312 254 213 152 -113 -475 -725 -616 SQ 20250807T064630.8Z 9350.282301 148 1 46.89 2 87.70 72.67 118.61 253.37 0.00 1 0.00 1 0 22 3.709e-03 3.676e-03 1.156e-04 1.154e-04 1.018027e+04 7.784980e+00 6.962034e+02 -6.000000e+00 2.052410e+02 282.03 -2.00 20.00 -2.00 505.33 0.00e+00 1.247473e-03 3.186953e-06 8.144949e-05 -6.000000e+00 1.037902e-04 282.03 -2.00 20.00 -2.00 500.68 0.00e+00 1.123069e+00 2.266308e-03 6.784700e-02 -6.000000e+00 7.357320e-02 227.76 -2.00 3.19 -2.00 502.24 0.00e+00 15.435 0.038 489.00 513.00 1 3.6694e+00 1.7342e-04 1.8348e-02 -6.0000e+00 5.6363e-03 -2.7417e-03 4.4146e-05 1.9162e-03 -6.0000e+00 1.4667e-03 8.3422e-03 1.1539e-03 1.0747e-05 8.6516e-05 -6.0000e+00 3.7161e-04 1.9504e-03 3.7753e-05 12 1 1 12 1 1 -0.06 20.96 1.31 0.00195 0.00995 690 180 1 4 0 67.850 20.96 15.00 14.55 25.78 2.0 776.94 -821 -543 -190 198 317 589 708 662 684 387 86 27 -214 -298 -370 -289 -125 91 397 258 197 259 210 270 427 310 127 101 -143 -640 -669 -509 -322 119 228 58 -32 -32 -190 -191 -108 -2 123 286 343 370 334 92 -70 -291 -627 -745 -825 -637 -243 13 159 229 315 367 390 449 440 385 277 132 -117 -236 -226 -323 -417 -373 -307 -107 -21 -222 -512 -551 -471 -544 -520 -379 -324 -254 -196 -274 -198 -180 -171 -18 123 304 538 509 451 297 -11 -266 -430 -755 -834 -677 -406 -78 -16 -185 -215 -274 -305 -167 -7 157 347 543 682 697 739 631 417 175 150 88 59 273 311 189 244 165 42 164 79 -200 -273 -271 -302 -83 104 103 224 296 239 237 272 234 206 112 -62 -429 -600 -569 -765 -516 -182 195 311 591 721 662 682 393 86 26 -209 -290 -358 -282 -124 90 401 264 202 267 217 273 433 315 129 103 -143 -641 -662 -508 -322 119 234 59 -33 -32 -191 -191 -109 -2 125 296 357 386 346 94 -71 -293 -617 -719 -812 -619 -243 13 162 236 323 376 400 464 445 389 284 133 -117 -233 -226 -321 -412 -370 -300 -106 -21 -219 -509 -540 -457 -527 -505 -370 -320 -248 -193 -272 -196 -178 -169 -18 123 306 544 511 443 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