File name: Pandora101s1_Izana_20250811_L2Fit_fwvt1c22d20230904p1-8.txt
File generation date: 20250812T012053.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c22p1-8
Local principal investigator: Alberto Redondas
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 101
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora101_OF_v3d20220624.txt
Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt
Level 1 file used: Pandora101s1_Izana_20250811_L1_smca1c22d20230904p1-8.txt
Full location name: Izana Atmospheric Research Center
Short location name: Izana
Country of location: Spain
Location latitude [deg]: 28.3090
Location longitude [deg]: -16.4994
Location altitude [m]: 2360
Local noon date: 20250811
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Based on session 12 fieldcal with sens applied
First and last pixel inside fitting window: 1643 1792
Nominal wavelengths inside fitting window [nm]: 492.0770 492.1980 492.3190 492.4400 492.5609 492.6818 492.8027 492.9236 493.0445 493.1653 493.2862 493.4070 493.5278 493.6486 493.7694 493.8901 494.0109 494.1316 494.2523 494.3730 494.4937 494.6143 494.7350 494.8556 494.9762 495.0968 495.2174 495.3379 495.4585 495.5790 495.6995 495.8200 495.9405 496.0609 496.1814 496.3018 496.4222 496.5426 496.6630 496.7833 496.9037 497.0240 497.1443 497.2646 497.3849 497.5051 497.6254 497.7456 497.8658 497.9860 498.1062 498.2263 498.3464 498.4666 498.5867 498.7068 498.8268 498.9469 499.0669 499.1870 499.3070 499.4270 499.5469 499.6669 499.7868 499.9068 500.0267 500.1466 500.2664 500.3863 500.5061 500.6260 500.7458 500.8655 500.9853 501.1051 501.2248 501.3445 501.4642 501.5839 501.7036 501.8233 501.9429 502.0625 502.1821 502.3017 502.4213 502.5408 502.6604 502.7799 502.8994 503.0189 503.1384 503.2578 503.3773 503.4967 503.6161 503.7355 503.8548 503.9742 504.0935 504.2128 504.3321 504.4514 504.5707 504.6900 504.8092 504.9284 505.0476 505.1668 505.2860 505.4051 505.5242 505.6434 505.7625 505.8815 506.0006 506.1197 506.2387 506.3577 506.4767 506.5957 506.7146 506.8336 506.9525 507.0714 507.1903 507.3092 507.4281 507.5469 507.6658 507.7846 507.9034 508.0221 508.1409 508.2596 508.3784 508.4971 508.6158 508.7345 508.8531 508.9718 509.0904 509.2090 509.3276 509.4462 509.5647 509.6833 509.8018 509.9203
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250811T064303.6Z 9354.279903 195 1 21.23 2 88.87 73.35 67.75 247.91 0.00 1 0.00 1 0 22 4.936e-03 4.879e-03 1.347e-03 1.344e-03 1.244732e+04 9.277603e+01 8.384067e+02 -6.000000e+00 2.731951e+02 282.04 -2.00 20.00 -2.00 505.36 0.00e+00 1.486380e-03 3.709025e-05 9.808369e-05 -6.000000e+00 1.381104e-04 282.04 -2.00 20.00 -2.00 500.74 0.00e+00 1.333820e+00 2.627881e-02 8.362553e-02 -6.000000e+00 9.778413e-02 227.70 -2.00 3.19 -2.00 502.29 0.00e+00 18.577 0.066 489.00 513.00 1 7.2113e+00 2.0105e-03 2.2738e-02 -6.0000e+00 7.4929e-03 -3.1556e-03 5.0988e-04 2.3657e-03 -6.0000e+00 1.9464e-03 1.6805e-04 -7.6265e-04 1.2319e-04 9.8747e-05 -6.0000e+00 4.9425e-04 -7.8639e-03 1.9452e-04 12 9 9 12 1 1 1.15 21.06 1.65 -0.00786 -0.01315 6 4 1 4 0 3031.550 21.06 15.00 14.60 27.29 2.0 787.00 -1096 -1015 534 -347 98 613 697 854 702 433 -34 -59 -316 -461 -722 -206 -331 49 213 404 160 220 489 602 606 327 371 98 -175 -1060 -732 -866 -575 21 526 355 35 188 -310 -323 39 219 260 396 395 462 334 118 -167 -143 -726 -846 -1142 -298 -337 -15 569 306 751 237 365 590 499 315 530 50 -146 -415 -245 -356 -362 -599 -627 41 -250 -170 -484 -850 -585 -600 -350 -449 -276 -105 -143 -131 -105 -316 -160 -58 184 541 755 1805 171 181 140 -513 -554 -1045 -791 -807 -452 39 89 201 -513 -471 -134 -501 -121 -7 424 531 599 812 746 702 517 49 15 -82 182 523 146 383 318 214 13 232 -251 -264 -348 -374 -321 -151 -46 250 323 372 78 428 283 252 369 184 47 -821 -678 -886 -1005 -951 510 -333 97 614 709 842 691 438 -34 -59 -310 -448 -701 -200 -330 48 213 409 163 224 500 617 625 339 382 99 -174 -1034 -729 -840 -573 22 530 360 35 194 -319 -331 40 218 263 405 407 476 343 120 -167 -144 -716 -818 -1102 -290 -337 -15 574 311 762 242 373 604 513 325 539 51 -145 -408 -246 -355 -359 -598 -613 41 -247 -167 -484 -840 -571 -585 -341 -441 -273 -101 -140 -129 -103 -310 -157 -57 182 538 755 1767 166 176 132 -474 -520 -976 -741 -750 -438 38 90 204 -522 -474 -134 -508 -120 -7 426 535 606 827 771 731 538 51 15 -82 180 518 146 384 320 215 14 233 -251 -260 -340 -364 -316 -151 -47 251 330 385 82 451 300 269 392 194 49 -843 -688 -903
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SQ 20250811T064856.2Z 9354.283983 203 1 41.71 2 87.63 74.04 68.91 248.80 0.00 1 0.00 1 0 22 3.832e-03 3.794e-03 2.249e-04 2.246e-04 1.003795e+04 1.510802e+01 6.873729e+02 -6.000000e+00 2.120636e+02 282.04 -2.00 20.00 -2.00 505.33 0.00e+00 1.315970e-03 6.195900e-06 8.376608e-05 -6.000000e+00 1.072413e-04 282.04 -2.00 20.00 -2.00 500.69 0.00e+00 1.083882e+00 4.402231e-03 6.757384e-02 -6.000000e+00 7.601180e-02 227.70 -2.00 3.19 -2.00 502.24 0.00e+00 15.239 0.036 489.00 513.00 1 4.8980e+00 3.3682e-04 1.8113e-02 -6.0000e+00 5.8232e-03 -4.7471e-03 8.5831e-05 1.9003e-03 -6.0000e+00 1.5153e-03 2.5002e-03 1.3049e-03 2.0938e-05 8.4104e-05 -6.0000e+00 3.8396e-04 1.2196e-03 4.1581e-05 12 9 1 12 1 1 32.22 21.06 1.37 0.00122 0.01027 186 55 1 4 0 223.040 21.06 15.00 14.61 27.36 2.0 787.59 -888 -640 -176 116 295 589 730 669 677 372 114 25 -224 -317 -402 -311 -138 125 429 257 189 254 217 274 444 327 160 111 -140 -667 -691 -505 -328 133 235 50 -28 -17 -192 -202 -79 23 171 315 390 386 337 124 -99 -255 -663 -710 -826 -679 -243 47 182 272 298 377 426 453 436 391 323 137 -114 -221 -199 -318 -428 -400 -296 -73 -32 -227 -524 -537 -518 -556 -511 -411 -405 -272 -201 -275 -232 -183 -185 14 101 308 570 636 401 315 -1 -289 -449 -777 -815 -672 -380 -20 -21 -166 -229 -258 -316 -180 12 162 393 554 663 700 743 678 410 201 154 56 102 293 312 244 245 143 26 204 74 -247 -310 -323 -337 -110 151 92 284 292 266 236 307 225 141 94 -140 -436 -645 -606 -834 -614 -170 112 291 594 727 672 677 369 114 25 -220 -310 -391 -305 -137 124 435 264 195 262 219 278 451 333 162 114 -140 -654 -687 -492 -329 134 242 52 -29 -18 -193 -203 -79 23 175 327 398 394 351 128 -100 -258 -655 -688 -796 -664 -244 47 186 281 307 387 439 458 442 396 324 139 -115 -219 -195 -317 -425 -399 -291 -72 -32 -225 -511 -529 -505 -542 -500 -405 -392 -266 -199 -274 -232 -182 -184 14 101 304 565 625 397 302 -1 -271 -425 -728 -768 -633 -363 -20 -21 -167 -229 -255 -312 -179 12 166 393 556 668 711 763 701 423 204 154 57 102 295 309 243 244 142 25 202 73 -246 -306 -318 -334 -108 152 95 287 299 276 247 323 231 145 98 -144 -441 -644 -607
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