File name: Pandora121s1_Izana_20240428_L2Fit_fout2c51d20221209p1-8.txt File generation date: 20240429T104820.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c51p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora121_OF_v2d20210519.txt Instrument calibration file used: Pandora121s1_CF_v51d20221209.txt Level 1 file used: Pandora121s1_Izana_20240428_L1_smca1c51d20221209p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20240428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Analab+Fld after lab cal First and last pixel inside fitting window: 224 365 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2431 305.3842 305.5254 305.6665 305.8076 305.9487 306.0899 306.2309 306.3720 306.5131 306.6542 306.7952 306.9362 307.0773 307.2183 307.3593 307.5003 307.6412 307.7822 307.9232 308.0641 308.2050 308.3460 308.4869 308.6278 308.7687 308.9095 309.0504 309.1913 309.3321 309.4729 309.6137 309.7546 309.8953 310.0361 310.1769 310.3177 310.4584 310.5992 310.7399 310.8806 311.0213 311.1620 311.3027 311.4433 311.5840 311.7247 311.8653 312.0059 312.1465 312.2871 312.4277 312.5683 312.7089 312.8494 312.9900 313.1305 313.2710 313.4115 313.5520 313.6925 313.8330 313.9734 314.1139 314.2543 314.3948 314.5352 314.6756 314.8160 314.9564 315.0967 315.2371 315.3775 315.5178 315.6581 315.7984 315.9387 316.0790 316.2193 316.3596 316.4998 316.6401 316.7803 316.9205 317.0607 317.2009 317.3411 317.4813 317.6215 317.7616 317.9018 318.0419 318.1820 318.3221 318.4622 318.6023 318.7424 318.8824 319.0225 319.1625 319.3025 319.4425 319.5825 319.7225 319.8625 320.0025 320.1424 320.2824 320.4223 320.5622 320.7021 320.8420 320.9819 321.1218 321.2617 321.4015 321.5413 321.6812 321.8210 321.9608 322.1006 322.2404 322.3801 322.5199 322.6596 322.7994 322.9391 323.0788 323.2185 323.3582 323.4979 323.6375 323.7772 323.9168 324.0565 324.1961 324.3357 324.4753 324.6149 324.7544 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Azimuth motor temperature [°C], 999=no temperature signal Column 98: Zenith motor temperature [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240428T073347.8Z 8884.315137 208 1 2.46 2 76.71 80.69 72.16 221.01 0.00 1 0.00 1 0 17 2.305e-01 8.895e-03 2.556e-01 6.393e-03 6.544531e-01 3.325510e-03 6.842295e-03 -6.000000e+00 1.314616e-01 228.47 -2.00 3.19 -2.00 320.04 0.00e+00 3.484931e-03 1.101681e-03 8.859441e-04 -6.000000e+00 5.625954e-03 276.98 -2.00 20.00 -2.00 319.52 0.00e+00 4.247 0.001 302.00 328.00 3 2.7870e+00 9.6045e-03 4.4950e-02 -6.0000e+00 3.2806e-01 7.3645e-02 1.1919e-02 3.1131e-02 -6.0000e+00 3.5572e-01 -3.1795e-02 1.1549e-02 1.7191e-02 -6.0000e+00 2.1093e-01 2.7167e-03 5.9778e-03 7.0496e-03 -6.0000e+00 9.0422e-02 5.5296e-04 -1.0932e-04 1.6397e-04 6.5475e-05 -6.0000e+00 6.0315e-03 -1.7681e-03 8.7569e-05 12 9 1 12 1 1 99.59 15.76 0.10 -0.00177 -0.00259 4 19 4 8 0 490.210 15.00 15.76 4.67 34.80 34.10 20.77 20.77 24.5 722.12 -142054 817 -126684 17212 -5541 48090 10805 -77888 16279 -99818 5092 -81360 27268 -40980 -27253 4984 34252 -1277 -23310 22338 -27300 32296 -18262 1283 10220 -14061 21959 -19137 -682 -20988 4136 -470 4314 -5504 -11821 -9797 -12392 2363 -2880 1171 -1066 -4307 4598 -2909 980 -3056 771 -1717 -630 -2201 -866 4343 2304 2077 -165 1969 -122 -700 -1423 -39 1262 397 3796 2959 1729 -1289 634 1978 1838 2061 915 805 1177 1716 -558 701 -726 -1459 -665 -700 -560 -1994 -615 -2356 237 156 452 132 -197 -147 1412 -637 -1285 370 727 -219 437 657 34 -562 -497 -1077 1430 -442 -2123 -1659 -1550 -764 -331 504 533 297 -158 133 244 -430 101 320 564 -216 -515 860 1023 1189 712 283 919 784 -289 489 -716 -475 323 -63 -73 -501 191 348 -206 335 -858 -231 -2257 5 -2140 107 -35 300 67 -955 101 -1846 37 -1572 249 -903 -641 105 605 -35 -853 566 -1120 758 -734 47 368 -657 742 -917 -28 -1169 219 -31 316 -445 -965 -799 -1182 237 -365 168 -173 -751 768 -534 176 -589 147 -350 -134 -502 -219 1166 672 656 -56 680 -43 -242 -492 -13 448 156 1607 1400 821 -608 300 950 985 1230 580 520 747 1029 -307 352 -364 -759 -390 -465 -420 -1631 -532 -2144 220 153 452 134 -196 -141 1259 -556 -1106 337 724 -241 527 857 46 -746 -621 -1249 1567 -510 -2616 -2090 -2025 -1046 -483 788 874 491 -261 210 369 -650 154 503 919 -358 -843 1348 1572 1780 1029 399 1299 1174 -473 839 -1315 -883 617 -126 -152 -1062 408 746 -433 679 -1693 -436 SS 20240428T074749.8Z 8884.324882 216 1 1.27 2 73.65 82.23 74.17 223.31 0.00 1 0.00 1 0 25 1.136e-01 9.561e-03 1.368e-01 6.920e-03 5.398431e-01 3.535112e-03 5.791646e-03 -6.000000e+00 6.473698e-02 228.48 -2.00 3.19 -2.00 319.16 0.00e+00 1.581675e-03 8.841321e-04 9.877304e-04 -6.000000e+00 2.772384e-03 276.98 -2.00 20.00 -2.00 318.60 0.00e+00 3.498 0.000 302.00 328.00 3 2.6593e+00 9.7792e-03 3.7085e-02 -6.0000e+00 1.6155e-01 2.9278e-02 1.1393e-02 2.5653e-02 -6.0000e+00 1.7520e-01 1.2553e-03 9.3364e-03 1.3165e-02 -6.0000e+00 1.0389e-01 -9.4000e-03 5.0058e-03 4.0992e-03 -6.0000e+00 4.4513e-02 1.2628e-03 -4.1916e-04 1.8356e-04 4.1643e-05 -6.0000e+00 2.9731e-03 -1.0751e-03 -3.0105e-05 12 9 9 12 1 1 999.00 15.77 0.09 -0.00108 -0.00422 2 28 4 8 0 325.060 14.98 15.77 4.94 35.10 34.10 20.77 20.77 24.6 723.45 43769 -40126 24672 -61083 30657 -45539 6779 -5488 -27049 18522 -30085 18321 -21951 35036 -25178 -7142 30036 -3315 3915 -6531 6202 5651 11110 -3331 -4945 5948 -3604 2380 -8480 4742 494 -1475 -2420 1698 -1676 -6122 -3601 -9916 5882 -1902 1690 -3491 -880 878 -412 1561 -3317 -1426 -5092 1541 -1988 2467 3332 467 874 462 251 -3275 2056 136 -1770 459 2573 3818 -1224 2998 -1495 1478 2303 2323 1033 1376 1902 55 683 284 -390 794 -900 -1105 -309 -433 -2419 -1454 -1585 -409 -875 289 910 -75 -678 -28 -395 857 -245 -534 1085 1074 -532 -166 -1082 -1399 204 -251 -1665 -998 -1297 -688 302 464 507 1 268 244 39 1113 -753 728 912 -160 286 952 993 175 988 -954 1431 4 767 -390 -456 -387 -587 141 -773 196 -15 186 5 12 -405 -50 394 -875 310 -1617 322 -953 99 -102 -688 326 -869 384 -818 952 -1454 -398 1302 -214 251 -478 416 383 759 -281 -458 518 -343 204 -801 427 55 -190 -348 239 -235 -895 -584 -1996 1242 -497 458 -1033 -264 262 -126 476 -1073 -463 -1736 526 -765 1003 1427 216 413 228 126 -1643 967 65 -895 248 1509 2365 -783 1805 -907 907 1538 1710 801 1085 1467 41 472 183 -244 499 -636 -873 -265 -401 -2369 -1469 -1670 -445 -973 322 1000 -80 -695 -28 -373 832 -260 -618 1353 1439 -734 -222 -1376 -1665 235 -301 -2121 -1305 -1748 -960 442 715 818 1 427 373 58 1607 -1126 1108 1438 -257 453 1470 1496 258 1412 -1337 1977 6 1192 -643 -775 -675 -1052 259 -1477 379 -29 366 10 22 -740 -90 SS 20240428T082610.7Z 8884.351513 235 1 9.19 2 65.25 86.46 80.06 229.07 0.00 1 0.00 1 0 25 1.448e-02 6.596e-03 3.999e-03 7.516e-04 3.696088e-01 3.807884e-04 4.001633e-03 -6.000000e+00 8.259368e-03 228.48 -2.00 3.19 -2.00 317.94 0.00e+00 7.154727e-04 6.480316e-05 1.847446e-04 -6.000000e+00 3.535413e-04 276.98 -2.00 20.00 -2.00 317.33 0.00e+00 2.373 0.000 302.00 328.00 3 1.7695e+00 1.0176e-03 2.5170e-02 -6.0000e+00 2.0611e-02 1.8460e-02 1.1469e-03 1.7283e-02 -6.0000e+00 2.2350e-02 2.8185e-03 7.5357e-04 8.5877e-03 -6.0000e+00 1.3253e-02 -7.4899e-03 3.9412e-04 2.5214e-03 -6.0000e+00 5.6804e-03 8.8634e-03 3.2369e-05 2.0718e-05 2.5417e-05 -6.0000e+00 3.7906e-04 -1.5310e-03 5.1147e-05 12 9 1 12 1 1 99.97 15.77 0.17 -0.00153 -0.00129 151 151 2 8 0 58.100 15.00 15.77 5.61 36.10 34.30 20.77 20.77 24.6 726.36 -1155 -815 -1576 -5218 -5515 -5390 -3692 -1749 -1772 -4267 -4982 -3906 -2667 -975 -125 -2011 -781 -161 434 762 20 212 222 -120 -208 45 -1023 -1546 -1237 114 1404 1471 1529 -2256 -3436 -3124 -2651 -1094 -494 -861 -1110 -671 -266 -347 425 -253 -64 -419 -658 429 905 743 1222 930 833 1101 241 19 35 283 975 1369 2002 1448 -229 -215 -705 -25 1217 759 979 1045 867 1121 480 272 -531 -778 -72 -1058 -974 -1459 -2249 -1601 -1093 -519 -311 179 465 352 483 -168 -44 308 35 19 657 690 -9 -401 -749 -977 -231 -68 -1319 -973 -1068 -661 95 311 384 61 280 -153 132 419 352 305 177 -230 55 400 729 694 845 21 877 1087 357 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