File name: Pandora121s1_Izana_20231031_L2Fit_fout2c51d20221209p1-8.txt File generation date: 20231103T081253.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c51p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora121_OF_v2d20210519.txt Instrument calibration file used: Pandora121s1_CF_v51d20221209.txt Level 1 file used: Pandora121s1_Izana_20231031_L1_smca1c51d20221209p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20231031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Analab+Fld after lab cal First and last pixel inside fitting window: 224 365 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2431 305.3842 305.5254 305.6665 305.8076 305.9487 306.0899 306.2309 306.3720 306.5131 306.6542 306.7952 306.9362 307.0773 307.2183 307.3593 307.5003 307.6412 307.7822 307.9232 308.0641 308.2050 308.3460 308.4869 308.6278 308.7687 308.9095 309.0504 309.1913 309.3321 309.4729 309.6137 309.7546 309.8953 310.0361 310.1769 310.3177 310.4584 310.5992 310.7399 310.8806 311.0213 311.1620 311.3027 311.4433 311.5840 311.7247 311.8653 312.0059 312.1465 312.2871 312.4277 312.5683 312.7089 312.8494 312.9900 313.1305 313.2710 313.4115 313.5520 313.6925 313.8330 313.9734 314.1139 314.2543 314.3948 314.5352 314.6756 314.8160 314.9564 315.0967 315.2371 315.3775 315.5178 315.6581 315.7984 315.9387 316.0790 316.2193 316.3596 316.4998 316.6401 316.7803 316.9205 317.0607 317.2009 317.3411 317.4813 317.6215 317.7616 317.9018 318.0419 318.1820 318.3221 318.4622 318.6023 318.7424 318.8824 319.0225 319.1625 319.3025 319.4425 319.5825 319.7225 319.8625 320.0025 320.1424 320.2824 320.4223 320.5622 320.7021 320.8420 320.9819 321.1218 321.2617 321.4015 321.5413 321.6812 321.8210 321.9608 322.1006 322.2404 322.3801 322.5199 322.6596 322.7994 322.9391 323.0788 323.2185 323.3582 323.4979 323.6375 323.7772 323.9168 324.0565 324.1961 324.3357 324.4753 324.6149 324.7544 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Azimuth motor temperature [°C], 999=no temperature signal Column 98: Zenith motor temperature [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231031T075542.7Z 8704.330355 205 1 51.02 2 82.67 110.33 66.32 286.97 0.00 1 0.00 1 0 17 4.190e-01 1.952e-02 4.131e-01 9.076e-03 7.580478e-01 5.041454e-03 7.956018e-03 -6.000000e+00 2.388538e-01 224.77 -2.00 3.19 -2.00 321.65 0.00e+00 -9.142057e-03 2.556960e-03 7.321039e-03 -6.000000e+00 1.042359e-02 277.25 -2.00 20.00 -2.00 321.20 0.00e+00 7.273 0.004 302.00 328.00 3 2.8283e+00 1.7889e-02 8.0898e-02 -6.0000e+00 5.9318e-01 1.8221e-01 2.6892e-02 7.7090e-02 -6.0000e+00 6.4643e-01 -3.0365e-01 2.9344e-02 2.6845e-02 -6.0000e+00 3.8139e-01 1.2614e-01 1.3672e-02 1.0684e-02 -6.0000e+00 1.6320e-01 6.1555e-05 -3.0394e-04 2.5716e-04 8.1716e-05 -6.0000e+00 1.1165e-02 1.3650e-03 1.7058e-05 12 8 8 10 0 0 98.31 15.86 0.29 0.00136 -0.00092 45 8 4 8 0 1133.490 15.00 15.86 16.82 46.60 46.60 20.77 20.87 26.2 776.90 -189702 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938 1009 2019 1986 570 2491 1344 2153 1426 1384 2473 1972 2135 424 1522 1445 891 1258 522 907 1520 2821 2279 2743 284 1856 1646 1003 1903 242 254 -604 814 -552 -967 280 -580 1124 220 912 -904 -332 -1254 -632 -434 140 -60 -1501 441 -1257 -1622 -2665 -1949 -1637 -2072 -567 -3005 -1203 -2319 -1944 -667 -330 1397 530 1244 75 689 950 499 1099 1550 582 657 2160 1051 1461 947 -1714 1623 2323 894 -8 -487 -1762 565 -1575 -104 0 234 1172 -635 194 -1250 -802 SS 20231031T080133.7Z 8704.334418 208 1 11.37 2 81.47 111.09 67.51 287.49 0.00 1 0.00 1 0 17 4.689e-01 1.048e-02 2.527e-01 5.700e-03 6.657098e-01 3.034194e-03 7.013846e-03 -6.000000e+00 2.653124e-01 224.77 -2.00 3.19 -2.00 320.96 0.00e+00 3.185924e-03 1.317102e-03 2.248441e-03 -6.000000e+00 1.172702e-02 277.25 -2.00 20.00 -2.00 320.47 0.00e+00 6.371 0.003 302.00 328.00 3 2.3461e+00 9.6479e-03 5.8003e-02 -6.0000e+00 6.5585e-01 5.9964e-02 1.3212e-02 3.3785e-02 -6.0000e+00 7.1347e-01 -7.9252e-02 1.4006e-02 1.9965e-02 -6.0000e+00 4.2332e-01 2.7650e-02 6.8323e-03 7.5777e-03 -6.0000e+00 1.8344e-01 2.0199e-04 -2.4516e-04 1.5564e-04 9.2520e-05 -6.0000e+00 1.2292e-02 7.8973e-04 1.1924e-05 12 9 9 12 1 1 85.41 15.86 0.23 0.00079 -0.00105 15 12 1 8 0 710.060 14.99 15.86 16.91 47.60 46.10 20.77 20.87 26.3 777.41 -141174 900000 -89234 199983 -201164 900000 -186512 -57830 -157574 -127776 -150358 -136128 12703 -95809 36126 -81348 162263 -46624 12632 5053 -30511 70676 -50768 -2307 -57125 9270 -30491 -4916 -20865 -17866 30194 -7400 35690 -17970 1554 -10641 -9994 10907 247 13845 -12015 13819 -9201 -3481 -1105 4873 1232 -2344 9580 -3396 12048 1835 6647 4835 3957 3325 1199 5300 -1403 4818 159 2686 2726 1702 4316 -2253 4648 -537 4355 257 4031 2975 662 1429 -498 2360 -4638 -281 -2975 155 -2175 -1207 -1211 -2005 225 -754 669 124 757 744 -105 -1106 -2148 -223 -977 -36 690 1052 666 -1357 -121 -2112 -919 -502 -1094 -1682 -1267 -565 159 1060 -306 750 -343 -42 26 -89 711 92 529 -299 443 696 219 1147 901 285 403 642 135 116 -635 -429 -575 -119 185 -10 515 -142 127 45 -485 -364 -1133 900000 -523 1111 -3166 900000 -2878 -321 -2383 -1538 -2413 -2269 71 -1833 248 -2034 901 -1036 168 76 -669 601 -1473 -46 -2004 186 -913 -111 -560 -529 680 -292 1057 -888 63 -476 -508 552 17 992 -1237 1176 -1033 -377 -119 510 138 -285 1095 -459 1580 298 1130 907 788 696 261 1088 -299 962 35 661 771 540 1359 -735 1420 -184 1552 109 1773 1348 296 587 -188 820 -1673 -104 -1259 76 -1265 -748 -806 -1426 167 -602 550 103 617 573 -75 -760 -1475 -163 -830 -34 742 1218 809 -1620 -135 -2144 -880 -507 -1193 -1936 -1542 -708 222 1577 -502 1249 -567 -66 39 -128 1056 146 879 -506 721 1080 330 1723 1306 398 561 987 229 211 -1252 -854 -1211 -256 425 -23 1232 -345 300 100 -1053 -750 SS 20231031T081649.6Z 8704.345018 213 1 53.50 2 78.36 113.13 70.59 288.86 0.00 1 0.00 1 0 17 7.794e-02 5.445e-03 2.154e-02 6.325e-04 5.309286e-01 3.273685e-04 5.604017e-03 -6.000000e+00 4.381568e-02 224.77 -2.00 3.19 -2.00 320.36 0.00e+00 1.725088e-03 1.170723e-04 4.043879e-04 -6.000000e+00 1.904753e-03 277.25 -2.00 20.00 -2.00 319.82 0.00e+00 4.805 0.001 302.00 328.00 3 4.7542e-01 9.7439e-04 4.4042e-02 -6.0000e+00 1.0840e-01 2.9123e-03 1.2259e-03 2.5315e-02 -6.0000e+00 1.1788e-01 2.2421e-02 1.1884e-03 1.3419e-02 -6.0000e+00 7.0110e-02 -2.2130e-02 6.0841e-04 4.7083e-03 -6.0000e+00 3.0282e-02 4.6556e-03 -3.9543e-04 1.7910e-05 4.9234e-05 -6.0000e+00 2.0390e-03 7.5020e-04 -9.9540e-06 10 0 0 10 0 0 10.41 15.86 0.17 0.00075 -0.00222 1001 171 2 8 0 51.140 15.00 15.86 17.36 47.60 45.60 20.77 20.87 26.4 779.81 -24703 -28721 -16639 -25535 -32498 -23533 -33932 -24440 -22074 -13580 -27247 -17325 -10828 -11693 -8489 -7789 -3694 -4213 -1050 -1051 -3046 -4204 -2093 -40 -5220 -2900 -4217 -5119 -6269 -3632 794 -142 830 -2613 -4877 -5599 -4842 -2336 -2034 -2440 -2919 -2077 -2155 -1338 -432 -602 -675 -454 -1343 -16 703 766 1032 1142 490 594 -112 -418 -564 -121 815 1752 2554 2176 79 81 -432 220 1725 1234 1393 1211 990 1059 397 44 -763 -1158 -427 -966 -731 -1267 -1944 -1139 -766 -123 272 654 967 674 820 -4 -43 296 72 24 810 889 20 -338 -771 -906 -237 -112 -1511 -1171 -1153 -755 31 203 313 82 262 -146 -12 300 230 216 64 -405 -123 370 677 545 590 -255 664 913 248 39 -235 -406 -257 -93 -35 -307 504 267 -48 77 -250 -424 -183 -252 -135 -214 -269 -180 -322 -246 -245 -147 -353 -234 -172 -237 -186 -196 -98 -124 -32 -34 -102 -143 -74 -2 -227 -130 -190 -224 -275 -169 42 -9 58 -192 -347 -411 -402 -231 -247 -348 -460 -345 -373 -233 -76 -108 -122 -84 -260 -3 159 192 279 331 150 188 -36 -134 -176 -38 267 634 1035 884 33 32 -183 97 781 640 775 689 547 547 187 20 -338 -535 -206 -550 -476 -925 -1524 -937 -674 -114 263 638 923 609 684 -3 -32 237 65 25 954 1077 25 -414 -934 -989 -249 -125 -1832 -1482 -1423 -991 44 320 527 141 432 -228 -18 425 337 334 106 -684 -204 584 1032 798 829 -345 950 1306 401 69 -446 -801 -530 -190 -75 -688 1141 613 -107 165 -508 -885 SS 20231031T082347.8Z 8704.349859 216 1 53.08 2 76.95 114.09 71.98 289.49 0.00 1 0.00 1 0 17 5.238e-02 5.649e-03 1.082e-02 4.753e-04 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