File name: Pandora101s1_Izana_20250822_L2Fit_fout2c22d20230904p1-8.txt File generation date: 20250823T012243.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 101 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora101_OF_v3d20220624.txt Instrument calibration file used: Pandora101s1_CF_v22d20230904.txt Level 1 file used: Pandora101s1_Izana_20250822_L1_smca1c22d20230904p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20250822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 fieldcal with sens applied First and last pixel inside fitting window: 222 363 Nominal wavelengths inside fitting window [nm]: 305.1209 305.2618 305.4026 305.5434 305.6843 305.8251 305.9659 306.1066 306.2474 306.3882 306.5289 306.6697 306.8104 306.9511 307.0918 307.2325 307.3732 307.5139 307.6545 307.7952 307.9358 308.0764 308.2170 308.3576 308.4982 308.6388 308.7794 308.9199 309.0605 309.2010 309.3415 309.4820 309.6225 309.7630 309.9035 310.0440 310.1844 310.3249 310.4653 310.6057 310.7461 310.8865 311.0269 311.1673 311.3076 311.4480 311.5883 311.7287 311.8690 312.0093 312.1496 312.2898 312.4301 312.5704 312.7106 312.8509 312.9911 313.1313 313.2715 313.4117 313.5519 313.6920 313.8322 313.9723 314.1125 314.2526 314.3927 314.5328 314.6729 314.8129 314.9530 315.0931 315.2331 315.3731 315.5131 315.6531 315.7931 315.9331 316.0731 316.2130 316.3530 316.4929 316.6329 316.7728 316.9127 317.0526 317.1924 317.3323 317.4722 317.6120 317.7518 317.8916 318.0315 318.1712 318.3110 318.4508 318.5906 318.7303 318.8701 319.0098 319.1495 319.2892 319.4289 319.5686 319.7082 319.8479 319.9875 320.1272 320.2668 320.4064 320.5460 320.6856 320.8252 320.9647 321.1043 321.2438 321.3833 321.5229 321.6624 321.8019 321.9413 322.0808 322.2203 322.3597 322.4991 322.6386 322.7780 322.9174 323.0568 323.1961 323.3355 323.4749 323.6142 323.7535 323.8928 324.0321 324.1714 324.3107 324.4500 324.5893 324.7285 324.8677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250822T070826.6Z 9365.297530 64 1 21.72 2 84.60 79.65 73.64 78.39 0.00 1 0.00 1 0 25 4.339e-01 4.219e-02 2.906e-01 1.687e-02 9.110605e-01 9.385428e-03 9.361937e-03 -6.000000e+00 2.473116e-01 227.48 -2.00 3.19 -2.00 321.59 0.00e+00 -3.024979e-02 4.042303e-03 5.760104e-03 -6.000000e+00 1.099952e-02 281.83 -2.00 20.00 -2.00 321.05 0.00e+00 9.325 0.008 302.00 328.00 3 3.8058e+00 3.1305e-02 1.0128e-01 -6.0000e+00 6.1598e-01 1.1954e+00 4.0427e-02 1.0275e-01 -6.0000e+00 6.6783e-01 -1.5178e+00 3.3250e-02 2.3217e-02 -6.0000e+00 3.9558e-01 6.0901e-01 1.6419e-02 3.2875e-02 -6.0000e+00 1.7174e-01 3.7935e-06 -1.4325e-03 4.2149e-04 2.8369e-04 -6.0000e+00 1.1579e-02 1.0453e-03 0.0000e+00 12 9 9 12 1 1 89.55 21.06 0.37 0.00105 -0.00972 8 5 1 5 0 2413.130 21.06 15.00 14.57 25.02 2.0 769.92 18635 6611 -9444 900000 -18442 11971 81524 900000 65152 101547 25518 85575 32563 28402 203645 39281 138290 106365 16008 31135 23378 39331 58741 82824 -86591 63467 29508 52319 5035 66744 15041 54804 -11933 37520 -12009 -83907 63083 48199 94324 112302 78438 78960 89285 -73140 33222 31152 91186 50676 44166 34177 52596 63241 39130 47439 66332 56314 39352 55899 42357 18476 11979 11916 13886 34083 12571 18794 14163 5845 15170 22711 18471 20513 13630 16441 17135 -2256 3293 -1501 -2086 -9555 -21 2410 1525 5726 182 0 3006 2965 -1040 -2853 -3437 991 -6312 -3839 -2600 -905 -3976 -2185 -4252 -2413 -6515 -4968 -2178 -4373 -7098 -2976 -2654 -2883 -1592 -1125 -113 1488 1472 110 1484 -296 -1372 -157 -211 1612 1603 2607 2617 2937 2172 3594 3945 1023 805 270 -159 -757 -1000 457 80 -122 1135 311 1502 623 -4496 -1581 579 223 -337 900000 -535 266 1341 900000 1513 1768 963 1821 1229 1181 3349 1634 2274 2405 821 1325 1018 1446 2046 2804 -17326 3070 1798 2205 273 2058 815 2366 -1027 2044 -918 -13068 2723 3022 4751 5656 5691 5729 5873 -19713 2989 2682 4405 3698 3586 3337 4811 5785 4694 5736 7636 7245 6167 7084 5532 2770 1877 2017 2593 5737 2663 3636 2932 1425 3889 6174 5629 6211 4206 4469 4045 -572 758 -383 -622 -3660 -8 1107 773 2958 106 0 1744 1824 -609 -1689 -1908 507 -3529 -2314 -1706 -682 -3578 -2201 -4661 -2533 -6494 -4294 -1702 -3644 -6563 -2770 -2617 -3105 -1929 -1489 -167 2309 2315 171 2179 -431 -2068 -245 -347 2616 2487 3778 3665 4208 3040 4767 5162 1449 1345 520 -322 -1660 -2352 1144 206 -326 3014 835 3873 1584 -11002 -3465 SS 20250822T071933.6Z 9365.305251 67 1 47.90 2 82.19 80.92 71.32 79.55 0.00 1 0.00 1 0 25 5.432e-01 8.987e-03 9.940e-02 1.896e-03 7.571570e-01 1.025197e-03 7.887181e-03 -6.000000e+00 3.083170e-01 227.48 -2.00 3.19 -2.00 321.15 0.00e+00 4.119975e-03 4.843819e-04 1.891672e-03 -6.000000e+00 1.349623e-02 281.83 -2.00 20.00 -2.00 320.64 0.00e+00 6.882 0.003 302.00 328.00 3 2.9458e+00 3.4146e-03 6.3939e-02 -6.0000e+00 7.6623e-01 1.5319e-01 4.8473e-03 3.8082e-02 -6.0000e+00 8.2966e-01 -1.8660e-01 5.1644e-03 2.2074e-02 -6.0000e+00 4.9426e-01 6.8845e-02 2.4638e-03 8.5248e-03 -6.0000e+00 2.1550e-01 6.6819e-05 -5.5335e-04 4.8716e-05 9.7789e-05 -6.0000e+00 1.4072e-02 9.3660e-04 0.0000e+00 11 9 0 11 8 0 99.21 21.06 0.31 0.00094 -0.00322 211 54 1 5 0 226.980 21.06 15.00 14.57 25.19 2.0 771.61 -221737 -138213 -186830 -129341 -229310 -68002 -203383 -165344 -146378 -129224 -151630 -143864 -93999 -113504 -83486 -86483 -45890 -67699 -28294 -63032 -18510 -48659 -28397 -44907 -82468 -27312 -30436 -29361 -42762 -6364 -26410 -265 -23320 -3618 -22962 -27462 -13479 3963 -4146 5330 4408 4470 4676 900000 -702 -2782 5849 -1411 4131 1881 6929 2784 8743 5397 8668 4260 4249 1290 2885 2694 2162 3911 5113 6210 3434 4827 2033 2791 2616 2462 2043 2749 1002 506 -367 -1455 -2420 -2565 -1177 -1433 -641 -1825 -1551 -2017 -349 -419 57 294 901 416 274 -715 -716 -631 -1051 -167 133 455 -291 -167 -963 -958 -816 -983 -1672 -1156 -892 -371 344 15 764 514 510 -108 154 5 73 -103 16 -109 316 780 532 440 92 400 247 625 126 258 -97 -27 -195 -183 -86 -194 267 127 32 -135 -325 -294 -2405 -766 -1734 -648 -2838 -180 -2289 -1467 -1202 -955 -1520 -1654 -904 -1729 -1207 -1545 -622 -1279 -398 -1292 -250 -897 -462 -953 -2689 -550 -632 -590 -1017 -123 -771 -7 -934 -122 -890 -1147 -563 171 -240 324 300 326 357 900000 -59 -247 497 -137 406 209 819 386 1260 875 1435 755 767 235 509 474 407 808 1213 1607 941 1277 561 819 887 941 845 1149 410 192 -128 -463 -758 -866 -455 -658 -342 -1099 -988 -1367 -244 -311 44 229 685 301 188 -470 -476 -449 -859 -154 140 524 -352 -199 -1072 -956 -775 -979 -1774 -1258 -1030 -454 455 23 1208 836 835 -171 234 7 111 -164 27 -182 517 1225 822 658 135 562 350 940 213 479 -192 -55 -421 -412 -201 -470 652 309 77 -315 -723 -621 SS 20250822T073451.0Z 9365.315868 72 1 47.82 2 78.86 82.66 68.12 81.15 0.00 1 0.00 1 0 17 1.997e-01 5.840e-03 1.163e-02 5.118e-04 5.820359e-01 2.644841e-04 6.133697e-03 -6.000000e+00 1.132204e-01 227.48 -2.00 3.19 -2.00 320.02 0.00e+00 1.314778e-03 8.821945e-05 6.380188e-04 -6.000000e+00 4.961900e-03 281.83 -2.00 20.00 -2.00 319.42 0.00e+00 5.004 0.001 302.00 328.00 3 2.1354e+00 7.7140e-04 4.6929e-02 -6.0000e+00 2.8146e-01 3.7777e-02 9.5242e-04 2.7751e-02 -6.0000e+00 3.0487e-01 -4.0147e-02 8.7350e-04 1.4316e-02 -6.0000e+00 1.8139e-01 9.3942e-03 4.5156e-04 4.5451e-03 -6.0000e+00 7.8865e-02 7.0771e-04 -2.4125e-04 1.3534e-05 4.5135e-05 -6.0000e+00 5.1722e-03 -7.3696e-05 0.0000e+00 10 0 0 10 0 0 5.55 20.96 0.24 -0.00007 -0.00189 1074 274 1 5 0 44.520 20.96 15.00 14.57 25.46 1.9 771.62 -70300 -64461 -65525 -67772 -75458 -74192 -74983 -58932 -61996 -54443 -55973 -42135 -37905 -22435 -21782 -14078 -10128 -8399 -8394 -8645 -8216 -9938 -7066 -8185 -9399 -7079 -7193 -11152 -7868 -7583 -4053 -1603 -1677 -3314 -5142 -6162 -3480 -730 396 1513 723 1175 1034 -133 1080 856 891 859 593 1680 2289 2084 2204 2034 1502 1531 718 432 346 447 1163 1741 2658 1976 919 538 76 295 949 844 696 424 439 -47 -518 -1136 -1855 -1500 -1293 -1145 -1055 -1453 -1776 -1321 -819 -155 264 452 738 726 454 50 -160 -15 -172 45 443 464 77 -326 -710 -740 -168 -800 -1028 -957 -606 -201 377 491 564 508 405 129 121 193 56 9 -98 -342 -105 288 269 313 157 -2 393 550 192 132 -156 -168 -143 -232 -123 -171 286 164 3 -124 -148 -239 -849 -827 -880 -866 -964 -963 -1111 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